THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE

Küçükuysal, Ceren; GÜNGÖR, Cansu; ATAYTÜR, Öykü; Vargün, Elif; GÜLCAN, Merve; EVREN, Özden

THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE

Elif VARGÜN, (Department of Chemistry, Science Faculty, Muğla Sıtkı Koçman University, 48000, Muğla, Turkey)

Özden EVREN, (Department of Chemistry, Science Faculty, Muğla Sıtkı Koçman University, 48000, Muğla, Turkey)

Merve GÜLCAN, (Department of Geological Engineering, Engineering Faculty, Muğla Sıtkı Koçman University,48000, Muğla, Turkey)

Öykü ATAYTÜR, (Department of Geological Engineering, Engineering Faculty, Muğla Sıtkı Koçman University,48000, Muğla, Turkey)

Cansu GÜNGÖR (Department of Geological Engineering, Engineering Faculty, Muğla Sıtkı Koçman University,48000, Muğla, Turkey)

Mugla Journal of Science and Technology

2 0

Yıl: 2017 Cilt: 3 Sayı: 2 Sayfa Aralığı: 178 - 183 Metin Dili: Türkçe İndeks Tarihi: 29-07-2022

THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE

Öz:

Kil minerallerinin düzgün dağılımı, polimer kil nanokompozit üretiminde önemli bir role sahiptir. Bu bakımdan, kompozitlerin interkale/eksfoliye yapılarını elde etmek için kilin farklı organomodifikasyon yöntemleri denenmiştir. Bu çalışmada, Çanakkale bentonitinin tetrametilamonyum klorür (TMAC), hekzadesilpiridinyum klorür (HDPC), hekzadesiltrimetilamonyum bromür (HDAB), feniltrimetilamonyum klorür (PMAC) olmak üzere dört farklı kuvaterner amonyum tuzu ile organomodifikasyonu incelenmiştir. Organobentonitler Fourier transform infrared spektroskopi (FTIR), X-ışını kırınımı (XRD) analizi ve termogravimetrik analiz (TGA) ile karakterize edilmiştir. HDAB ve HDPC tuzları kullanılarak bentonitin bazal aralığı 14.9 Å'dan sırasıyla 20.7 Å'a ve 21.4 Å'a kadar artırılmıştır. Bununla birlikte, diğer modifiye edici tuzlar d-aralıklarında önemli değişikliklere neden olamamışlardır

Anahtar Kelime:

KUVATERNER TUZLARININ TÜRÜ VE MİKTARININ ÇANAKKALE BENTONİTİNİN MODİFİKASYONU ÜZERİNE ETKİLERİ

Öz:

The improved dispersion of clay minerals has an essential role for polymer clay nanocomposite manufacturing. In this regard, different organomodifications of clay have been attempted to obtain intercalated/exfoliated structures of composites. In present study, Çanakkale bentonite was organically modified by four different quaternary ammonium salts: tetramethylammonium chloride (TMAC), hexadecylpyridinium chloride (HDPC), hexadecyltrimethylammonium bromide (HDAB), phenyltrimethylammonium chloride (PMAC). Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) analysis and thermogravimetric analysis (TGA) were performed to characterize the organobentonites. The results revealed that there is an increment of basal spacing of bentonite with HDAB and HDPC salts from 14.9 Å to 20.7 Å and 21.4 Å, respectively. However, other modifiers cannot lead to significant changes in d-spacings

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	Vargün E, Küçükuysal C, EVREN Ö, GÜLCAN M, ATAYTÜR Ö, GÜNGÖR C (2017). THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. , 178 - 183.
Chicago	Vargün Elif,Küçükuysal Ceren,EVREN Özden,GÜLCAN Merve,ATAYTÜR Öykü,GÜNGÖR Cansu THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. (2017): 178 - 183.
MLA	Vargün Elif,Küçükuysal Ceren,EVREN Özden,GÜLCAN Merve,ATAYTÜR Öykü,GÜNGÖR Cansu THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. , 2017, ss.178 - 183.
AMA	Vargün E,Küçükuysal C,EVREN Ö,GÜLCAN M,ATAYTÜR Ö,GÜNGÖR C THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. . 2017; 178 - 183.
Vancouver	Vargün E,Küçükuysal C,EVREN Ö,GÜLCAN M,ATAYTÜR Ö,GÜNGÖR C THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. . 2017; 178 - 183.
IEEE	Vargün E,Küçükuysal C,EVREN Ö,GÜLCAN M,ATAYTÜR Ö,GÜNGÖR C "THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE." , ss.178 - 183, 2017.
ISNAD	Vargün, Elif vd. "THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE". (2017), 178-183.

APA	Vargün E, Küçükuysal C, EVREN Ö, GÜLCAN M, ATAYTÜR Ö, GÜNGÖR C (2017). THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology, 3(2), 178 - 183.
Chicago	Vargün Elif,Küçükuysal Ceren,EVREN Özden,GÜLCAN Merve,ATAYTÜR Öykü,GÜNGÖR Cansu THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology 3, no.2 (2017): 178 - 183.
MLA	Vargün Elif,Küçükuysal Ceren,EVREN Özden,GÜLCAN Merve,ATAYTÜR Öykü,GÜNGÖR Cansu THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology, vol.3, no.2, 2017, ss.178 - 183.
AMA	Vargün E,Küçükuysal C,EVREN Ö,GÜLCAN M,ATAYTÜR Ö,GÜNGÖR C THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology. 2017; 3(2): 178 - 183.
Vancouver	Vargün E,Küçükuysal C,EVREN Ö,GÜLCAN M,ATAYTÜR Ö,GÜNGÖR C THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology. 2017; 3(2): 178 - 183.
IEEE	Vargün E,Küçükuysal C,EVREN Ö,GÜLCAN M,ATAYTÜR Ö,GÜNGÖR C "THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE." Mugla Journal of Science and Technology, 3, ss.178 - 183, 2017.
ISNAD	Vargün, Elif vd. "THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE". Mugla Journal of Science and Technology 3/2 (2017), 178-183.