Yıl: 2018 Cilt: 6 Sayı: 1 Sayfa Aralığı: 17 - 24 Metin Dili: Türkçe DOI: 10.21541/apjes.290368 İndeks Tarihi: 04-02-2019

Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi

Öz:
Endüstriyel atık sular içerisinde tekstil atık suları çok çeşitli kimyasallar ve boyar maddeler içermelerinden dolayı dikkat çekmektedirler. Bu boyar maddeleri su kaynaklarına, ırmaklara ve denizlere arıtılmadan bırakıldıklarında suda yaşayan canlılar ve besin zinciri olumsuz etkilenmektedir. Bu zararlı etkilerin en aza indirilmesi için endüstriyel atık suların arıtılması canlılar için hayati önem taşımaktadır. Bu çalışmada, akrilik elyafların boyanmasında kullanılan iki farklı bazik karakterdeki tekstil boyar maddesi (Basic Blue 41-BB41 and Basic Red 46-BR46) farklı pH, süre, sıcaklık ve başlangıç boyar madde konsantrasyonlarında sülfonik asit esaslı polimerik membran ile çözelti ortamından % 75 ile % 100 aralığında boyar madde giderme yüzdesi ile giderildi. Gibbs serbest enerjisi (ΔG) değerleri BB41 ve BR46 boyar maddeleri için 318 K’de sırası ile -5.2 kj/mol ve -5,52 kj/mol olarak bulundu. Adsorpsiyon izotermleri incelendiğinde her iki boyar maddenin polimer membranına adsorpsiyonunun Freundlich izotermine uyduğu tespit edildi
Anahtar Kelime:

Konular: Kimya, Uygulamalı Polimer Bilimi Mühendislik, Kimya

Elimination of Basic Blue 41 ve Basic Red 46 Dyestuffs from Solution by Anionic Polymer Membrane

Öz:
Textile wastewaters in industrial wastewaters are attracting attention because of containing a various chemicals and dyestuffs. When these dyestuffs are discharge to water resources, rivers and seas, the aquatic life and food chain without any treatment are adversely affected. The treatment of industrial wastewater is vital for all living creatures to minimize these harmful effects. Two different basic dyestuffs (Basic Blue 41-BB41 and Basic Red 46-BR46), which are used to dyeing of acrylic fibers were removed from the solution with a sulfonic acid based polymeric membrane adsorbent at different pH, time, temperature and initial dyestuff concentration with 75% to 100% removal percentage range values in this study. The Gibbs free energy (ΔG) values were found to be -5.2 kJ/mol and -5.52 kJ/mol for the BB41 and BR 46 dyes, respectively, at 318 K. According to the adsorption isotherms, the adsorption of both dyestuffs on the polymer membrane were fit to the Freundlich isotherm
Anahtar Kelime:

Konular: Kimya, Uygulamalı Polimer Bilimi Mühendislik, Kimya
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA OZDOGAN TASCİ R, ÇELEBİ M (2018). Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. , 17 - 24. 10.21541/apjes.290368
Chicago OZDOGAN TASCİ REYHAN,ÇELEBİ Mithat Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. (2018): 17 - 24. 10.21541/apjes.290368
MLA OZDOGAN TASCİ REYHAN,ÇELEBİ Mithat Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. , 2018, ss.17 - 24. 10.21541/apjes.290368
AMA OZDOGAN TASCİ R,ÇELEBİ M Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. . 2018; 17 - 24. 10.21541/apjes.290368
Vancouver OZDOGAN TASCİ R,ÇELEBİ M Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. . 2018; 17 - 24. 10.21541/apjes.290368
IEEE OZDOGAN TASCİ R,ÇELEBİ M "Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi." , ss.17 - 24, 2018. 10.21541/apjes.290368
ISNAD OZDOGAN TASCİ, REYHAN - ÇELEBİ, Mithat. "Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi". (2018), 17-24. https://doi.org/10.21541/apjes.290368
APA OZDOGAN TASCİ R, ÇELEBİ M (2018). Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE, 6(1), 17 - 24. 10.21541/apjes.290368
Chicago OZDOGAN TASCİ REYHAN,ÇELEBİ Mithat Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE 6, no.1 (2018): 17 - 24. 10.21541/apjes.290368
MLA OZDOGAN TASCİ REYHAN,ÇELEBİ Mithat Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE, vol.6, no.1, 2018, ss.17 - 24. 10.21541/apjes.290368
AMA OZDOGAN TASCİ R,ÇELEBİ M Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE. 2018; 6(1): 17 - 24. 10.21541/apjes.290368
Vancouver OZDOGAN TASCİ R,ÇELEBİ M Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE. 2018; 6(1): 17 - 24. 10.21541/apjes.290368
IEEE OZDOGAN TASCİ R,ÇELEBİ M "Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi." ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE, 6, ss.17 - 24, 2018. 10.21541/apjes.290368
ISNAD OZDOGAN TASCİ, REYHAN - ÇELEBİ, Mithat. "Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi". ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE 6/1 (2018), 17-24. https://doi.org/10.21541/apjes.290368