A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure

SEMERCİ, Fatih

doi:10.18596/jotcsa.355518

A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure

Fatih SEMERCİ (Kırklareli Üniversitesi)

Journal of the Turkish Chemical Society, Section A: Chemistry

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Yıl: 2018 Cilt: 5 Sayı: 3 Sayfa Aralığı: 1083 - 1094 Metin Dili: İngilizce DOI: 10.18596/jotcsa.355518 İndeks Tarihi: 29-02-2020

A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure

Öz:

A new thermally highly stable 2D coordination polymer, formulated as [Co(μ6-abtc)0.5(μ-obix)]n (abtc = dioxygenated form of 3,3′,5,5′-azobenzenetetracarboxylate) obtained employing thesemi-flexible 1,2-bis(imidazole-1-ylmethyl)benzene (obix) linker in hydro(solvo)thermal method.The complex was characterized by various techniques such as IR spectroscopy, elemental analysis,single crystal and powder crystal analysis. Crystallographic study of complex 1 reveal that twometal(II) ions are linked by O atoms of carboxylate groups of abtc ligand to build paddle-wheel SBU(secondary building unit). These SBUs are stabilized by the connection of obix ligand. The Co(II) ionsare μ6-bridged by hexadentate abtc ligand to generate 2D polymer layers with 3,4-connected binodalnet (point symbol ${4.62}2{42.62.82})$ and topological type is 3,4L13. Thermal analysis shows thatcomplex 1 thermally stable up to 401 °C.

Anahtar Kelime:

Konular: Kimya, Analitik Termodinamik Spektroskopi Kimya, Uygulamalı Kimya, Organik Kimya, Tıbbi Fizikokimya Kimya, İnorganik ve Nükleer

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	SEMERCİ F (2018). A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. , 1083 - 1094. 10.18596/jotcsa.355518
Chicago	SEMERCİ Fatih A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. (2018): 1083 - 1094. 10.18596/jotcsa.355518
MLA	SEMERCİ Fatih A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. , 2018, ss.1083 - 1094. 10.18596/jotcsa.355518
AMA	SEMERCİ F A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. . 2018; 1083 - 1094. 10.18596/jotcsa.355518
Vancouver	SEMERCİ F A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. . 2018; 1083 - 1094. 10.18596/jotcsa.355518
IEEE	SEMERCİ F "A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure." , ss.1083 - 1094, 2018. 10.18596/jotcsa.355518
ISNAD	SEMERCİ, Fatih. "A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure". (2018), 1083-1094. https://doi.org/10.18596/jotcsa.355518

APA	SEMERCİ F (2018). A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(3), 1083 - 1094. 10.18596/jotcsa.355518
Chicago	SEMERCİ Fatih A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. Journal of the Turkish Chemical Society, Section A: Chemistry 5, no.3 (2018): 1083 - 1094. 10.18596/jotcsa.355518
MLA	SEMERCİ Fatih A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. Journal of the Turkish Chemical Society, Section A: Chemistry, vol.5, no.3, 2018, ss.1083 - 1094. 10.18596/jotcsa.355518
AMA	SEMERCİ F A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(3): 1083 - 1094. 10.18596/jotcsa.355518
Vancouver	SEMERCİ F A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(3): 1083 - 1094. 10.18596/jotcsa.355518
IEEE	SEMERCİ F "A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure." Journal of the Turkish Chemical Society, Section A: Chemistry, 5, ss.1083 - 1094, 2018. 10.18596/jotcsa.355518
ISNAD	SEMERCİ, Fatih. "A New Highly Thermally Stable Co(II)-coordination polymer with Semi-flexible Bis(Imidazole) Directed Secondary Building Unit: Solvothermal Synthesis and Structure". Journal of the Turkish Chemical Society, Section A: Chemistry 5/3 (2018), 1083-1094. https://doi.org/10.18596/jotcsa.355518