Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies

Hilmi Arkut AKALIN, (Manisa Celal Bayar Üniversitesi, Fen Bilimleri Enstitüsü, Manisa, Türkiye)
Ümran HİÇSÖNMEZ, (Manisa Celal Bayar Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Manisa, Türkiye)
Hatice YILMAZ (Dokuz Eylül Üniversitesi, Mühendislik Fakültesi, Maden Mühendisliği Bölümü, İzmir, Türkiye)
Journal of the Turkish Chemical Society, Section A: Chemistry
3 0
Yıl: 2018 Cilt: 5 Sayı: 1 Sayfa Aralığı: 85 - 115 Metin Dili: İngilizce DOI: 10.18596/jotcsa.317771 İndeks Tarihi: 26-02-2020

Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies

Öz:
In this study, cesium adsorption performance of raw vermiculite obtained from Sivas-Yıldızeli region of Turkey was investigated using batch adsorption method. In order to obtain theoptimum adsorption conditions; different adsorbent dosages, contact times, solution pH’s, initialcesium concentrations and temperature ranges were investigated. The concentration of cesiumin solution was determined by ICP-OES. Kinetic studies demonstrated that adsorption processwas in accordance with pseudo-second order kinetic model and equilibrium isotherm modelingstudies showed that the process was compatible with Langmuir, Freundlich and Temkinadsorption isotherm models, indicating that Cs adsorption process had both physical andchemical character. Negative Gibbs energy values obtained from thermodynamic studiesrevealed that the adsorption process was spontaneous and had a high feasibility. Additionally,the negative enthalpy value indicated that process was exothermic, suggesting that the adsorbedCs+ ions decreased with increasing reaction temperatures. Positive entropy value showed thatdisorderliness between solid-liquid phase increased during adsorption. Results clearly indicatethat vermiculite mineral has a promising potential in removing Cs+ ions from aqueous mediawhich leads mineral may also be used in decomposing and efficiently removing radioactivecesium from contaminated waters.
Anahtar Kelime:

Konular: Kimya, Analitik Termodinamik Spektroskopi Kimya, Uygulamalı Kimya, Organik Kimya, Tıbbi Fizikokimya Kimya, İnorganik ve Nükleer
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA AKALIN H, HİÇSÖNMEZ Ü, YILMAZ H (2018). Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. , 85 - 115. 10.18596/jotcsa.317771
Chicago AKALIN Hilmi Arkut,HİÇSÖNMEZ Ümran,YILMAZ HATICE Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. (2018): 85 - 115. 10.18596/jotcsa.317771
MLA AKALIN Hilmi Arkut,HİÇSÖNMEZ Ümran,YILMAZ HATICE Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. , 2018, ss.85 - 115. 10.18596/jotcsa.317771
AMA AKALIN H,HİÇSÖNMEZ Ü,YILMAZ H Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. . 2018; 85 - 115. 10.18596/jotcsa.317771
Vancouver AKALIN H,HİÇSÖNMEZ Ü,YILMAZ H Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. . 2018; 85 - 115. 10.18596/jotcsa.317771
IEEE AKALIN H,HİÇSÖNMEZ Ü,YILMAZ H "Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies." , ss.85 - 115, 2018. 10.18596/jotcsa.317771
ISNAD AKALIN, Hilmi Arkut vd. "Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies". (2018), 85-115. https://doi.org/10.18596/jotcsa.317771
APA AKALIN H, HİÇSÖNMEZ Ü, YILMAZ H (2018). Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(1), 85 - 115. 10.18596/jotcsa.317771
Chicago AKALIN Hilmi Arkut,HİÇSÖNMEZ Ümran,YILMAZ HATICE Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. Journal of the Turkish Chemical Society, Section A: Chemistry 5, no.1 (2018): 85 - 115. 10.18596/jotcsa.317771
MLA AKALIN Hilmi Arkut,HİÇSÖNMEZ Ümran,YILMAZ HATICE Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. Journal of the Turkish Chemical Society, Section A: Chemistry, vol.5, no.1, 2018, ss.85 - 115. 10.18596/jotcsa.317771
AMA AKALIN H,HİÇSÖNMEZ Ü,YILMAZ H Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(1): 85 - 115. 10.18596/jotcsa.317771
Vancouver AKALIN H,HİÇSÖNMEZ Ü,YILMAZ H Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(1): 85 - 115. 10.18596/jotcsa.317771
IEEE AKALIN H,HİÇSÖNMEZ Ü,YILMAZ H "Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies." Journal of the Turkish Chemical Society, Section A: Chemistry, 5, ss.85 - 115, 2018. 10.18596/jotcsa.317771
ISNAD AKALIN, Hilmi Arkut vd. "Removal of Cesium from Aqueous Solution by Adsorption onto Sivas- Yildizeli (Türkiye) Vermiculite: Equilibrium, Kinetic and Thermodynamic Studies". Journal of the Turkish Chemical Society, Section A: Chemistry 5/1 (2018), 85-115. https://doi.org/10.18596/jotcsa.317771
Sayfa Oluşturulma Tarihi
23-04-2024 10:37

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