Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption

KIRBIYIK, Çisem

doi:10.3906/kim-1810-32

Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption

Çisem KIRBIYIK (Konya Teknik Üniversitesi)

Turkish Journal of Chemistry

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Yıl: 2019 Cilt: 43 Sayı: 2 Sayfa Aralığı: 687 - 704 Metin Dili: İngilizce DOI: 10.3906/kim-1810-32 İndeks Tarihi: 08-05-2020

Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption

Öz:

Magnetic and nonmagnetic activated carbons (ACs) were successfully prepared by using AC obtained fromspent coffee grounds (SCGs) for use in CO2 and CH4 capture. SCGs were activated by chemical activation to produce ACs and a magnetic α-Fe 2 O3 /AC composite was prepared by coprecipitation method from the ACs produced. Magnetic and nonmagnetic samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy dispersive X-ray spectrometry (EDX) techniques. The textural properties of samples were determined by nitrogen adsorption-desorption using the Brunauer–Emmett–Teller (BET) and Barrett–Joyner–Halenda (BJH) methods. The results showed that the porosity of AC was not blocked by αFe 2 O3 particles. According to adsorption-desorption experiments, the best results were obtained with the magnetic α-Fe 2 O3 /AC sample (1.68 mmol g −1 for CO2 and 0.65 mmol g −1for CH4) at 0 °C and 120 kPa. Adsorption performances were evaluated using four isotherm models. The isosteric heats of adsorption calculated for both adsorbents were smaller than 80 kJ/mol and it revealed that CO2 and CH4 adsorption is dominated by the physical adsorption. The α-Fe 2 O3 /AC multicycle CO2 adsorption tests showed that it can be successfully regenerated with high sorption capacity. The α-Fe 2 O3 /AC composite is a promising adsorbent for potential application.

Anahtar Kelime:

Konular: Kimya, Analitik Kimya, Uygulamalı Kimya, Organik Kimya, Tıbbi Mühendislik, Kimya Kimya, İnorganik ve Nükleer

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	KIRBIYIK Ç (2019). Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. , 687 - 704. 10.3906/kim-1810-32
Chicago	KIRBIYIK Çisem Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. (2019): 687 - 704. 10.3906/kim-1810-32
MLA	KIRBIYIK Çisem Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. , 2019, ss.687 - 704. 10.3906/kim-1810-32
AMA	KIRBIYIK Ç Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. . 2019; 687 - 704. 10.3906/kim-1810-32
Vancouver	KIRBIYIK Ç Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. . 2019; 687 - 704. 10.3906/kim-1810-32
IEEE	KIRBIYIK Ç "Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption." , ss.687 - 704, 2019. 10.3906/kim-1810-32
ISNAD	KIRBIYIK, Çisem. "Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption". (2019), 687-704. https://doi.org/10.3906/kim-1810-32

APA	KIRBIYIK Ç (2019). Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. Turkish Journal of Chemistry, 43(2), 687 - 704. 10.3906/kim-1810-32
Chicago	KIRBIYIK Çisem Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. Turkish Journal of Chemistry 43, no.2 (2019): 687 - 704. 10.3906/kim-1810-32
MLA	KIRBIYIK Çisem Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. Turkish Journal of Chemistry, vol.43, no.2, 2019, ss.687 - 704. 10.3906/kim-1810-32
AMA	KIRBIYIK Ç Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. Turkish Journal of Chemistry. 2019; 43(2): 687 - 704. 10.3906/kim-1810-32
Vancouver	KIRBIYIK Ç Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption. Turkish Journal of Chemistry. 2019; 43(2): 687 - 704. 10.3906/kim-1810-32
IEEE	KIRBIYIK Ç "Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption." Turkish Journal of Chemistry, 43, ss.687 - 704, 2019. 10.3906/kim-1810-32
ISNAD	KIRBIYIK, Çisem. "Modification of biomass-derived activated carbon with magnetic α-Fe2O3 nanoparticles for CO2 and CH4 adsorption". Turkish Journal of Chemistry 43/2 (2019), 687-704. https://doi.org/10.3906/kim-1810-32