Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation
Yıl: 2018 Cilt: 5 Sayı: 2 Sayfa Aralığı: 469 - 478 Metin Dili: İngilizce DOI: 10.18596/jotcsa.396618 İndeks Tarihi: 22-02-2020
Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation
Öz: A new polymerization mechanistic transformation strategy, combining two differenttechniques of controlled polymerization modes, namely atom transfer radical polymerization (ATRP)and photoinduced radical oxidation/addition/deactivation (PROAD), is effectively used for the blockcopolymers’ formation. Thus, mono- or bi- bromide functional polystyrenes (PS-Br or Br-PS-Br)synthesized by light-induced ATRP were used as a macroinitiator on isobutyl vinyl ether in the livingcationic polymerization via PROAD process to give the corresponding block copolymers. Thus,depending upon the macroinitiator’s surface, AB/ABA type block copolymers (PS-b-PIBVE or PIBVEb-PS-b-PIBVE) were formed. The final polymers and precursor polymers were characterized byspectral and chromatographic analyses.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
- Yagci Y, Atilla Tasdelen M. Mechanistic transformations involving living and controlled/living polymerization methods. Progress in Polymer Science. 2006;31(12):1133-70.
- Ciftci M, Arslan M, Buchmeiser M, Yagci Y. Polyethylene-g-Polystyrene Copolymers by Combination of ROMP, Mn2(CO)10-Assisted TEMPO Substitution and NMRP. ACS Macro Letters. 2016;5(8):946-9.
- Ciftci M, Norsic S, Boisson C, D'Agosto F, Yagci Y. Synthesis of Block Copolymers Based on Polyethylene by Thermally Induced Controlled Radical Polymerization Using Mn2(CO)10. Macromolecular Chemistry and Physics. 2015;216(9):958-63.
- Ciftci M, Kork S, Xu GJ, Buchmeiser MR, Yagci Y. Polyethylene-g-poly(cyclohexene oxide) by Mechanistic Transformation from ROMP to Visible Light-Induced Free Radical Promoted Cationic Polymerization. Macromolecules. 2015;48(6):1658-63.
- Ciftci M, Kork S, Xu G, Buchmeiser MR, Yagci Y. Polyethylene-g-poly(cyclohexene oxide) by Mechanistic Transformation from ROMP to Visible Light-Induced Free Radical Promoted Cationic Polymerization. Macromolecules. 2015;48(6):1658-63.
- Castle TC, Hutchings LR, Khosravi E. Synthesis of Block Copolymers by Changing Living Anionic Polymerization into Living Ring Opening Metathesis Polymerization. Macromolecules. 2004;37(6):2035-40.
- Yagci Y, Serhatli IE, Kubisa P, Biedron T. SYNTHESIS OF BLOCK COPOLYMERS BY COMBINATION OF AN ACTIVATED MONOMER AND FREE-RADICAL POLYMERIZATION MECHANISM. Macromolecules. 1993;26(10):2397-9.
- Hizal G, Yagci Y, Schnabel W. N-ALKOXY PYRIDINIUM ION TERMINATED POLYTETRAHYDROFURANS - SYNTHESIS AND THEIR USE IN PHOTOINITIATED BLOCK COPOLYMERIZATION. Polymer. 1994;35(20):4443- 8.
- Yagci Y, Onen A, Schnabel W. BLOCK COPOLYMERS BY COMBINATION OF RADICAL AND PROMOTED CATIONIC POLYMERIZATION ROUTES. Macromolecules. 1991;24(16):4620-3.
- Hizal G, Sarman A, Yagci Y. SYNTHESIS OF HYDROXY-TERMINATED POLYTETRAHYDROFURAN BY PHOTOINDUCED PROCESS. Polym Bull. 1995;35(5):567-73.
- Kahveci MU, Acik G, Yagci Y. Synthesis of Block Copolymers by Combination of Atom Transfer Radical Polymerization and Visible Light-Induced Free Radical Promoted Cationic Polymerization. Macromol Rapid Commun. 2012;33(4):309-13.
- Studer A, Schulte T. Nitroxide-mediated radical processes. Chemical Record. 2005;5(1):27-35.
- Acik G, Kahveci MU, Yagci Y. Synthesis of Block Copolymers by Combination of Atom Transfer Radical Polymerization and Visible Light Radical Photopolymerization Methods. Macromolecules. 2010;43(21):9198- 201.
- Degirmenci M, Toprak A. Synthesis of block copolymers by transformation of free radical promoted cationic polymerization to atom transfer radical polymerization C. Polym J. 2005;37(9):700-6.
- Yagci Y, Schnabel W. LIGHT-INDUCED SYNTHESIS OF BLOCK AND GRAFT-COPOLYMERS. Prog Polym Sci. 1990;15(4):551-601.
- Murtezi E, Ciftci M, Yagci Y. Synthesis of clickable hydrogels and linear polymers by type II photoinitiation. Polymer International. 2015;64(5):588-94.
- Aydogan C, Ciftci M, Yagci Y. Hyperbranched Polymers by Type II Photoinitiated Self-Condensing Vinyl Polymerization. Macromol Rapid Commun. 2016;37(7):650-4.
- Aydogan C, Ciftci M, Kumbaraci V, Talinli N, Yagci Y. Hyperbranced Polymers by Photoinduced Self- Condensing Vinyl Polymerization Using Bisbenzodioxinone. Macromolecular Chemistry and Physics. 2017;218(10):6.
- Pan X, Tasdelen MA, Laun J, Junkers T, Yagci Y, Matyjaszewski K. Photomediated controlled radical polymerization. Progress in Polymer Science. 2016;62:73-125.
- Liu G, Shi H, Cui Y, Tong J, Zhao Y, Wang D, et al. Toward rapid aqueous RAFT polymerization of primary amine functional monomer under visible light irradiation at 25 [degree]C. Polymer Chemistry. 2013;4(4):1176-82.
- Guillaneuf Y, Bertin D, Gigmes D, Versace D-L, Lalevée J, Fouassier J-P. Toward Nitroxide-Mediated Photopolymerization. Macromolecules. 2010;43(5):2204-12.
| APA | ÇİFTÇİ M (2018). Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. , 469 - 478. 10.18596/jotcsa.396618 |
| Chicago | ÇİFTÇİ Mustafa Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. (2018): 469 - 478. 10.18596/jotcsa.396618 |
| MLA | ÇİFTÇİ Mustafa Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. , 2018, ss.469 - 478. 10.18596/jotcsa.396618 |
| AMA | ÇİFTÇİ M Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. . 2018; 469 - 478. 10.18596/jotcsa.396618 |
| Vancouver | ÇİFTÇİ M Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. . 2018; 469 - 478. 10.18596/jotcsa.396618 |
| IEEE | ÇİFTÇİ M "Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation." , ss.469 - 478, 2018. 10.18596/jotcsa.396618 |
| ISNAD | ÇİFTÇİ, Mustafa. "Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation". (2018), 469-478. https://doi.org/10.18596/jotcsa.396618 |
| APA | ÇİFTÇİ M (2018). Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(2), 469 - 478. 10.18596/jotcsa.396618 |
| Chicago | ÇİFTÇİ Mustafa Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. Journal of the Turkish Chemical Society, Section A: Chemistry 5, no.2 (2018): 469 - 478. 10.18596/jotcsa.396618 |
| MLA | ÇİFTÇİ Mustafa Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. Journal of the Turkish Chemical Society, Section A: Chemistry, vol.5, no.2, 2018, ss.469 - 478. 10.18596/jotcsa.396618 |
| AMA | ÇİFTÇİ M Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(2): 469 - 478. 10.18596/jotcsa.396618 |
| Vancouver | ÇİFTÇİ M Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(2): 469 - 478. 10.18596/jotcsa.396618 |
| IEEE | ÇİFTÇİ M "Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation." Journal of the Turkish Chemical Society, Section A: Chemistry, 5, ss.469 - 478, 2018. 10.18596/jotcsa.396618 |
| ISNAD | ÇİFTÇİ, Mustafa. "Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation". Journal of the Turkish Chemical Society, Section A: Chemistry 5/2 (2018), 469-478. https://doi.org/10.18596/jotcsa.396618 |
