Yıl: 2017 Cilt: 5 Sayı: 3 Sayfa Aralığı: 10 - 18 Metin Dili: Türkçe İndeks Tarihi: 29-07-2022

Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi

Öz:
Demir ve alüminyum elektrotlar ile donatılmış elektrokoagülasyon prosesinin (EP) kullanıldığı çalışmada Reaktif Yellow 160 (RY160) boyarmaddesi giderimi üzerine başlangıç pH, akım yoğunluğu, iletkenlik ve elektroliz süresinin etkisi incelenmiştir. EP'de elektrot materyalinden bağımsız olarak yüksek renk giderim verimi elde edilmiştir. Optimum işletme şartları alüminyum elektrot kullanılması durumunda, pH = 5, akım yoğunluğu 100 A/m2, elektroliz süresi 10 dakika, iletkenlik 1000 µS/cm iken demir elektrot kullanılması durumunda pH = 7, akım yoğunluğu 200 A/m2, elektroliz süresi 5 dakika, iletkenlik 1000 µS/cm olarak belirlenmiştir. Renk giderim verimi alüminyum elektrot çifti için 2,3 kWsa/m3 enerji sarfiyatı ve 0,52 $/m3 toplam maliyetle %96,4 iken demir elektrot çifti için 1,7 kWsa/m3 enerji sarfiyatı ve 0,28 $/m3 toplam maliyetle %95,8 elde edilmiştir. Sonuçlar, demir elektrot kullanımının alüminyum elektrot ile karşılaştırıldığında RY160 boyarmaddesinin gideriminde daha ekonomik olduğunu göstermiştir.
Anahtar Kelime:

Decolorization of Reactive Yellow 160 Dye by Using Electrocoagulation

Öz:
The effect of initial pH, current density, conductivity and electrolysis time on Reactive Yellow 160 (RY160) dye removal was investigated by using electrocoagulation process (EC) equipped with iron and aluminum electrodes couple. High color removal efficiency was obtained independent of electrode materials in EC. Optimum operational conditions was determined as pH = 5, current density 100 A /m2, electrolysis time 10 min and conductivity 1000 ?S / cm for aluminum electrodes while it was pH = 7, current density 200 A/m2, electrolysis time 5 min and conductivity 1000 ?S/cm for iron electrodes. Color removal was 96.4% with 2.3 kWh/m3 energy consumption and 0.52 $/m3 operating cost for aluminum electrode while it was 95.8% with 1.7 kWh/m3 energy consumption and 0,28 $/m3 operating cost for iron electrode. The results show that, iron electrodes are more cost effective than aluminum electrodes in removal of RY160 dye.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • [1] M. A. Al-Ghouti, M. A. M. Khraisheh, S. J. Allen, and M. N. Ahmad, "The removal of dyes from textile wastewater: A study of the physical characteristics and adsorption mechanisms of diatomaceous earth," Journal of Environmental Management, vol. 69, no. 3, pp. 229-238, 2003.
  • [2] Y. Gunes, R. Atav, and O. Namirti, "Effectiveness of ozone in decolorization of reactive dye effluents depending on the dye chromophore," Textile Research Journal, vol. 82, no. 10, pp. 994- 1000, 2011.
  • [3] J. Blanco, F. Torrades, M. Morón, M. Brouta-Agnésa, and J. García-Montaño, "PhotoFenton and sequencing batch reactor coupled to photo-Fenton processes for textile wastewater reclamation: Feasibility of reuse in dyeing processes," Chemical Engineering Journal, vol. 240, pp. 469-475, 2014.
  • [4] Y. K. Ong, F. Y. Li, S. P. Sun, B. W. Zhao, C. Z. Liang, and T. S. Chung, "Nanofiltration hollow fiber membranes for textile wastewater treatment: Lab-scale and pilot-scale studies," Chemical Engineering Science, vol. 114, pp. 51-57, 2014.
  • [5] F. Ciner, S. K. A. Solmaz, T. Yonar, and G. E. Ustun, "Treatability studies on wastewater from textile dyeing factories in Bursa, Turkey," International Journal of Environment and Pollution, vol. 19, no. 4, pp. 403-407, 2003.
  • [6] Y. Uysal, D. Aktas, and Y. Caglar, "Determination of Colour removal efficiency of Lemna minor L. from industrial effluents," Journal of Environmental Protection and Ecology, vol. 15, no. 4, pp. 1718-1726, 2014.
  • [7] Z. Aksu and G. Dönmez, "Combined effects of molasses sucrose and reactive dye on the growth and dye bioaccumulation properties of Candida tropicalis," Process Biochemistry, vol. 40, no. 7, pp. 2443-2454, 2005.
  • [8] H. S. Rai, M. S. Bhattacharyya, J. Singh, T. K. Bansal, P. Vats, and U. C. Banerjee, "Removal of Dyes from the Effluent of Textile and Dyestuff Manufacturing Industry: A Review of Emerging Techniques With Reference to Biological Treatment," Critical Reviews in Environmental Science and Technology, vol. 35, no. 3, pp. 219-238, 2005.
  • [9] H. Kocyigit and A. Ugurlu, "Biological decolourization of reactive azo dye by anaerobic/aerobic sequencing batch reactor system," Global NEST journal, vol. 17, no. X, pp. 1-10, 2015.
  • [10] S. Ozdemir, K. Cirik, D. Akman, E. Sahinkaya, and O. Cinar, "Treatment of azo dyecontaining synthetic textile dye effluent using sulfidogenic anaerobic baffled reactor," Bioresource Technology, vol. 146, pp. 135-143, 2013.
  • [11] C. S. D. Rodrigues, L. M. Madeira, and R. A. R. Boaventura, "Treatment of textile dye wastewaters using ferrous sulphate in a chemical coagulation/flocculation process," Environmental Technology, vol. 34, no. 6, pp. 719-729, 2013.
  • [12] V. Golob, A. Vinder, and M. Simonic, "Efficiency of the coagulation/flocculation method for the treatment of dyebath effluents," Dyes and Pigments, vol. 67, no. 2, pp. 93-97, 2005.
  • [13] O. T. Can, M. Kobya, E. Demirbas, and M. Bayramoglu, "Treatment of the textile wastewater by combined electrocoagulation," Chemosphere, vol. 62, no. 2, 2006.
  • [14] S. Karthikeyan, A. Titus, A. Gnanamani, A. B. Mandal, and G. Sekaran, "Treatment of textile wastewater by homogeneous and heterogeneous Fenton oxidation processes," Desalination, vol. 281, no. 1, pp. 438-445, 2011.
  • [15] S. Şahinkaya, "COD and color removal from synthetic textile wastewater by ultrasound assisted electro-Fenton oxidation process," Journal of Industrial and Engineering Chemistry, vol. 19, no. 2, pp. 601-605, 2013.
  • [16] M. F. Sevimli and C. Kinaci, "Decolorization of textile wastewater by ozonation and Fenton's process," in Water Science and Technology, 2002, vol. 45, no. 12, pp. 279-286.
  • [17] N. Daneshvar, A. Oladegaragoze, and N. Djafarzadeh, "Decolorization of basic dye solutions by electrocoagulation: An investigation of the effect of operational parameters," Journal of Hazardous Materials, vol. 129, no. 1-3, pp. 116-122, 2006.
  • [18] M. Y. Mollah, R. Schennach, J. R. Parga, and D. L. Cocke, "Electrocoagulation (EC)--Science and Applications.," Journal of Hazardous Materials, vol. 84, no. 1, pp. 29-41, 2001.
  • [19] M. Y. A. Mollah, P. Morkovsky, J. A. G. Gomes, M. Kesmez, J. Parga, and D. L. Cocke, "Fundamentals, present and future perspectives of electrocoagulation," Journal of Hazardous Materials, vol. 114, no. 1-3. pp. 199-210, 2004.
  • [20] I. Arslan-alaton, M. Kobya, A. Akyol, and M. Bayramoglu, "Electrocoagulation of azo dye production wastewater with iron electrodes: Process evaluation by multi-response central composite design," Coloration Technology, vol. 125, no. 4, pp. 234-241, 2009.
  • [21] M. Kobya, E. Demirbas, O. T. Can, and M. Bayramoglu, "Treatment of levafix orange textile dye solution by electrocoagulation," Journal of Hazardous Materials, vol. 132, no. 2-3, 2006.
  • [22] O. T. Can, M. Kobya, E. Demirbas, and M. Bayramoglu, "Treatment of the textile wastewater by combined electrocoagulation," Chemosphere, vol. 62, no. 2, pp. 181-187, 2006.
  • [23] C. S. Keskin, A. Özdemir, and I. A. Şengil, "Simultaneous decolorization of binary mixture of reactive yellow and acid violet from wastewaters by electrocoagulation," Water Science and Technology, vol. 63, no. 8, pp. 1644-1650, 2011.
  • [24] H. A. Kabuk, Y. Avsar, F. Ilhan, and K. Ulucan, "Comparison of pH Adjustment and Electrocoagulation Processes on Treatability of Metal Plating Wastewater," Separation Science and Technology, vol. 49, no. 4, pp. 613-618, 2014.
  • [25] K. K. Dermentzis, A. Christoforidis, and E. Valsamidou, "Removal of nickel, copper, zinc and chromium from synthetic and industrial wastewater by electrocoagulation," International Journal of Environmental Sciences, vol. 1, no. 5, pp. 697-710, 2011.
  • [26] F. Akbal and S. Camci, "Comparison of electrocoagulation and chemical coagulation for heavy metal removal," Chemical Engineering and Technology, vol. 33, no. 10, pp. 1655-1664, 2010.
  • [27] Ü. Tezcan Ün, S. Ugur, A. S. Koparal, and Ü. Bakir Ögütveren, "Electrocoagulation of olive mill wastewaters," Separation and Purification Technology, vol. 52, no. 1, pp. 136-141, 2006.
  • [28] H. Inan, A. Dimoglo, H. Şimşek, and M. Karpuzcu, "Olive oil mill wastewater treatment by means of electro-coagulation," Separation and Purification Technology, vol. 36, no. 1, pp. 23-31, 2004.
  • [29] O. Apaydin, U. Kurt, and M. T. Gonullu, "An Investigation on the Treatment of Tannery Wastewater by Electrocoagulation," Water, vol. 11, no. 4, pp. 546-555, 2009.
  • [30] A. Deghles and U. Kurt, "Treatment of tannery wastewater by a hybrid electrocoagulation/electrodialysis process," Chemical Engineering and Processing: Process Intensification, vol. 104, pp. 43-50, 2016.
  • [31] M. Ugurlu, A. Gürses, Ç. Dogar, and M. Yalçin, "The removal of lignin and phenol from paper mill effluents by electrocoagulation," Journal of Environmental Management, vol. 87, no. 3, pp. 420-428, 2008.
  • [32] M. Kobya, E. Senturk, and M. Bayramoglu, "Treatment of poultry slaughterhouse wastewaters by electrocoagulation," Journal of Hazardous Materials, vol. 133, no. 1-3, pp. 172-176, 2006.
  • [33] C. Sarala, "Domestic Wastewater Treatment by Electrocoagulation with Fe-Fe Electrodes," International Journal of Engineering Trends and Technology, vol. 3, no. 4, pp. 530-533, 2012.
  • [34] S. Barişçi and O. Turkay, "Domestic greywater treatment by electrocoagulation using hybrid electrode combinations," Journal of Water Process Engineering, vol. 10, pp. 56-66, 2016.
  • [35] F. Ilhan, U. Kurt, O. Apaydin, and M. T. Gonullu, "Treatment of leachate by electrocoagulation using aluminum and iron electrodes," Journal of Hazardous Materials, vol. 154, no. 1-3, pp. 381-389, 2008.
  • [36] S. Top, E. Sekman, S. Hoşver, and M. S. Bilgili, "Characterization and electrocaogulative treatment of nanofiltration concentrate of a full-scale landfill leachate treatment plant," Desalination, vol. 268, no. 1-3, pp. 158-162, 2011.
  • [37] O. T. Can and M. Bayramoglu, "The effect of process conditions on the treatment of benzoquinone solution by electrocoagulation," Journal of Hazardous Materials, vol. 173, no. 1-3, pp. 731-736, 2010.
  • [38] M. Bayramoglu, M. Kobya, O. T. Can, and M. Sozbir, "Operating cost analysis of electrocoagulation of textile dye wastewater," Separation and Purification Technology, vol. 37, no. 2, pp. 117-125, 2004.
  • [39] E. Demirbas and M. Kobya, "Operating cost and treatment of metalworking fluid wastewater by chemical coagulation and electrocoagulation processes," Process Safety and Environmental Protection, vol. 105, pp. 79-90, 2017.
  • [40] I. A. Şengil, S. Kulaç, and M. Özacar, "Treatment of tannery liming drum wastewater by electrocoagulation," Journal of Hazardous Materials, vol. 167, no. 1-3, pp. 940-946, 2009.
  • [41] P. K. Holt, G. W. Barton, M. Wark, and C. A. Mitchell, "A quantitative comparison between chemical dosing and electrocoagulation," Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 211, no. 2-3, pp. 233-248, 2002.
APA AYGÜN A, EREN D (2017). Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. , 10 - 18.
Chicago AYGÜN Ahmet,EREN Doç. Dr. Beytullah Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. (2017): 10 - 18.
MLA AYGÜN Ahmet,EREN Doç. Dr. Beytullah Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. , 2017, ss.10 - 18.
AMA AYGÜN A,EREN D Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. . 2017; 10 - 18.
Vancouver AYGÜN A,EREN D Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. . 2017; 10 - 18.
IEEE AYGÜN A,EREN D "Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi." , ss.10 - 18, 2017.
ISNAD AYGÜN, Ahmet - EREN, Doç. Dr. Beytullah. "Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi". (2017), 10-18.
APA AYGÜN A, EREN D (2017). Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE, 5(3), 10 - 18.
Chicago AYGÜN Ahmet,EREN Doç. Dr. Beytullah Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE 5, no.3 (2017): 10 - 18.
MLA AYGÜN Ahmet,EREN Doç. Dr. Beytullah Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE, vol.5, no.3, 2017, ss.10 - 18.
AMA AYGÜN A,EREN D Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE. 2017; 5(3): 10 - 18.
Vancouver AYGÜN A,EREN D Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE. 2017; 5(3): 10 - 18.
IEEE AYGÜN A,EREN D "Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi." ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE, 5, ss.10 - 18, 2017.
ISNAD AYGÜN, Ahmet - EREN, Doç. Dr. Beytullah. "Elektrokoagülayon Yöntemiyle Reaktif Yellow 160 Boyar Maddesinin Giderimi". ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE 5/3 (2017), 10-18.