Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls

Merey, Gokce; Güngör, Füsun Seyma; Ozguz, Emre; Tarakçı, Nurdan; Anac, Olcay

doi:10.3906/kim-1805-65

Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls

Füsun Şeyma KIŞKAN, (İstanbul Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Emre ÖZGÜZ, (İstanbul Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Olcay ANAÇ, (İstanbul Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Nurdan TARAKÇI, (İstanbul Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Gökçe MEREY (Hitit Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü, Çorum, Türkiye)

Turkish Journal of Chemistry

5 0

Yıl: 2018 Cilt: 42 Sayı: 5 Sayfa Aralığı: 1384 - 1397 Metin Dili: İngilizce DOI: 10.3906/kim-1805-65 İndeks Tarihi: 30-11-2020

Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls

Öz:

Catalytic reactions of α, β -conjugated carbonyl compounds have been a practical tool towards the synthesisof different useful heterocyclic compounds. Despite the numerous reactions with carbon-carbon double bond conjugatedcarbonyls, reactions of acetylenic carbonyls are limited. In this study, efficient dioxole synthesis was carried outvia acetylenic aldehydes and butadiene formation was preferred over cyclopropene formation via acetylenic esters asdifferent functional groups on these substrates change the product distribution. Both reaction conditions (such assolvent and temperature) and electrophilic structure of metal carbenoids alter the product distribution; acceptor (A),donor-acceptor (DA), and acceptor-acceptor (AA) functionalized diazo compounds yield different product types overdifferent mechanisms.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	Güngör F, Ozguz E, Anac O, Tarakçı N, Merey G (2018). Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. , 1384 - 1397. 10.3906/kim-1805-65
Chicago	Güngör Füsun Seyma,Ozguz Emre,Anac Olcay,Tarakçı Nurdan,Merey Gokce Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. (2018): 1384 - 1397. 10.3906/kim-1805-65
MLA	Güngör Füsun Seyma,Ozguz Emre,Anac Olcay,Tarakçı Nurdan,Merey Gokce Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. , 2018, ss.1384 - 1397. 10.3906/kim-1805-65
AMA	Güngör F,Ozguz E,Anac O,Tarakçı N,Merey G Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. . 2018; 1384 - 1397. 10.3906/kim-1805-65
Vancouver	Güngör F,Ozguz E,Anac O,Tarakçı N,Merey G Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. . 2018; 1384 - 1397. 10.3906/kim-1805-65
IEEE	Güngör F,Ozguz E,Anac O,Tarakçı N,Merey G "Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls." , ss.1384 - 1397, 2018. 10.3906/kim-1805-65
ISNAD	Güngör, Füsun Seyma vd. "Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls". (2018), 1384-1397. https://doi.org/10.3906/kim-1805-65

APA	Güngör F, Ozguz E, Anac O, Tarakçı N, Merey G (2018). Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. Turkish Journal of Chemistry, 42(5), 1384 - 1397. 10.3906/kim-1805-65
Chicago	Güngör Füsun Seyma,Ozguz Emre,Anac Olcay,Tarakçı Nurdan,Merey Gokce Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. Turkish Journal of Chemistry 42, no.5 (2018): 1384 - 1397. 10.3906/kim-1805-65
MLA	Güngör Füsun Seyma,Ozguz Emre,Anac Olcay,Tarakçı Nurdan,Merey Gokce Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. Turkish Journal of Chemistry, vol.42, no.5, 2018, ss.1384 - 1397. 10.3906/kim-1805-65
AMA	Güngör F,Ozguz E,Anac O,Tarakçı N,Merey G Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. Turkish Journal of Chemistry. 2018; 42(5): 1384 - 1397. 10.3906/kim-1805-65
Vancouver	Güngör F,Ozguz E,Anac O,Tarakçı N,Merey G Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls. Turkish Journal of Chemistry. 2018; 42(5): 1384 - 1397. 10.3906/kim-1805-65
IEEE	Güngör F,Ozguz E,Anac O,Tarakçı N,Merey G "Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls." Turkish Journal of Chemistry, 42, ss.1384 - 1397, 2018. 10.3906/kim-1805-65
ISNAD	Güngör, Füsun Seyma vd. "Synthetic strategies towards the carbenoid reactions of α, β -acetylenic carbonyls". Turkish Journal of Chemistry 42/5 (2018), 1384-1397. https://doi.org/10.3906/kim-1805-65