Mustafa ÇİFTÇİ
(Bursa Teknik Üniversitesi, Doğa Bilimleri Mimarlık Ve Mühendislik Fakültesi, Kimya Bölümü, Bursa, Türkiye)
Yıl: 2018Cilt: 5Sayı: 2ISSN: 2149-0120 / 2149-0120Sayfa Aralığı: 469 - 478İngilizce

34 0
Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation
A new polymerization mechanistic transformation strategy, combining two different techniques of controlled polymerization modes, namely atom transfer radical polymerization (ATRP) and photoinduced radical oxidation/addition/deactivation (PROAD), is effectively used for the block copolymers’ formation. Thus, mono- or bi- bromide functional polystyrenes (PS-Br or Br-PS-Br) synthesized by light-induced ATRP were used as a macroinitiator on isobutyl vinyl ether in the living cationic polymerization via PROAD process to give the corresponding block copolymers. Thus, depending upon the macroinitiator’s surface, AB/ABA type block copolymers (PS-b-PIBVE or PIBVEb- PS-b-PIBVE) were formed. The final polymers and precursor polymers were characterized by spectral and chromatographic analyses.
Fen > Temel Bilimler > Kimya, Analitik
Fen > Temel Bilimler > Kimya, Uygulamalı
Fen > Temel Bilimler > Kimya, İnorganik ve Nükleer
Fen > Temel Bilimler > Kimya, Tıbbi
Fen > Temel Bilimler > Kimya, Organik
Fen > Temel Bilimler > Fizikokimya
Fen > Temel Bilimler > Spektroskopi
Fen > Temel Bilimler > Termodinamik
DergiAraştırma MakalesiErişime Açık
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