Yıl: 2020 Cilt: 32 Sayı: 2 Sayfa Aralığı: 192 - 196 Metin Dili: İngilizce DOI: 10.7240/jeps.631637 İndeks Tarihi: 25-10-2020

Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition

Öz:
In this study, we report the sinterability of Seydişehir α-Al2O3 by coating TiO2 colloidal particles by sol-gel method. In thiscontext, efforts have been made to decrease the amount of impurities with washing process, to stabilize transformation withcalcination and to reduce grain size by jet-mill grinding. It is aimed to increase the density of Al2O3 by coating TiO2 by sol-gelmethod. The ceramic powders were dry-pressed, they were sintered at 15800C for different hours(1h, 3h and 6h). The role ofTiO2 content and sintering time on the microstructural properties and density of final products were investigated.
Anahtar Kelime:

TiO2 ile Sol Jel Kaplanmış Seydişehir Alüminanın Sinterlenmesi

Öz:
Bu çalışmada, Seydişehir α-Al2O3, TiO2 kolloidal parçacıklar ile sol-jel yöntemiyle kaplanmış ve α-Al2O3’nın sinterlenebilirlik özellikleri rapor edilmiştir. Yıkama işlemi ile kirlilik miktarını azaltmaya, kalsine ile dönüşümü stabilize etmeye ve jet değirmen öğütme ile α-Al2O3’nın tane boyutu azaltılmaya çalışılmıştır. TiO2 sol-jel yöntemi kullanılarak kaplama ile Al2O3'ün yoğunluğunun arttırılması amaçlanmıştır. Seramik tozları kuru preslenmiş, farklı saatler (1 saat, 3 saat ve 6 saat) boyunca 1580 0C'de sinterlenmiştir. TiO2 içeriğinin ve sinterleme süresinin nihai ürünün mikroyapısal özellikleri ve yoğunluğu üzerindeki rolü araştırılmıştır.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • [1] Yong, Y., You, W., Zheng, W., Gang L. and Wei, T. (2008). Preparation and sintering behaviour of nanostructured alumina/titania composite powders modified with nano-dopants. Mater. Sci. Eng. A., 490, 457-464.
  • [2] Erten, R., Emrullahoğlu, C.B., Yazıcı, Z.O. and Emrullahoğlu, Ö.F. (2004). An investigation on injection moulding of Seydişehir alumina. Key Eng. Mater., Vols. 264-268, 2523-2526.
  • [3] Palacı, Y.(2001). Alüminanın özelliklerine, şekillendirme yönteminin, katkılarının ve sinterleme sıcaklığının etkisi. Doktora Tezi, İstanbul Teknik Üniversitesi, Türkiye, p. 8-10.
  • [4] Engürlü, S., Taşlıçukur Öztürk, Z. and Kuşkonmaz, N. (2017). Investigation of the production of β- Al2O3 solid electrolyte from Seydişehir α-Al2O3. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Cilt 21 (3),816-819.
  • [5] Jayasankar, M., Ananthakumar, S., Mukundan, P., Wunderlich, W. and Warrier, K.G.K.(2008). Al2O3 @ TiO2-A simple sol–gel strategy to the synthesis of low temperature sintered alumina– aluminium titanate composites through a core– shell approach. J. Sol. St. Chem., 181,2748–2754.
  • [6] Avcı, G.G., Mısırlı, Z. and Günay, V. (1996). Processing and characterization of microfiltration supports prepared from alumina powders. Cer. Inter., 22, 23-26.
  • [7] Ahmed, M.A., Abdel-Messih, M.F. (2011). Structural and nano-composite features of TiO2– Al2O3 powders prepared by sol–gel method. J. Alloys Comp., 509,2154–2159.
  • [8] Arıer, U.Ö.A. and Tepehan, F.Z. (2013). Influence of Al2O3:TiO2 ratio on the structural and optical properties of TiO2–Al2O3 nano-composite films produced by sol gel method. Comp.: Part B., 58, 147–151.
  • [9] Toygun, Ş., Köneçoğlu, G. and Kalpaklı, Y. (2013). General principles of sol – gel. J. Eng. Nat. Sci. Sig., 31, 456-476.
  • [10] Dascalescu, T., Todan, L., Rusu, A., Preda, S., Andronescu, C.,Culita, D.C., Munteanu, C. and Zaharescu, M. (2014). Nanosized Al2O3-TiO2 oxide powder with enhanced porosity obtained by sol-gel method. Rev. Roum. Chim., 59 (2), 125- 134.
  • [11] Farias, R.F., Arnold, U., Martı´nez, L., Schuchardt, U., Jannini, M.J.D.M. and Airoldi, C. (2003). Synthesis, characterization and catalytic properties of sol–gel derived mixed oxides. J. Phys. Chem. Sol., 64, 2385–2389.
  • [12] Jung, Y., Kim, D., Kim, Y., Park, E. and Baeck, S. (2008). Synthesis of alumina–titania solid solution by sol–gel method. J. Phy. Chem. Sol., 69, 1464–1467.
  • [13] Leblebicier, Y., Yüzer, H. and Emrullahoğlu, Ö.F. (2000). Sol Jel metodu ile mikronaltı incelikte alümina üretimi. Afyon Kocatepe University J. Sci., 2 (1),1-12.
  • [14] Shi-Jie, S., Li-Ping, Y., Xiao-Min, L., Xiao-Ling, W., Hui, Y. and Xiao-Dong, S. (2013). Preparation and characterization of TiO2 doped and MgO stabilized Na–β″-Al2O3 electrolyte via a citrate sol–gel method. J. All. Comp., 563, 176– 179.
  • [15] Yang, L.P, Shan, S., Wei, X., Liu, X., Yang, H. and Shen, X. (2014). The mechanical and electrical properties of ZrO2–TiO2–Na-β/β″- alumina composite electrolyte synthesized via a citratesol–gel method. Cer. Inter., 40 9055–9060.
  • [16] Habibpanah, A.A., Pourhashem, S. and Sarpoolaky, H. (2011). Preparation and characterization of photocatalytic titania–alumina composite membranes by sol–gel methods. J. Eur. Cer. Soc., 31, 2867–2875.
  • [17] Akbarnezhad, Sh., Mousavi, S.M. and Sarhaddi, R. (2010). Sol-gel synthesis of alumina-titania ceramic membrane: Preparation and characterization. Ind. J. Sci. Tech., Vol. 3 No. 10 ISSN: 0974- 6846, 1048-1051.
  • [18] Mohammadi, M.R. (2014). Semiconductor TiO2– Al2O3 thin film gas sensors derived from aqueous particulate sol–gel process. Mater. Sci. Semi. Proc., 27,711–718.
  • [19] Cheng-Li, W., Weng-Sing, H., Hsueh-Liang,C., Huey-Jiuan, L., Horng-Huey, K. (2016). Kinetics of anatase transition to rutile TiO2 from titanium dioxide precursor powders synthesized by a solgel process. Cer. Inter., 42, 13136–13143.
  • [20] Vanessa, D., Homero, M., Mariana, F., Anderson, L., Rodrigo, P., Fernanda, M. (2019). Atomic layer deposited TiO2 and Al2O3 thin films as coatings for aluminum food packaging application. Mater.,12, 682.
  • [21] Dorian, A.H.H., Wanqiang, X., Michael, F. and Charles, C.S. (2012). Abnormal grain growth of rutile TiO2 induced by ZrSiO4. J. Cry. Grow., Volume 359 83-91.
APA taslicukur ozturk z, Engürlü S, kuşkonmaz n (2020). Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. , 192 - 196. 10.7240/jeps.631637
Chicago taslicukur ozturk zeynep,Engürlü Selin,kuşkonmaz nilgün Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. (2020): 192 - 196. 10.7240/jeps.631637
MLA taslicukur ozturk zeynep,Engürlü Selin,kuşkonmaz nilgün Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. , 2020, ss.192 - 196. 10.7240/jeps.631637
AMA taslicukur ozturk z,Engürlü S,kuşkonmaz n Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. . 2020; 192 - 196. 10.7240/jeps.631637
Vancouver taslicukur ozturk z,Engürlü S,kuşkonmaz n Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. . 2020; 192 - 196. 10.7240/jeps.631637
IEEE taslicukur ozturk z,Engürlü S,kuşkonmaz n "Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition." , ss.192 - 196, 2020. 10.7240/jeps.631637
ISNAD taslicukur ozturk, zeynep vd. "Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition". (2020), 192-196. https://doi.org/10.7240/jeps.631637
APA taslicukur ozturk z, Engürlü S, kuşkonmaz n (2020). Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. International journal of advances in engineering and pure sciences (Online), 32(2), 192 - 196. 10.7240/jeps.631637
Chicago taslicukur ozturk zeynep,Engürlü Selin,kuşkonmaz nilgün Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. International journal of advances in engineering and pure sciences (Online) 32, no.2 (2020): 192 - 196. 10.7240/jeps.631637
MLA taslicukur ozturk zeynep,Engürlü Selin,kuşkonmaz nilgün Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. International journal of advances in engineering and pure sciences (Online), vol.32, no.2, 2020, ss.192 - 196. 10.7240/jeps.631637
AMA taslicukur ozturk z,Engürlü S,kuşkonmaz n Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. International journal of advances in engineering and pure sciences (Online). 2020; 32(2): 192 - 196. 10.7240/jeps.631637
Vancouver taslicukur ozturk z,Engürlü S,kuşkonmaz n Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition. International journal of advances in engineering and pure sciences (Online). 2020; 32(2): 192 - 196. 10.7240/jeps.631637
IEEE taslicukur ozturk z,Engürlü S,kuşkonmaz n "Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition." International journal of advances in engineering and pure sciences (Online), 32, ss.192 - 196, 2020. 10.7240/jeps.631637
ISNAD taslicukur ozturk, zeynep vd. "Sintering of Seydişehir Alumina from Sol Gel Method with TiO2 Addition". International journal of advances in engineering and pure sciences (Online) 32/2 (2020), 192-196. https://doi.org/10.7240/jeps.631637