Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations

DOĞAN, Başak; SÖZÜER, Işıl Topaloğlu; KILIÇKAYA, Gülşah; AÇAR SELÇUKİ, NURSEL

Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations

Gülşah KILIÇKAYA, (İzmir Yüksek Teknoloji Enstitüsü, İzmir, Türkiye)

Başak DOĞAN, (İzmir Yüksek Teknoloji Enstitüsü, İzmir, Türkiye)

NURSEL AÇAR SELÇUKİ, (Ege Üniversitesi, Fen Fakültesi, İzmir, Türkiye)

Işıl Topaloğlu SÖZÜER (İzmir Yüksek Teknoloji Enstitüsü, İzmir, Türkiye)

Turkish Journal of Chemistry

1 0

Yıl: 2009 Cilt: 33 Sayı: 5 Sayfa Aralığı: 693 - 708 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations

Öz:

Reaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO2 Cl2 (THF)2] with PPh3 yielded the oxomolybdenum(IV) species [MoOCl 2 (THF)2 ] (1) by the removal of one oxygen atom as PPh3 O. The complexes [MoOCl 2(=NC6H4CN)] 2, [MoOCl2 (CNC6H4 OH)] 3, [MoOCl2(=NC6H4NH2)] 4, and [MoOCl2(=NC6H4OCH3)] 5, were synthesized by the reactions of [MoOCl 2 (THF)2] with XC6H4Y (X = NH2 , Y = CN; X= CN, Y = OH; X = Y = NH2; X = NH2, Y = OCH3) . All the new compounds were characterized by elemental analyses, and FTIR, UV-Vis, and 1 H- and 13 C-NMR spectra. Geometrical parameters and molecular orbital calculations showed that compounds 2-5 are stabilized by a charge transfer between the Mo center and the phenyl ring.

Anahtar Kelime:

Konular: Mühendislik, Kimya

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	KILIÇKAYA G, DOĞAN B, AÇAR SELÇUKİ N, SÖZÜER I (2009). Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. , 693 - 708.
Chicago	KILIÇKAYA Gülşah,DOĞAN Başak,AÇAR SELÇUKİ NURSEL,SÖZÜER Işıl Topaloğlu Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. (2009): 693 - 708.
MLA	KILIÇKAYA Gülşah,DOĞAN Başak,AÇAR SELÇUKİ NURSEL,SÖZÜER Işıl Topaloğlu Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. , 2009, ss.693 - 708.
AMA	KILIÇKAYA G,DOĞAN B,AÇAR SELÇUKİ N,SÖZÜER I Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. . 2009; 693 - 708.
Vancouver	KILIÇKAYA G,DOĞAN B,AÇAR SELÇUKİ N,SÖZÜER I Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. . 2009; 693 - 708.
IEEE	KILIÇKAYA G,DOĞAN B,AÇAR SELÇUKİ N,SÖZÜER I "Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations." , ss.693 - 708, 2009.
ISNAD	KILIÇKAYA, Gülşah vd. "Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations". (2009), 693-708.

APA	KILIÇKAYA G, DOĞAN B, AÇAR SELÇUKİ N, SÖZÜER I (2009). Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. Turkish Journal of Chemistry, 33(5), 693 - 708.
Chicago	KILIÇKAYA Gülşah,DOĞAN Başak,AÇAR SELÇUKİ NURSEL,SÖZÜER Işıl Topaloğlu Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. Turkish Journal of Chemistry 33, no.5 (2009): 693 - 708.
MLA	KILIÇKAYA Gülşah,DOĞAN Başak,AÇAR SELÇUKİ NURSEL,SÖZÜER Işıl Topaloğlu Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. Turkish Journal of Chemistry, vol.33, no.5, 2009, ss.693 - 708.
AMA	KILIÇKAYA G,DOĞAN B,AÇAR SELÇUKİ N,SÖZÜER I Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. Turkish Journal of Chemistry. 2009; 33(5): 693 - 708.
Vancouver	KILIÇKAYA G,DOĞAN B,AÇAR SELÇUKİ N,SÖZÜER I Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations. Turkish Journal of Chemistry. 2009; 33(5): 693 - 708.
IEEE	KILIÇKAYA G,DOĞAN B,AÇAR SELÇUKİ N,SÖZÜER I "Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations." Turkish Journal of Chemistry, 33, ss.693 - 708, 2009.
ISNAD	KILIÇKAYA, Gülşah vd. "Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations". Turkish Journal of Chemistry 33/5 (2009), 693-708.