Yıl: 2015 Cilt: 39 Sayı: 1 Sayfa Aralığı: 80 - 90 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches

Öz:
The present study investigates fatty acid composition and trans fatty acid formation in oils extracted from French-friedpotatoes, which were produced in the laboratory and collected from diferent restaurants. Potatoes were fried at 180 °C at diferentfrying periods (1, 7, 13, 19, 25, and 31 min) and the fatty acid composition of the extracted oils was determined. Principal componentanalysis and hierarchical cluster analysis were used to characterize and classify the samples. Four major fatty acids were identifedin the samples, namely palmitic acid, stearic acid, oleic acid, and linoleic acid. Linolelaidic acid (C18:2 trans) was detected in the oilsamples extracted from potatoes fried in margarine. Tree principal components (PCs) and 4 main clusters were obtained from thechemometric analysis, which characterized the samples. Tree PCs were found to be explanatory of more than 84.96% of the totalvariability in the data set.
Anahtar Kelime:

Konular: Orman Mühendisliği
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • Agilent (2008). Agilent Application Catalogue 2008. Column Selection for the Analysis of Fatty Acid Methyl Esters. Catalogue No: 5989-3760 EN. Santa Clara, CA, USA: Agilent.
  • Aro A, Amelsvoort JV, Becker W, van Erp-Baart MA, Kafatos A, Leth T, van Poppel G (1998). Trans fatty acids in dietary fats and oils from 14 European countries: Te TRANSFAIR Study. J Food Compos Anal 11: 137–149.
  • Bakker N, Van’t Veer P, Zock PL (1997). Adipose fatty acids and cancers of the breast, prostate and colon: an ecological study. Int J Cancer 72: 587–591.
  • Bansal G, Zhou W, Tan TW, Neo FL, Lo HL (2009). Analysis of trans fatty acids in deep frying oils by three diferent approaches. Food Chem 116: 535–541.
  • Boskou G, Salta FN, Chiou A, Troullidou E, Andrikopoulos NK (2006). Content of trans, trans-2,4-decadienal in deep-fried and pan-fried potatoes. Eur J Lipid Sci Tech 108: 109–115.
  • Bougnoux P, Hajjaji N, Maheo K, Couet C, Chevalier S (2010). Fatty acids and breast cancer: sensitization to treatments and prevention of metastatic re-growth. Prog Lipid Res 49: 76–86.
  • Brat J, Pokorny J (2000). Fatty acid composition of margarines and cooking fats available on the Czech market. J Food Compos Anal 13: 337–343.
  • Brodnjak-Vončina DZ, Kodba C, Novič M (2005). Multivariate data analysis in classifcation of vegetable oils characterized by the content of fatty acids. Chemometr Intell Lab 75: 31–43.
  • Brühl L (2014). Fatty acid alterations in oils and fats during heating and frying. Eur J Lipid Sci Tech 116: 707–715.
  • Chang SS, Peterson RJ, Ho CT (1978). Chemical reactions involved in the deep-fat frying of foods. J Amer Oil Chem Soc 55: 718– 727.
  • Choe E, Min DB (2007). Chemistry of deep fat frying oils. J Food Sci 72: R77–R86.
  • Dobarganes C, Marquez-Ruiz G, Velasco J (2000). Interactions between fat and food during deep-frying. Eur J Lipid Sci Tech 102: 521–528.
  • Dogan M, Toker OS (2014). Hydroxymethylfurfural content and physicochemical properties of the caramel samples enriched with diferent dietary fbres. Quality Assurance and Safety of Crops & Foods (in press).
  • García-López C, Grané-Teruel N, Berenguer-Navarro V, García- García JE, Martín-Carratalá ML (1996). Major fatty acid composition of 19 almond cultivars of diferent origins: a chemometric approach. J Agr Food Chem 44: 1751–1755.
  • Gertz C (2000). Chemical and physical parameters as quality indicators of used frying fats. Eur J Lipid Sci Tech 102: 566–572.
  • Haswell SJ (1992). Introduction to chemometrics. In: Gemperline P, editor. Practical Guide to Chemometrics. 1st ed. New York, NY, USA: Marcel Dekker, pp. 1–3.
  • Hwang D (2000). Fatty acids and immune responses a new perspective in searching for clues to mechanism. Annu Rev Nutr 20: 431–456.
  • Kadegowda AKG, Piperova LS, Erdman RA (2008). Principal component and multivariate analysis of milk long-chain fatty acid composition during diet-induced milk fat depression. J Dairy Sci 91: 749–759.
  • Kaiser HF (1970). A second generation little jify. Psychometrika 35: 401–415.
  • Kandhro A, Sherazi STH, Mahesar SA, Bhanger MI, Younis Talpur M, Rauf A (2008). GC-MS quantification of fatty acid profile including trans FA in the locally manufactured margarines of Pakistan. Food Chem 109: 207–211.
  • Karabulut I, Turan S (2006). Some properties of margarines and shortenings marketed in Turkey. J Food Compos Anal 19: 55–58.
  • Karn S, Abraham RA, Ramakrishnan L (2013). Assessment of trans fatty acid content in widely consumed snacks by gas chromatography in a developing country. Food Nutr Sci 4: 1281–1286.
  • Kermanshahi YK, Tabaraki R, Karimi H, Nikorazm M, Abbasi S (2010). Classifcation of Iranian bottled waters as indicated by manufacturer’s labeling. Food Chem 120: 1218–1223.
  • Kim J, Kim DN, Lee SH, Yoo SH, Lee S (2010). Correlation of fatty acid composition of vegetable oils with rheological behavior and oil uptake. Food Chem 118: 398–402.
  • Kinsella JE, Bruckner G, Mai J, Shimp J (1981). Metabolism of trans fatty acids with emphasis on the efects of trans, trans- octadecadienoate on lipid composition, essential fatty acid, and prostaglandins: an overview. Am J Clin Nutr 34: 2307–2318.
  • Kris-Etherton PM, Harris WS, Appel LJ (2002). Fish consumption, fish oil, omega-3 fatty acids, and cardiovascular disease. Circulation 106: 2747–2757.
  • Krokida MK, Oreopoulou V, Maroulis ZB (2000). Water loss and oil uptake as a function of frying time. J Food Eng 44: 39–46.
  • Larrigaudiere C, Lentheric I, Puy J, Pinto E (2004). Biochemical characterization of core browning and brown heart disorder in pear by multivariate analysis. Postharvest Biol Tech 31: 29–39.
  • Lima DC, dos Santos AMP, Araujo RGO, Scarminio IS, Bruns RE, Ferreira SLC (2010). Principal component analysis and hierarchical cluster analysis for homogeneity evaluation during the preparation of a wheat four laboratory reference material for inorganic analysis. Microchem J 95: 222–226.
  • López A, Montaño A, García P, Garrido A (2006). Fatty acid profle of table olives and its multivariate characterization using unsupervised (PCA) and supervised (DA) chemometrics. J Agr Food Chem 54: 6747–6753.
  • Martín-Carratalá ML, García-López C, Berenguer-Navarro V, Grané-Teruel N (1998). New contribution to the chemometric characterization of almond cultivars on the basis of their fatty acid profles. J Agr Food Chem 46: 963–967.
  • Matos LC, Cunha SC, Amaral JS, Pereira JA, Andrade PB, Seabra RM, Oliveira BPP (2007). Chemometric characterization of three varietal olive oils (Cvs. Cobrançosa, Madural and Verdeal Transmontana) extracted from olives with diferent maturation indices. Food Chem 102: 406–414.
  • Matsuzaki H, Okamoto T, Aoyama M, Maruyama T, Niiya I, Yanagita T, Sugano M (2002). Trans fatty acids in margarines marketed in eleven countries. J Oleo Sci 51: 555–561.
  • Mensink RP, Katan MB (1990). Efect of dietary trans fatty acids on high density and low density lipoprotein cholesterol levels in healthy subjects. New Engl J Med 323: 439–445.
  • Mensink RP, Zock PL, Katan MG, Hornstra G (1992). Efect of dietary cis and trans fatty acids on serum lipoprotein (a) in humans. J Lipid Res 33: 1493–1501.
  • Mori TA, Burke V, Puddey IB, Watts GF, O’Neal DN, Best JD, Beilin JL (2000). Purified eicosapentaenoic and docosahexaenoic acids have diferential efects on serum lipids and lipoproteins, LDL particle size, glucose, and insulin in mildly hyperlipidemic men. Am J Clin Nutr 71: 1085–1094.
  • Nestel P (2014). Trans fatty acids: are its cardiovascular risks fully appreciated? Clin Ter 36: 315–321.
  • Nestel P, Noakes M, Belling B, McArthur R, Clifon P, Janus E, Abbey M (1992). Plasma lipoprotein and Lp (a) changes its substitution of elaidic acid for oleic acid in the diet. J Lipid Res 33: 1029–1036.
  • Patras A, Brunton NP, Downey G, Rawson A, Warriner K, Gernigon G (2011). Application of principal component and hierarchical analysis to classify fruits and vegetables commonly consumed in Ireland based on in vitro antioxidant activity. J Food Compos Anal 24: 250–256.
  • Pozo-Diez RM (1995). Estudio de1 proceso de fitura de alimentos frescos y congelados prefritos. Comportamiento de1 aceite de semilla de girasol de alto contenido en acido oleico. PhD, University of Alcalá, Alcalá de Henares, Spain (in Spanish).
  • Sahin S, Sumnu SG (2009) Advances in Deep-Fat Frying of Foods. Boca Raton, FL, USA: CRC Press.
  • Sathe SK, Seeram NP, Kshirsagar HH, Heber D, Lapsley, KA (2008). Fatty acid composition of California grown almonds. J Food Sci 73: C607–C614.
  • Sato T (1994). Application of principal-component analysis on near-infrared spectroscopic data of vegetable oils for their classifcation. J Am Oil Chem Soc 71: 293–298.
  • Sebedio JL, Grandgirard A, Septier C, Prevost J (1987). Etat d’alteration de quelques huiles de friture prelevées en restauration. Revue Francaise des Corps Gras 34: 15 (in French).
  • Shin EC, Craf BD, Pegg RB, Phillips RD, Eitenmille RR (2010). Chemometric approach to fatty acid profles in runner type peanut cultivars by principal component analysis (PCA). Food Chem 119: 1262–1270.
  • Sneath PHA, Sokal RR, editors (1973). Numerical Taxonomy: Te Principles and Practice of Numerical Classifcation. San Francisco, CA, USA: W.H. Freeman.
  • Taşan M, Dağlıoğlu O (2005). Trans fatty acids: their chemical structures, formation and dietary intake. J Tekirdag Agric Fac 2: 79–88 (in Turkish with English abstract).
  • Toker OS, Dogan M, Canıyılmaz E, Ersöz NB, Kaya Y (2013). Te efects of diferent gums and their interactions on the rheological properties of a dairy dessert: a mixture design approach. Food Bioprocess Tech 6: 896–908.
  • Triantafllou D, Zografos V, Katsikas H (2003). Fatty acid content of margarines in the Greek market (including trans-fatty acids): a contribution to improving consumers’ information. Int J Food Sci Nutr 54: 135–141.
  • Tsanev R, Russeva A, Rizov T, Dontcheva I (1998). Content of trans- fatty acids in edible margarines. J Amer Oil Chem Soc 75: 143–145.
  • Tsuzuki W, Matsuoka A, Ushida K (2010). Formation of trans fatty acids in edible oils during the frying and heating process. Food Chem 123: 976–982.
  • Ward JH (1963). Hierarchical grouping to optimize an objective function. J Am Stat Assoc 58: 236–244.
  • Yalcin H, Toker OS, Dogan M (2012). Efect of oil type and fatty acid composition on dynamic and steady shear rheology of vegetable oils. J Oleo Sci 61:181–187.
APA yıldırım e, Toker O, KARAMAN S, KAYACIER A, DOGAN M (2015). Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. , 80 - 90.
Chicago yıldırım elif,Toker Omer Said,KARAMAN Safa,KAYACIER Ahmed,DOGAN Mahmut Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. (2015): 80 - 90.
MLA yıldırım elif,Toker Omer Said,KARAMAN Safa,KAYACIER Ahmed,DOGAN Mahmut Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. , 2015, ss.80 - 90.
AMA yıldırım e,Toker O,KARAMAN S,KAYACIER A,DOGAN M Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. . 2015; 80 - 90.
Vancouver yıldırım e,Toker O,KARAMAN S,KAYACIER A,DOGAN M Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. . 2015; 80 - 90.
IEEE yıldırım e,Toker O,KARAMAN S,KAYACIER A,DOGAN M "Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches." , ss.80 - 90, 2015.
ISNAD yıldırım, elif vd. "Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches". (2015), 80-90.
APA yıldırım e, Toker O, KARAMAN S, KAYACIER A, DOGAN M (2015). Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. Turkish Journal of Agriculture and Forestry, 39(1), 80 - 90.
Chicago yıldırım elif,Toker Omer Said,KARAMAN Safa,KAYACIER Ahmed,DOGAN Mahmut Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. Turkish Journal of Agriculture and Forestry 39, no.1 (2015): 80 - 90.
MLA yıldırım elif,Toker Omer Said,KARAMAN Safa,KAYACIER Ahmed,DOGAN Mahmut Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. Turkish Journal of Agriculture and Forestry, vol.39, no.1, 2015, ss.80 - 90.
AMA yıldırım e,Toker O,KARAMAN S,KAYACIER A,DOGAN M Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. Turkish Journal of Agriculture and Forestry. 2015; 39(1): 80 - 90.
Vancouver yıldırım e,Toker O,KARAMAN S,KAYACIER A,DOGAN M Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches. Turkish Journal of Agriculture and Forestry. 2015; 39(1): 80 - 90.
IEEE yıldırım e,Toker O,KARAMAN S,KAYACIER A,DOGAN M "Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches." Turkish Journal of Agriculture and Forestry, 39, ss.80 - 90, 2015.
ISNAD yıldırım, elif vd. "Investigation of fatty acid composition and trans fatty acid formation in extracted oils from French-fried potatoes and classifcation of samples using chemometric approaches". Turkish Journal of Agriculture and Forestry 39/1 (2015), 80-90.