Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.

FELIX, Nworie; EMEKA, İtumoh; ANSELM, Ogah; IKELLE, İkelle; CLİNTON, Oroke; NWABUEZE, Elom; N, Illochi; IENNA, Nwabue

doi:10.18596/jotcsa.438332

Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.

Nworie FELIX, (Ebonyi State University)

Nwabue IENNA, (Ebonyi State University)

İkelle IKELLE, (Ebonyi State University)

Ogah ANSELM, (Ebonyi State University)

Elom NWABUEZE, (Ebonyi State University)

Illochi N, (Evangel University)

İtumoh EMEKA, (Ebonyi State University)

Oroke CLİNTON (Ebonyi State University)

Journal of the Turkish Chemical Society, Section A: Chemistry

4 0

Yıl: 2018 Cilt: 5 Sayı: 3 Sayfa Aralığı: 1257 - 1270 Metin Dili: İngilizce DOI: 10.18596/jotcsa.438332 İndeks Tarihi: 29-02-2020

Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.

Öz:

Plantain peel biomass was carbonized, activated, and characterized using BET surface area andXRD. The XRD diffraction indicated crystalline structure with crystallite size of 14.56 nm evaluated throughDebye-Scherrer equation. The pore size (cc/g) and pore surface area (m2/g) of the biochar was 8.79 and 16.69respectively from BET surface area. Various parametric properties such as effect of initial metal ionconcentration, pH, and contact time were studied in a batch reaction process. Adsorption of zinc from aqueoussolution decreased with an increase of pH and initial concentration. Equilibrium modeling studies suggestedthat the data fitted mainly to the Langmuir isotherm. Adsorption kinetic data tested using various kineticmodels fitted the Bangham’s pore diffusion model implicating pore diffusion as the main rate limiting step. Thesorption studies indicated the potential of plantain peel biochar as an effective, efficient and low cost adsorbentfor remediating zinc (II) ions contaminated environment.

Anahtar Kelime:

Konular: Kimya, Analitik Termodinamik Spektroskopi Kimya, Uygulamalı Kimya, Organik Kimya, Tıbbi Fizikokimya Kimya, İnorganik ve Nükleer

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

1. Oberio HS, Vadlani P V, Saida L, Hughes J D. Ethanol production from plantain peels using statistically optimized simultaneous saccharification and fermentation process. Waste Management. 2011; 31: 1576-85.
2. Onyebado CO, Iyagba ET, Offor OJ. Solid soap production using plantain peels ash as source of alkali. Journal of Applied Science and Environmental Management.2004; 6: 73-7.
3. Mitani N, Jian FM. Uptake system of silicon in different plant species. J. Exp. Bot. 2005; 56 (414): 1255–61.
4. Uchimiya M, Chang S, Klasson KT. Screening biochars for heavy metal retention in soil: Role of oxygen functional groups. J. Haz. Mat. 2011; 190 (1-3): 432-41.
5. Betiku E, Sheriff O A. Modeling and optimization of Thevetiaperuviana (yellow oleander) oil biodiesel synthetic via Musa paradisiacal (plantain) peels as heterogeneous base catalyst: A case of artificial neural network vs. response surface methodology. Ind. crop. prod. 2014; 53: 314-22.
6. Wolfe K, Wu K, Liu RH. Antioxidant activity of apple peels. J. Agric. Food Chem. 2003; 51:609- 14.
7. Ismail S, Khan F, Zafar- Iqbal M. Phytoremediation: Assessing tolerance of tree species against trace metal (Pb and Cd) toxicity. Pakistan J Botany. 2013; 45: 2181-6.
8. Parizanganeh AH, Bijnavand V, Zamani AA, Hajabolfath A. Concentration, distribution and comparison of total and bioavailable trace metals in top soils of Bonab district in Zanjan province. Open J. Soil Sci. 2012; 2: 123-32.
9. Dada AO, Ojediran JO, Olalekan AP. Sorption of Pb2+ from aqueous solution unto modified rice husk: isotherm studies. Adv Chem Phys. 2013: 1– 6 (id: 842425).
10. Babel S, Kurniawan TA. Low-cost adsorbents for heavy metals uptake from contaminated water: a review. J Hazard Mater. 2003; 97(1–3): 219–43.
11. Komkiene J, Baltrenaite E. Biochar as adsorbent for removal of heavy metal ions [Cadmium(II), Copper (II), Lead(II), Zinc(II) from aqueous phase. Int. J. Environ. Sci. Technol. 2016; 13: 471-82.
12. Inyang M, Cao B, Pullammannappallil P, Zimmerman A R. Enhanced lead sorption by biochar derived from anaerobically digested sugarcane bagasse. Sep. Sci. Technol. 2011; 46(12): 1950-6.
13. Tiwari LD, Lee S. Activated carbon and manganese coated activated carbon precursor to dead biomass in the remediation of arsenic contaminated water. Environmental Engineering Research. 2012; 17:541-8.
14. Prasad AS. Zinc deficiency by global health organization. British Medical Journal. 2003; 326 (7386): 409-10.
15. Jindapon W, Jaiyen S, Ngamcharussrivichai C. Al2O3-supported Mixed Ca and Zn Compounds Prepared from Waste Seashells for Synthesis of Palm Fatty Acid Methyl Esters, Chemical Engineering Communications. 2015; 202: 1591–9.
16. Morin TJ, Chengeto SW, Makura V, Tatlock HM, Lindeman SV, Bennett B, Long GJ, Grandjean F, Gardinier JR. Pyrazolylmethyls prescribe the electronic properties of iron(II) tetra(pyrazolyl)lutidine chloride complexes, Dalton Trans. 2011; 40: 8024–34.
17. Zhou Y, Gao B, Zimmerman AR, Cao X. Biocharsupported zerovalent iron reclaims silver from aqueous solution to form antimicrobial nanocomposite. Chemosphere. 2014; 117: 801-5.
18. Demirbas A. Effects of temperature and particle size on biochar yield from pyrolysis of agricultural residues. Journal of Analytical and Applied Pyrolysis. 2003; 72: 243-8.
19. Thavamani SS, Rajkumar R. Removal of Cr(II), Pb(II) and Ni(II) from aqueous solution by adsorption on alumina. Res. J. Chem. Sci. 2013; 3(8): 44-8.
20. Okareh OT, Adeolu AT. Removal of Lead ion from industrial effluent using plantain wastes. Br. J. App. Sci. Technol. 2015; 8(3): 267-276.
21. Cao XD, Ma L, Gao B, Harris W. Dairy manure derived biochar effectively sorbs lead and atrazine. Environ. Sci. Technol. 2009; 43(9): 3285-91.
22. Mazhar IK, Saima QM, Sajida P, Muhammed YK. Citrus paradise: An effective bio-adsorbent for arsenic(V) remediation. Pak. J. Anal. Environ. Chem. 2014; 15(1): 35-41.
23. Farouq R, Yousef NS. Equilibrium and Kinetics Studies of Adsorption of Copper (II) Ions on Natural Biosorbent. Int. J. Chem. Eng. Appl. 2015; 6: 319- 24.
24. Chakrapani CH, SureshBabu CH, Vani KNK, Somasekhara Rao K. Adsorption kinetics for the removal of fluoride from aqueous solution by activated carbon adsorbents derived from the peels of selected citrus fruits.. E- journal of chemistry. 2010; 7(SI): S419-27.
25. Antonija k, Natlija V, Dam H, Davor K. Lignocellulosic materials as dye adsorbents: Adsorption of methylene blue and congo red on brewers spent grain. Croat. Chim. Acta, 2018; 91: 53-64.
26. Panida S, Xianshe F. Kinetic models on chromium(VI) adsorption onto carbonized oil palm kernel with potassium hydroxide activation. Intl J. Adv. Chem. Eng. Biol. Sci. 2016; 3(1): 68-75.
27. Erol K. The adsorption of calmoduline via nicotinamide immobilized poly(HEMA-GMA) cryogels. JOTCSA. 2017; 4(1): 133-48.
28. Yildiz A. Adsorption of Acid Red 114 onto Fe3O4 at Caffeic acid recyclable magnetic nanocomposite. JOTCSA. 2017; 4(1): 327-40.

APA	FELIX N, IENNA N, IKELLE İ, ANSELM O, NWABUEZE E, N I, EMEKA İ, CLİNTON O (2018). Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. , 1257 - 1270. 10.18596/jotcsa.438332
Chicago	FELIX Nworie,IENNA Nwabue,IKELLE İkelle,ANSELM Ogah,NWABUEZE Elom,N Illochi,EMEKA İtumoh,CLİNTON Oroke Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. (2018): 1257 - 1270. 10.18596/jotcsa.438332
MLA	FELIX Nworie,IENNA Nwabue,IKELLE İkelle,ANSELM Ogah,NWABUEZE Elom,N Illochi,EMEKA İtumoh,CLİNTON Oroke Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. , 2018, ss.1257 - 1270. 10.18596/jotcsa.438332
AMA	FELIX N,IENNA N,IKELLE İ,ANSELM O,NWABUEZE E,N I,EMEKA İ,CLİNTON O Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. . 2018; 1257 - 1270. 10.18596/jotcsa.438332
Vancouver	FELIX N,IENNA N,IKELLE İ,ANSELM O,NWABUEZE E,N I,EMEKA İ,CLİNTON O Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. . 2018; 1257 - 1270. 10.18596/jotcsa.438332
IEEE	FELIX N,IENNA N,IKELLE İ,ANSELM O,NWABUEZE E,N I,EMEKA İ,CLİNTON O "Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.." , ss.1257 - 1270, 2018. 10.18596/jotcsa.438332
ISNAD	FELIX, Nworie vd. "Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.". (2018), 1257-1270. https://doi.org/10.18596/jotcsa.438332

APA	FELIX N, IENNA N, IKELLE İ, ANSELM O, NWABUEZE E, N I, EMEKA İ, CLİNTON O (2018). Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(3), 1257 - 1270. 10.18596/jotcsa.438332
Chicago	FELIX Nworie,IENNA Nwabue,IKELLE İkelle,ANSELM Ogah,NWABUEZE Elom,N Illochi,EMEKA İtumoh,CLİNTON Oroke Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. Journal of the Turkish Chemical Society, Section A: Chemistry 5, no.3 (2018): 1257 - 1270. 10.18596/jotcsa.438332
MLA	FELIX Nworie,IENNA Nwabue,IKELLE İkelle,ANSELM Ogah,NWABUEZE Elom,N Illochi,EMEKA İtumoh,CLİNTON Oroke Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. Journal of the Turkish Chemical Society, Section A: Chemistry, vol.5, no.3, 2018, ss.1257 - 1270. 10.18596/jotcsa.438332
AMA	FELIX N,IENNA N,IKELLE İ,ANSELM O,NWABUEZE E,N I,EMEKA İ,CLİNTON O Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(3): 1257 - 1270. 10.18596/jotcsa.438332
Vancouver	FELIX N,IENNA N,IKELLE İ,ANSELM O,NWABUEZE E,N I,EMEKA İ,CLİNTON O Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(3): 1257 - 1270. 10.18596/jotcsa.438332
IEEE	FELIX N,IENNA N,IKELLE İ,ANSELM O,NWABUEZE E,N I,EMEKA İ,CLİNTON O "Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.." Journal of the Turkish Chemical Society, Section A: Chemistry, 5, ss.1257 - 1270, 2018. 10.18596/jotcsa.438332
ISNAD	FELIX, Nworie vd. "Activated Plantain Peel Biochar As Adsorbent For Sorption of Zinc(II) Ions: Equilibrium and Kinetics Studies.". Journal of the Turkish Chemical Society, Section A: Chemistry 5/3 (2018), 1257-1270. https://doi.org/10.18596/jotcsa.438332