Investigation of the adsorption kinetics of methylene blue onto cotton wastes

USTA, Mustafa; Ertas, Murat; acemioğlu, bilal; ALMA, MEHMET HAKKI

Investigation of the adsorption kinetics of methylene blue onto cotton wastes

Bilal ACEMİOĞLU, (Kilis 7 Aralık Üniversitesi, Fen ve Edebiyat, Fakültesi, Kimya, Bölümü, Kilis, Türkiye)

MURAT ERTAŞ, (Bursa Teknik Üniversitesi, Orman Fakültesi, Orman Endüstri Mühendisliği, Bölümü, Bursa, Türkiye)

Mehmet Hakkı ALMA, (Kahramanmaraş Sütçü İmam Üniversitesi, Orman Fakültesi, Endüstri Mühendisliği Bölümü, Kahramanmaraş, Türkiye)

Mustafa USTA (Karadeniz Teknik Üniversitesi, Orman Fakültesi, Orman Endüstrisi Mühendisliği Bölümü, Trabzon, Türkiye)

Turkish Journal of Chemistry

1 0

Yıl: 2014 Cilt: 38 Sayı: 3 Sayfa Aralığı: 454 - 469 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Investigation of the adsorption kinetics of methylene blue onto cotton wastes

Öz:

Cotton stalk (CS), cotton waste (CW), and cotton dust (CD), which are cotton wastes, were used as adsorbents to study the adsorption kinetics of methylene blue from aqueous solution. Kinetics of the batch adsorption experiment was investigated according to the pseudo-first order, the pseudo-second order, and the intraparticle diffusion models used commonly in the literature. The effects of the initial concentration, solution pH, and temperature on kinetic parameters (adsorption rate constant, initial adsorption rate, equilibrium adsorption capacity, etc.) were studied. The results showed that the adsorption process was well fitted to the pseudo-second order model for all adsorbents. The activation energy (E a ) of the adsorption process was determined by using the pseudo-second-order rate constants by means of Arrhenius−1equation. The values of E a were estimated as 7.05, 10.89, and 35.72 kJ mol for CS, CW, and CD, respectively. From the results, it was understood that the adsorption process was controlled by an intraparticle diffusion mechanism as well as both an activated process and a physical adsorption process.

Anahtar Kelime:

Konular: Mühendislik, Kimya

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

Ho, Y. S.; McKay, G. Trans IChemE. 1998, 76(B), 313318.
Dogan, M.; Alkan, M. Chemosphere. 2003, 50, 517528.
Walker, G. M.; Hansen, L.; Hanna, J. A.; Allen, S. J. Water Res. 2003, 37, 20812089.
Ho, Y. S.; McKay, G. Trans IChemE. 1998, 76(B), 183191.
Kumar, K. V. Process Biochem. 2006, 41, 11981202.
Ahmad, R..; Kumar, R. Clean- Soil, Air, Water 2011, 39, 74 82.
Jovic-Jovicic, N.; Milutinovic-Nikolic, A.; Grzetic, I.; Javonovic, D. Chem. Eng. Technol. 2008, 31, 567574.
Senthilkumaar, S.; Kalaamani, P.; Subburamaan, C. V.; Subramaniam, N. G.; Kang, T. V. Chem. Eng. Technol. 2011, 34, 14591467.
Hameed, B. H.; El-Khaiary, M. I. J. Hazard. Mater. 2008, 154, 639648.
Yao, Z.; Wang, L.; Qi, J. Clean-Soil, Air, Water 2009, 37, 642 648.
Hameed, B. H.; Mahmoud, D. K.; Ahmad, A. L. J. Hazard. Mater. 2008, 158, 6572. Acemioglu, B. Chem. Eng. J. 2005, 106, 7381.
Ertas, M.; Acemioglu, B.; Alma, M. H.; Usta, M. J. Hazard. Mater. 2010, 183, 421427
Lagergren, S. Kungliga Suenska Vetens kapsakademiens. Handlingar, Band, 1898, 24, 139.
Ho, Y. S.; McKay, G. Chem. Eng. J. 1998, 70, 115124.
Ho, Y. S.; McKay, G. Process Biochem. 1999, 34, 451465.
Weber, W. J.; Morris J. C. J. Saint. Eng. Div. ASCE, 1963, 89(SA2), 3159.
Dogar, C.; Gurses, A.; A ̧cıkyıldız, M.; Ozkan, E. Colloid Surface B. 2010, 76, 279285.
Yakub, M. T.; Sen, T. K.; Ang, H. M. Water Air Soil Poll. 2012, 223, 52675282.
Vucurovic, V. M.; Razmovski, R. N.; Tekic, M. G. J. Taiwan Inst. Chem. Eng. 2012, 43, 108111.
Nasuha, N.; Hameed, B. H.; Mohd Din, A. T. J. Hazard. Mater. 2010, 175, 126132.
Saha, P.; Chowdhury, S.; Gupta, S.; Kumar, I.; Kumar, R.; CLEAN - Soil, Air, Water 2010, 38, 437445.
Sarioglu, M.; Atay, U. A. Global Nest J. 2006, 8, 113120.
Malash, G. F.; El-Khaiary, M. J. Colloid Interf. Sci. 2010, 348, 537545.
Hameed, B. H.; Mahmoud, D. K.; Ahmad, A. L. J. Hazard. Mater. 2008, 158, 499506.
Aroguz, A. Z.; Gulen, J.; Evers, R. H. Bioresource Technol. 2008, 99, 15031508.
Dogan, M.; Abak, H.; Alkan, M. J. Hazard. Mater. 2009, 164, 172181.
Erta ̧s, M. MSc Thesis, Karadeniz Technical University, Trabzon, 2005 (in Turkish).

APA	acemioğlu b, Ertas M, ALMA M, USTA M (2014). Investigation of the adsorption kinetics of methylene blue onto cotton wastes. , 454 - 469.
Chicago	acemioğlu bilal,Ertas Murat,ALMA MEHMET HAKKI,USTA Mustafa Investigation of the adsorption kinetics of methylene blue onto cotton wastes. (2014): 454 - 469.
MLA	acemioğlu bilal,Ertas Murat,ALMA MEHMET HAKKI,USTA Mustafa Investigation of the adsorption kinetics of methylene blue onto cotton wastes. , 2014, ss.454 - 469.
AMA	acemioğlu b,Ertas M,ALMA M,USTA M Investigation of the adsorption kinetics of methylene blue onto cotton wastes. . 2014; 454 - 469.
Vancouver	acemioğlu b,Ertas M,ALMA M,USTA M Investigation of the adsorption kinetics of methylene blue onto cotton wastes. . 2014; 454 - 469.
IEEE	acemioğlu b,Ertas M,ALMA M,USTA M "Investigation of the adsorption kinetics of methylene blue onto cotton wastes." , ss.454 - 469, 2014.
ISNAD	acemioğlu, bilal vd. "Investigation of the adsorption kinetics of methylene blue onto cotton wastes". (2014), 454-469.

APA	acemioğlu b, Ertas M, ALMA M, USTA M (2014). Investigation of the adsorption kinetics of methylene blue onto cotton wastes. Turkish Journal of Chemistry, 38(3), 454 - 469.
Chicago	acemioğlu bilal,Ertas Murat,ALMA MEHMET HAKKI,USTA Mustafa Investigation of the adsorption kinetics of methylene blue onto cotton wastes. Turkish Journal of Chemistry 38, no.3 (2014): 454 - 469.
MLA	acemioğlu bilal,Ertas Murat,ALMA MEHMET HAKKI,USTA Mustafa Investigation of the adsorption kinetics of methylene blue onto cotton wastes. Turkish Journal of Chemistry, vol.38, no.3, 2014, ss.454 - 469.
AMA	acemioğlu b,Ertas M,ALMA M,USTA M Investigation of the adsorption kinetics of methylene blue onto cotton wastes. Turkish Journal of Chemistry. 2014; 38(3): 454 - 469.
Vancouver	acemioğlu b,Ertas M,ALMA M,USTA M Investigation of the adsorption kinetics of methylene blue onto cotton wastes. Turkish Journal of Chemistry. 2014; 38(3): 454 - 469.
IEEE	acemioğlu b,Ertas M,ALMA M,USTA M "Investigation of the adsorption kinetics of methylene blue onto cotton wastes." Turkish Journal of Chemistry, 38, ss.454 - 469, 2014.
ISNAD	acemioğlu, bilal vd. "Investigation of the adsorption kinetics of methylene blue onto cotton wastes". Turkish Journal of Chemistry 38/3 (2014), 454-469.