Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs

TOMAKİN, Murat; YILMAZ, SALİH; POLAT, ISMAIL; BACAKSIZ, Emin

Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs

İsmail POLAT, (Karadeniz Teknik Üniversitesi, Mühendislik Mimarlık Fakültesi, Trabzon, Türkiye)

Salih YILMAZ, (Adana Bilim ve Teknoloji Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, Malzeme Mühendisliği Bölümü, Adana, Türkiye)

Murat TOMAKİN, (Recep Tayyip Erdoğan Üniversitesi, Fen Edebiyat Fakültesi, Fizik Bölümü)

Emin BACAKSIZ (Recep Tayyip Erdoğan Üniversitesi, Fen Edebiyat Fakültesi, Fizik Bölümü)

Turkish Journal of Physics

2 0

Yıl: 2017 Cilt: 41 Sayı: 2 Sayfa Aralığı: 160 - 170 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs

Öz:

ZnO- and Mg-doped ZnO samples are prepared by spray pyrolysis on conducting glass substrates to fabricate ZnO-based dye-sensitized solar cells (DSSCs). In uences of Mg-doping content on the power conversion efficiencies of ZnO-based DSSCs are investigated. X-ray diffraction results show that all the samples exhibit a hexagonal wurtzite structure. Scanning electron microscopy data indicate that the ZnO sample has uniform rods with 1 m diameter. With respect to ZnO, the band gap value of 4 at.% Mg-doped ZnO samples improves to the value of 3.27 eV and a further increase in Mg level up to 6 at.% gives rise to a decline in the band gap value of 3.22 eV. Photoluminescence measurements illustrate that intensities of the ultraviolet peak and a red luminescence peak take their maximum values for 4 at.% Mg doping. From solar cell performance measurements, the best power conversion efficiency of 0.08% is obtained for the doping amount of 4 at.% Mg.

Anahtar Kelime:

Konular: Fizik, Uygulamalı

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

[1] O'Regan, B.; Gratzel, M. Nature 1991 , 353 , 737-739.
[2] Gratzel, M. Nature 2001 , 414 , 338-344.
[3] Nazeeruddin, M. K.; Pechy, P.; Renouard, T.; Zakeeruddin, S. M.; Humphry-Baker, R.; Comte, P.; Liska, P.; Cevey, L.; Costa, E.; Shklover, V.; et al. J. Am. Chem. Soc. 2001 , 123 , 1613-1624.
[4] Chen, C.; Wang, M.; Li, J.; Pootrakulchote, N.; Alibabaei, L.; Ngocle, C.; Decopper, J.; Tsai, J.; Gratzel, C.; Wu, C.; et al. ACS Nano . 2009 , 3 , 3103-3109.
[5] Chen, Z.; Tang, Y.; Zhang, L.; Luo, L. Electrochim. Acta 2006 , 51 , 5870-5875.
[6] Kashyout, A. B.; Soliman, M.; Gamal, M. E.; Fathy, M. Mater. Chem. Phys. 2005 , 90 , 230-233.
[7] Lu, L.; Li, R.; Fan, K.; Peng, T. Sol. Energy 2010 , 84 , 844-853.
[8] Wang, Z. L. Mater. Sci. Eng., R. 2009 , 64 , 33-71.
[9] Ylmaz, S.; Bacaksz, E.; McGlynn, E.; Polat, _ I.; Ozcan, S. Thin Solid Films 2012 , 520 , 5172-5178.
[10] Lupan, O.; Guerin, V. M.; Ghimpu, L.; Tiginyanu, I. M.; Pauporte, T. Chem. Phys. Lett. 2012 , 550 , 125-129.
[11] Jin, C. F.; Yuan, X.; Ge, W. W.; Hong, J. M.; Xin, X. Q. Nanotechnology 2003 , 14 , 667-669.
[12] Kong, X.; Sun, X.; Li, X.; Li, Y. Mater. Chem. Phys . 2003 , 82 , 997-1001.
[13] Atuchin, V. V.; Galashov, E. N.; Kozhukhov, A. S.; Pokrovsky, L. D.; Shlegel, V. N. J. Cryst. Growth 2011 , 318 , 1147-1150.
[14] Motevalizadeh, L.; Shohany, B. G.; Abrishami, M. E. Mod. Phys. Lett. B 2016 , 30 , 1650024-1650028.
[15] Olvera, M. D. L.; Maldonado, A.; Asomoza, R. Sol. Energy Mater. Sol. Cells 2002 , 73 , 425-433.
[16] Rahmani, M. B.; Keshmiri, S. H.; Sha ei, M.; Latham, K.; Wlodarski, W.; du Plessis, J.; Kalantar-Zadeh, K. Sens. Lett. 2009 , 7 , 621-628.
[17] Kaipeng, L.; Beifang, Y.; Hongwei, Y.; Zhengping, F.; Meiwang, W.; Youjun, C.; Jian, Z. J. Lumin . 2009 , 129 , 969-972.
[18] Bacaksz, E.; Aksu, S.; Ylmaz, S.; Parlak, M.; Altunbas, M. Thin Solid Films 2010 , 518 , 4076-4080.
[19] Mariappan, R.; Ponnuswamy, V.; Suresh, R.; Suresh, P.; Chandra Bose, A.; Ragavendar, M. J. Alloys Compd. 2014 , 582 , 387-391.
[20] Sahal, M.; Mar, B.; Mollar, M.; Manjon, F. J. Phys. Status Solidi C 2010 , 7 , 2306-2310.
[21] Yun, S.; Lee, J.; Chung, J.; Lim, S. J. Phys. Chem. Solids 2010 , 71 , 1724-1731.
[22] Polat, _ I. J. Mater. Sci. - Mater. Electron. 2014 , 25 , 3721-3726.
[23] Raj, C. J.; Prabakar, K.; Karthick, S. N.; Hemalatha, K. V.; Son, M. K.; Kim, H. J. J. Phys. Chem. C 2013 , 117 , 2600-2607.
[24] Polat, _ I.; Ylmaz, S.; Bacaksz, E.; Atasoy, Y.; Tomakin, M. J. Mater. Sci. - Mater. Electron. 2014 , 25 , 3173-3178.
[25] Iqbal, J.; Jan, T.; Ismail, M.; Ahmad, N.; Arif, A.; Khan, M.; Adil, M.; Sami-ul, H.; Arshad, A. Ceram. Int. 2014 , 40 , 7487-7493.
[26] Ylmaz, S.; Parlak, M.; Ozcan, S.; Altunbas, M.; McGlynn, E.; Bacaksz, E. Appl. Surf. Sci . 2011 , 257 , 9293-9298.
[27] Li, Z. H.; Cho, E. S.; Kwon, S. J. Appl. Surf. Sci . 2014 , 314 , 97-103.
[28] Ginting, R. T.; Yap, C. C.; Yahaya, M.; Salleh, M. M. J. Alloys Compd . 2014 , 585 , 696-702.
[29] Caglar, M.; Caglar, Y.; Ilican, S. Physica B 2016 , 485 , 6-13.
[30] Agrawal, A.; Dar, T. A.; Phase, D. M.; Sen, P. J. Cryst. Growth 2013 , 384 , 9-12.
[31] Abed, C.; Bouzidi, C.; Elhouichet, H.; Gelloz, B.; Ferid, M. Appl. Surf. Sci . 2015 , 349 , 855-863.
[32] Singh, V. P.; Rath, C. RSC Adv . 2015 , 5 , 44390-44397.
[33] Zhaoa, M.; Wanga, X.; Ninga, L.; Hea, H.; Jiaa, J.; Zhang, L.; Xinjian, L. J. Alloys Compd . 2010 , 507 , 97-100.
[34] Ylmaz, S.; McGlynn, E.; Bacaksz, E.; Cullen, J.; Chellappan, R. K. Chem. Phys. Lett . 2012 , 525 , 72-76.
[35] Lin, Y. J.; Wu, P. H.; Tsai, C. L.; Liu, C. J.; Lin, Z. R.; Chang, H. C.; Lee, C. T. J. Appl. Phys. 2008 , 103 , 113709-11373.
[36] Ye, N.; Qi, J.; Qi, Z.; Zhang, X.; Yang, Y.; Liu, J.; Zhang, Y. J. Power Sources 2010 , 195 , 5806-5809.
[37] Nayeri, F. D.; Soleimani, E. A.; Salehi, F. Renewable Energy 2013 , 60 , 246-255.

APA	POLAT I, YILMAZ S, TOMAKİN M, BACAKSIZ E (2017). Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. , 160 - 170.
Chicago	POLAT ISMAIL,YILMAZ SALİH,TOMAKİN Murat,BACAKSIZ Emin Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. (2017): 160 - 170.
MLA	POLAT ISMAIL,YILMAZ SALİH,TOMAKİN Murat,BACAKSIZ Emin Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. , 2017, ss.160 - 170.
AMA	POLAT I,YILMAZ S,TOMAKİN M,BACAKSIZ E Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. . 2017; 160 - 170.
Vancouver	POLAT I,YILMAZ S,TOMAKİN M,BACAKSIZ E Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. . 2017; 160 - 170.
IEEE	POLAT I,YILMAZ S,TOMAKİN M,BACAKSIZ E "Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs." , ss.160 - 170, 2017.
ISNAD	POLAT, ISMAIL vd. "Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs". (2017), 160-170.

APA	POLAT I, YILMAZ S, TOMAKİN M, BACAKSIZ E (2017). Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. Turkish Journal of Physics, 41(2), 160 - 170.
Chicago	POLAT ISMAIL,YILMAZ SALİH,TOMAKİN Murat,BACAKSIZ Emin Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. Turkish Journal of Physics 41, no.2 (2017): 160 - 170.
MLA	POLAT ISMAIL,YILMAZ SALİH,TOMAKİN Murat,BACAKSIZ Emin Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. Turkish Journal of Physics, vol.41, no.2, 2017, ss.160 - 170.
AMA	POLAT I,YILMAZ S,TOMAKİN M,BACAKSIZ E Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. Turkish Journal of Physics. 2017; 41(2): 160 - 170.
Vancouver	POLAT I,YILMAZ S,TOMAKİN M,BACAKSIZ E Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs. Turkish Journal of Physics. 2017; 41(2): 160 - 170.
IEEE	POLAT I,YILMAZ S,TOMAKİN M,BACAKSIZ E "Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs." Turkish Journal of Physics, 41, ss.160 - 170, 2017.
ISNAD	POLAT, ISMAIL vd. "Role of Mg doping in the structural, optical, and electrical characteristics of ZnO-based DSSCs". Turkish Journal of Physics 41/2 (2017), 160-170.