Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes
Yıl: 2018 Cilt: 5 Sayı: 3 Sayfa Aralığı: 1249 - 1256 Metin Dili: İngilizce DOI: 10.18596/jotcsa.381305 İndeks Tarihi: 29-02-2020
Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes
Öz: The preparation of multi-walled carbon nanotubes (MW-CNTs) supported Cu and Pdnanoparticles utilizing a supercritical carbon dioxide (scCO2) deposition method were investigated. Novelvic-dioxime complexes of Cu(II) and Pd(II) were used as metallic precursors. The ligand used in theseprecursors was 4-(trifluoromethyl)aniline-vic-dioxide. Ligand and metal complexes were synthesized andidentified with various analysis methods including 1H and 19F NMR, FT-IR, UV-Vis, elemental analysis andmagnetic susceptibility. MW-CNTs supported Pd and Cu nanoparticles were characterized by high-resolutiontransmission electron microscopy (HR-TEM), X-ray diffraction (XRD) and scanning electron microscopy withEDX (SEM-EDX). SEM-EDX and HR-TEM micrographs showed a homogenous distribution of reasonably welldispersedCu and Pd nanoparticles on the support. The nature and crystallinity of the nano metal particleswere confirmed using XRD. Crystallite sizes ranged from 7-20 nm for palladium and 20-30 nm for copper.This study demonstrated that these oxime complexes are suitable precursors for the preparation ofsupported nanoparticles using a supercritical carbon dioxide deposition method.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | ULUSAL F, Güzel B (2018). Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. , 1249 - 1256. 10.18596/jotcsa.381305 |
| Chicago | ULUSAL Fatma,Güzel Bilgehan Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. (2018): 1249 - 1256. 10.18596/jotcsa.381305 |
| MLA | ULUSAL Fatma,Güzel Bilgehan Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. , 2018, ss.1249 - 1256. 10.18596/jotcsa.381305 |
| AMA | ULUSAL F,Güzel B Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. . 2018; 1249 - 1256. 10.18596/jotcsa.381305 |
| Vancouver | ULUSAL F,Güzel B Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. . 2018; 1249 - 1256. 10.18596/jotcsa.381305 |
| IEEE | ULUSAL F,Güzel B "Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes." , ss.1249 - 1256, 2018. 10.18596/jotcsa.381305 |
| ISNAD | ULUSAL, Fatma - Güzel, Bilgehan. "Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes". (2018), 1249-1256. https://doi.org/10.18596/jotcsa.381305 |
| APA | ULUSAL F, Güzel B (2018). Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(3), 1249 - 1256. 10.18596/jotcsa.381305 |
| Chicago | ULUSAL Fatma,Güzel Bilgehan Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. Journal of the Turkish Chemical Society, Section A: Chemistry 5, no.3 (2018): 1249 - 1256. 10.18596/jotcsa.381305 |
| MLA | ULUSAL Fatma,Güzel Bilgehan Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. Journal of the Turkish Chemical Society, Section A: Chemistry, vol.5, no.3, 2018, ss.1249 - 1256. 10.18596/jotcsa.381305 |
| AMA | ULUSAL F,Güzel B Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(3): 1249 - 1256. 10.18596/jotcsa.381305 |
| Vancouver | ULUSAL F,Güzel B Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(3): 1249 - 1256. 10.18596/jotcsa.381305 |
| IEEE | ULUSAL F,Güzel B "Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes." Journal of the Turkish Chemical Society, Section A: Chemistry, 5, ss.1249 - 1256, 2018. 10.18596/jotcsa.381305 |
| ISNAD | ULUSAL, Fatma - Güzel, Bilgehan. "Green Preparation of Multiwalled Carbon Nanotubes-Supported Pd and Cu Nanoparticles with Novel Vic-dioxime Metal Complexes". Journal of the Turkish Chemical Society, Section A: Chemistry 5/3 (2018), 1249-1256. https://doi.org/10.18596/jotcsa.381305 |
