ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ

Gürü, Metin; BİLİCİ, İbrahim Ethem; KESKİN, Ali İhsan

ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ

İbrahim Ethem BİLİCİ, (Hitit Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü, Çorum, Türkiye)

Metin GÜRÜ, (Gazi Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü, Ankara, Türkiye)

Ali İhsan KESKİN (Mersin Üniversitesi, Tarsus Teknik Eğitim Fakültesi, Otomotiv Bölümü, Mersin, Türkiye)

Isı Bilimi ve Tekniği Dergisi

2 0

Yıl: 2019 Cilt: 39 Sayı: 1 Sayfa Aralığı: 51 - 58 Metin Dili: Türkçe İndeks Tarihi: 30-11-2020

ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ

Öz:

Plastik malzemelerin kullanılmasının artışıyla birlikte Polietilen (PE) nin de kullanımı da bütün dünyadaartmıştır. Bu yüksek miktardaki PE doğal bozulmama özelliğinden dolayı çevresel problemleri de beraberindegetirmektedir. Fakat bu PE sıvı yakıtlara dönüştürülebildiği için çevresel ve ekonomik olarak fayda sağlayabilir. Budeneysel çalışmada PE dizel yakıt katkısına dönüştürülerek polimer bazlı yakıtların dizel motorlarda eksoz emisyonuve performans paramatereleri incelenmiştir. PE atıklar termal piroliz yöntemiyle yakıta dönüştürülmüştür. PE atıkkatkılı yakıt %5, %10 ve %20 oranlarında dizel yakıt ile karıştırılarak herhangi bir modifikasyon gerçekleştrilmedentest edilmiştir. Genel olarak motor performans ve eksoz emisyon değerleri dizel yakıtlar ile benzer özelliklergöstermiştir. Spesifik yakıt tüketimi (SFC) değeri PE oranının artmasıyla hafif düzeyde artış göstermiştir.Karbonmonoksit (CO) ve azot oksit (NOx) değerleri de dizel yakıt ile karşılaştırıldığında artma eğilimi göstermiştir.

Anahtar Kelime:

INVESTIGATION OF PYROLYSIS OF WASTE POLYETHYLENE (PE) AND EFFECTS ON DIESEL ENGINE AND EMISSION PARAMETERS

Öz:

With the increment of usage of plastic materials, the use of polyethylene (PE) all over the world is also increasing. The great amount of PE usage results in a huge amount of PE waste. These huge amounts of PE wastes are generating environmental problems due to their non-degradable properties. But, PE wastes can be converted into liquid fuels for both economic and environmental benefits. In this experimental study, the conversion of PE wastes into diesel fuel and influence of the polymer-based fuels on the performance and exhaust emission of diesel engine was investigated. The conversion of PE wastes was carried out by utilizing the thermal pyrolysis process. The blends of the PE waste based fuel with diesel fuel were tested with three different ratios (5%, 10%, and 20%) in an unmodified direct injection diesel engine at full load condition. In general, engine performance and exhaust emission values of the blend fuels were similar to that of diesel fuel. Specific fuel consumption (SFC) values of the blend fuels slightly increased depending on the ratio of PE based fuel in the test fuels. The carbon monoxide (CO) and oxides of nitrogen (NO)x emissions of the blended fuels values showed an increasing trend as compared to the values of diesel fuel.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

Akpanudoh, N.S., Gobin, K., Manos, G., 2005, Catalytic degradation of plastic waste to liquid fuel over commercial cracking catalysts - Effect of polymer to catalyst ratio/acidity content, Journal of Molecular Catalysis a-Chemical, 235(1-2), 67-73.
Al Dawody, M.F., Bhatti, S.K.,2014, Experimental and Computational Investigations for Combustion, Performance and Emission Parameters of a Diesel Engine Fueled with Soybean Biodiesel-Diesel Blends. In: Othong, S., Waewsak, J. (eds.) 2013 International Conference on Alternative Energy in Developing Countries and Emerging Economies, Energy Procedia, 52,421-430.
Ali, M.F., Ahmed, S., Qureshi, M.S., 2011, Catalytic coprocessing of coal and petroleum residues with waste plastics to produce transportation fuels, Fuel Processing Technology, 92(5), 1109-1120.
Al-Salem, S.M., Lettieri, P., Baeyens, J., 2009, Recycling and recovery routes of plastic solid waste (PSW): A review, Waste Management, 29(10), 2625- 2643.
Arabiourrutia, M., Elordi, G., Lopez, G., Borsella, E., Bilbao, J., Olazar, M., 2012, Characterization of the waxes obtained by the pyrolysis of polyolefin plastics in a conical spouted bed reactor, Journal of Analytical and Applied Pyrolysis, 94, 230-237.
Bockhorn, H., Hornung, A., Hornung, U., Schwaller, D., 1999, Kinetic study on the thermal degradation of polypropylene and polyethylene, Journal of Analytical and Applied Pyrolysis, 48(2), 93-109.
Breyer, S., Mekhitarian, L., Rimez, B., Haut, B., 2017, Production of an alternative fuel by the co-pyrolysis of landfill recovered plastic wastes and used lubrication oils, Waste Management, 60, 363-374.
Can, O., 2014, Combustion characteristics, performance and exhaust emissions of a diesel engine fueled with a waste cooking oil biodiesel mixture, Energy Conversion and Management, 87, 676-686.
Ceamanos, J., Mastral, J.F., Millera, A., Aldea, M.E., 2002, Kinetics of pyrolysis of high density polyethylene. Comparison of isothermal and dynamic experiments, Journal of Analytical and Applied Pyrolysis, 65(2), 93- 110.
Çetinkaya, S., Salman S., 2014, Motor ve Taşıt Test Tekniği Ders Notları, Gazi Üniversitesi, Sayfa 81.
Coelho, A., Costa, L., Marques, M.M., Fonseca, I.M., Lemos, M., Lemos, F., 2012, The effect of ZSM-5 zeolite acidity on the catalytic degradation of highdensity polyethylene using simultaneous DSC/TG analysis, Applied Catalysis a-General, 413, 183-191.
Elordi, G., Lopez, G., Olazar, M., Aguado, R., Bilbao, J., Product distribution modelling in the thermal pyrolysis of high density polyethylene, Journal of Hazardous Materials, 144(3), 708-714.
Elordi, G., Olazar, M., Castano, P., Artetxe, M., Bilbao, J., 2012, Polyethylene Cracking on a Spent FCC Catalyst in a Conical Spouted Bed, Industrial & Engineering Chemistry Research, 51(43), 14008-14017.
Elordi, G., Olazar, M., Lopez, G., Amutio, M., Artetxe, M., Aguado, R., Bilbao, J., 2009, Catalytic pyrolysis of HDPE in continuous mode over zeolite catalysts in a conical spouted bed reactor, Journal of Analytical and Applied Pyrolysis, 85(1–2), 345-351.
Gobin, K., Manos, G., 2004, Polymer degradation to fuels over microporous catalysts as a novel tertiary plastic recycling method, Polymer Degradation and Stability, 83(2), 267-279.
Gonzalez, Y.S., Costa, C., Marquez, M.C., Ramos, P., 2011, Thermal and catalytic degradation of polyethylene wastes in the presence of silica gel, 5A molecular sieve and activated carbon, Journal of Hazardous Materials, 187(1-3), 101-112.
Gulab, H., Jan, M.R., Shah, J., Manos, G.,2010, Plastic catalytic pyrolysis to fuels as tertiary polymer recycling method: Effect of process conditions, Journal of Environmental Science and Health Part aToxic/Hazardous Substances & Environmental Engineering, 45(7), 908-915.
Guru, M., Artukoglu, B.D., Keskin, A., Koca, A., 2009, Biodiesel production from waste animal fat and improvement of its characteristics by synthesized nickel and magnesium additive, Energy Conversion and Management 50(3), 498-502.
Hitachi: DSC Measurement of Polyethlene. In., vol. 1. (2017)
Horvat, N., Ng, F.T.T., 1999, Tertiary polymer recycling: study of polyethylene thermolysis as a first step to synthetic diesel fuel. Fuel 78(4), 459-470
Huang, W.C., Huang, M.S., Huang, C.F., Chen, C.C., Ou, K.L., 2010, Thermochemical conversion of polymer wastes into hydrocarbon fuels over various fluidizing cracking catalysts, Fuel, 89(9), 2305-2316.
İlkılıç, C., Cilgin, E., Aydin, H., 2015, Terebinth oil for biodiesel production and its diesel engine application, Journal of the Energy Institute, 88(3), 292-303.
Jan, M.R., Shah, J., Gulab, H., 2010, Catalytic degradation of waste high-density polyethylene into fuel products using BaCO3 as a catalyst, Fuel Processing Technology, 91(11), 1428-1437.
Kannan, P., Ibrahim, S., Reddy, K.S.K., Al Shoaibi, A., Srinivasakannan, C., 2014, A Comparative Analysis of the Kinetic Experiments in Polyethylene Pyrolysis, Journal of Energy Resources Technology-Transactions of the Asme, 136(2).
Kantarelis, E., Donaj, P., Yang, W., Zabaniotou, A., 2009, Sustainable valorization of plastic wastes for energy with environmental safety via High-Temperature Pyrolysis (HTP) and High-Temperature Steam Gasification (HTSG), Journal of Hazardous Materials, 167(1–3), 675-684.
Keskin, A., Guru, M., Altiparmak, D., Aydin, K., 2008, Using of cotton oil soapstock biodiesel-diesel fuel blends as an alternative diesel fuel, Renewable Energy 33(4), 553-557 (2008).
Kim, D., Shin, S., Sohn, S., Choi, J., Ban, B., 2002, Waste plastics as supplemental fuel in the blast furnace process: improving combustion efficiencies, Journal of Hazardous Materials, 94(3), 213-222.
Kumar, S., Prakash, R., Murugan, S., Singh, R.K., 2013, Performance and emission analysis of blends of waste plastic oil obtained by catalytic pyrolysis of waste HDPE with diesel in a CI engine, Energy Conversion and Management, 74, 323-331.
Levine, S.E., Broadbelt, L.J., 2009, Detailed mechanistic modeling of high-density polyethylene pyrolysis: Low molecular weight product evolution, Polymer Degradation and Stability, 94(5), 810-822.
Lin, Y.H., Yang, M.H., 2008, Tertiary recycling of polyethylene waste by fluidised-bed reactions in the presence of various cracking catalysts, Journal of Analytical and Applied Pyrolysis, 83(1), 101-109.
Liu, X.L., Li, X.X., Liu, J., Wang, Z., Kong, B., Gong, X.M., Yang, X.Z., Lin, W.G., Guo, L.,2014, Study of high density polyethylene (HDPE) pyrolysis with reactive molecular dynamics, Polymer Degradation and Stability, 104, 62-70.
Luu, P.D., Truong, H.T., Luu, B.V., Pham, L.N., Imamura, K., Takenaka, N., Maeda, Y., 2014, Production of biodiesel from Vietnamese Jatropha curcas oil by a co-solvent method, Bioresource Technology, 173, 309-316.
Mani, M., Subash, C., Nagarajan, G., 2009, Performance, emission and combustion characteristics of a DI diesel engine using waste plastic oil, Applied Thermal Engineering, 29(13), 2738-2744.
Mehmood, C.T., Qazi, I.A., Hashmi, I., Bhargava, S., Deepa, S., 2016, Biodegradation of low density polyethylene (LDPE) modified with dye sensitized titania and starch blend using Stenotrophomonas pavanii, International Biodeterioration & Biodegradation, 113, 276-286.
Meng, A., Chen, S., Long, Y., Zhou, H., Zhang, Y., Li, Q., 2015, Pyrolysis and gasification of typical components in wastes with macro-TGA, Waste Management, 46, 247-256.
Miskolczi, N., Bartha, L., Deák, G., Jóver, B., 2004, Thermal degradation of municipal plastic waste for production of fuel-like hydrocarbons, Polymer Degradation and Stability, 86(2), 357-366.
Mohammadi, P., Tabatabaei, M., Nikbakht, A.M., Farhadi, K., Far, M.K., Castaldi, M.J., 2013, Simultaneous Energy Recovery from Waste Polymers in Biodiesel and Improving Fuel Properties, Waste and Biomass Valorization, 4(1), 105-116.
Oliveira, J.F.G., Lucena, I.L., Saboya, R.M.A., Rodrigues, M.L., Torres, A.E.B., Fernandes, F.A.N., Cavalcante, C.L., Parente, E.J.S.,2010, Biodiesel production from waste coconut oil by esterification with ethanol: The effect of water removal by adsorption, Renewable Energy, 35(11), 2581-2584.
Panda, A.K., Singh, R.K., Mishra, D.K., 2010, Thermolysis of waste plastics to liquid fuel A suitable method for plastic waste management and manufacture of value added products-A world prospective, Renewable & Sustainable Energy Reviews, 14(1), 233- 248.
Panda, A.K., Singh, R.K., Mishra, D.K., 2012, Thermocatalytic Degradation of Thermocol Waste to Value Added Liquid Products, Asian Journal of Chemistry, 24(12), 5539-5542.
Prakash, R., Singh, R.K., Murugan, S., 2013, Experimental investigation on a diesel engine fueled with bio-oil derived from waste wood-biodiesel emulsions, Energy, 55, 610-618.
Puente de la , G., Klocker, C., Sedran, U., 2002, Conversion of waste plastics into fuels - Recycling polyethylene in FCC, Applied Catalysis BEnvironmental, 36(4), 279-285.
Rashedul, H.K., Masjuki, H.H., Kalam, M.A., Ashraful, A.M., Rahman, S.M.A., Shahir, S.A., 2014, The effect of additives on properties, performance and emission of biodiesel fuelled compression ignition engine, Energy Conversion and Management, 88, 348-364.
Santella, C., Cafiero, L., De Angelis, D., La Marca, F., Tuffi, R., Vecchio Ciprioti, S.2016, Thermal and catalytic pyrolysis of a mixture of plastics from small waste electrical and electronic equipment (WEEE), Waste Management, 54, 143-152.
Siddiqui, M.N., Redhwi, H.H., 2009, Catalytic coprocessing of waste plastics and petroleum residue into liquid fuel oils, Journal of Analytical and Applied Pyrolysis, 86(1), 141-147.
Walendziewski, J., 2002, Engine fuel derived from waste plastics by thermal treatment, Fuel, 81(4), 473- 481.
Wang, H., Chen, D., Yuan, G., Ma, X., Dai, X., 2013, Morphological characteristics of waste polyethylene/polypropylene plastics during pyrolysis and representative morphological signal characterizing pyrolysis stages, Waste Management, 33(2), 327-339. Wang, L.-F., Rhim, J.-W., 2016, Grapefruit seed extract incorporated antimicrobial LDPE and PLA films: Effect of type of polymer matrix, LWT - Food Science and Technology, 74, 338-345.

APA	BİLİCİ İ, Gürü M, KESKİN A (2019). ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. , 51 - 58.
Chicago	BİLİCİ İbrahim Ethem,Gürü Metin,KESKİN Ali İhsan ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. (2019): 51 - 58.
MLA	BİLİCİ İbrahim Ethem,Gürü Metin,KESKİN Ali İhsan ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. , 2019, ss.51 - 58.
AMA	BİLİCİ İ,Gürü M,KESKİN A ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. . 2019; 51 - 58.
Vancouver	BİLİCİ İ,Gürü M,KESKİN A ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. . 2019; 51 - 58.
IEEE	BİLİCİ İ,Gürü M,KESKİN A "ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ." , ss.51 - 58, 2019.
ISNAD	BİLİCİ, İbrahim Ethem vd. "ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ". (2019), 51-58.

APA	BİLİCİ İ, Gürü M, KESKİN A (2019). ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. Isı Bilimi ve Tekniği Dergisi, 39(1), 51 - 58.
Chicago	BİLİCİ İbrahim Ethem,Gürü Metin,KESKİN Ali İhsan ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. Isı Bilimi ve Tekniği Dergisi 39, no.1 (2019): 51 - 58.
MLA	BİLİCİ İbrahim Ethem,Gürü Metin,KESKİN Ali İhsan ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. Isı Bilimi ve Tekniği Dergisi, vol.39, no.1, 2019, ss.51 - 58.
AMA	BİLİCİ İ,Gürü M,KESKİN A ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. Isı Bilimi ve Tekniği Dergisi. 2019; 39(1): 51 - 58.
Vancouver	BİLİCİ İ,Gürü M,KESKİN A ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ. Isı Bilimi ve Tekniği Dergisi. 2019; 39(1): 51 - 58.
IEEE	BİLİCİ İ,Gürü M,KESKİN A "ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ." Isı Bilimi ve Tekniği Dergisi, 39, ss.51 - 58, 2019.
ISNAD	BİLİCİ, İbrahim Ethem vd. "ATIK POLİETİLEN PİROLİZİNİN DİZEL MOTOR ve EMİSYON PARAMETRELERİNE ETKİSİNİN İNCELENMESİ". Isı Bilimi ve Tekniği Dergisi 39/1 (2019), 51-58.