Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu
Yıl: 2020 Cilt: 6 Sayı: 1 Sayfa Aralığı: 181 - 195 Metin Dili: Türkçe DOI: 10.21324/dacd.612505 İndeks Tarihi: 23-12-2020
Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu
Öz: Laboratuvarda geliştirilen kuru atık biyolojik nitrifikasyon organizmasına (KANO), Cu+2iyonlarının biyosorpsiyonu, sıcaklık,başlangıç Cu+2 derişimi, pH ve biyosorbent dozuna göre kesikli ünitelerde araştırılmıştır. Deneysel çalışmalar ile elde edilen R2, qdenve qhes değerleri göz önüne alındığında, adsorpsiyon eşitliği, Cu+2 iyonlarının KANO’ya biyosorpsiyonu, tek kademe olarak belirtilenen iyi, Langmuir izotermi tarafından tanımlanmaktadır. Deneysel çalışmalarda belirlenen qe değeri, çözelti sıcaklığı arttıkçayükselirken, KANO yapısından sıcaklık ve pH’a bağlı olarak çözeltiye salınan organik madde ve NH4N artmaktadır. KANO’ya enyüksek Cu+2 biyosorpsiyonu, başlangıç pH ve sıcaklığı olan 5,0 ve 55 °C’de olduğu belirlenmiştir. Deneysel sonuçlar, KANO’ya, Cu+2biyosorpsiyonunun endotermik bir reaksiyon olduğunu göstermektedir. Sorpsiyon hızı için kinetik modeller, yalancı I. derece ve yalancıII. derece, partikül içi difüzyon, Elovich karşılaştırıldığında, adsorpsiyonun en iyi yalancı II. derece kinetik model tarafındantanımlandığını göstermektedir. ΔG° değeri sıcaklık arttıkça azalmaktadır. Bu durum adsorpsiyon sürecinin Gibbs enerjisinin artmasınısağlamaktadır. Negatif ΔG° değeri, KANO üzerine Cu+2 biyosorpsiyonunun uygulanabilir olduğu anlamına gelmektedir.
Anahtar Kelime: Biosorption of Cu2+ onto Biyological Waste Nitrification Organisms
Öz: The biosorption of Cu2+ ions from aqueous solutions onto the dry waste nitrification organisms (DWNO) which were enriched in the laboratory was investigated in batch experimental system with respect to the temperature, initial Cu2+ concentrations, pH, and biosorbent doses. Considering the R2 value, qexp and qcal, the adsorption equilibrium was well described by the Langmuir isotherm model which is suggesting that the Cu2+ ions were adsorbed onto the DWNO in a monolayer. The value of qe increased with increasing the temperature while also increases the release of organic matter and NH4N from the DWNO. The highest sorption of Cu2+ onto DWNO was determined at the initial pH value and temperature of 5.0 and 55°C, respectively. The results confirming that the biosorption reaction of Cu2+ on the DWNO was thought to be endothermic. A comparison of the kinetic models such as pseudo first and secondorder kinetics, intraparticle diffusion, and Elovich on the sorption rate demonstrated that the system was best described by the pseudo secondorder kinetic model. The value of ΔG° was decreasing with increasing temperature. It indicates that the adsorption process leads to an increase in Gibbs energy. The negative ΔG° value means the Cu2+sorption onto the DWNO is feasible.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | Aslan S, topçu u (2020). Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. , 181 - 195. 10.21324/dacd.612505 |
| Chicago | Aslan Sukru,topçu uğur savaş Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. (2020): 181 - 195. 10.21324/dacd.612505 |
| MLA | Aslan Sukru,topçu uğur savaş Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. , 2020, ss.181 - 195. 10.21324/dacd.612505 |
| AMA | Aslan S,topçu u Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. . 2020; 181 - 195. 10.21324/dacd.612505 |
| Vancouver | Aslan S,topçu u Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. . 2020; 181 - 195. 10.21324/dacd.612505 |
| IEEE | Aslan S,topçu u "Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu." , ss.181 - 195, 2020. 10.21324/dacd.612505 |
| ISNAD | Aslan, Sukru - topçu, uğur savaş. "Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu". (2020), 181-195. https://doi.org/10.21324/dacd.612505 |
| APA | Aslan S, topçu u (2020). Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. Doğal Afetler ve Çevre Dergisi, 6(1), 181 - 195. 10.21324/dacd.612505 |
| Chicago | Aslan Sukru,topçu uğur savaş Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. Doğal Afetler ve Çevre Dergisi 6, no.1 (2020): 181 - 195. 10.21324/dacd.612505 |
| MLA | Aslan Sukru,topçu uğur savaş Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. Doğal Afetler ve Çevre Dergisi, vol.6, no.1, 2020, ss.181 - 195. 10.21324/dacd.612505 |
| AMA | Aslan S,topçu u Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. Doğal Afetler ve Çevre Dergisi. 2020; 6(1): 181 - 195. 10.21324/dacd.612505 |
| Vancouver | Aslan S,topçu u Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu. Doğal Afetler ve Çevre Dergisi. 2020; 6(1): 181 - 195. 10.21324/dacd.612505 |
| IEEE | Aslan S,topçu u "Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu." Doğal Afetler ve Çevre Dergisi, 6, ss.181 - 195, 2020. 10.21324/dacd.612505 |
| ISNAD | Aslan, Sukru - topçu, uğur savaş. "Biyolojik Atık Nitrifikasyon Organizmasına Cu+2 Biyosorpsiyonu". Doğal Afetler ve Çevre Dergisi 6/1 (2020), 181-195. https://doi.org/10.21324/dacd.612505 |
