Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties

Zuhal YOLCU (Giresun Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Giresun, Türkiye)
Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi
2 2
Yıl: 2020 Cilt: 13 Sayı: 1 Sayfa Aralığı: 25 - 32 Metin Dili: İngilizce DOI: 10.18185/erzifbed.566231 İndeks Tarihi: 26-01-2021

Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties

Öz:
In this work dichlorotetrakis(1-vinylimidazole)cadmium(II), [CdCl2(vim)4] complex was synthesized using 1-vinylimidazole (vim) ligand and CdCl2. The structure of the complex was characterized by FT-IR spectroscopy,thermal analysis (TG, DTG, DTA) and X-ray single crystal studies. In the FT-IR spectrum of the complex, thecharacteristic peaks (C−H stretch, C=C and C=N vibration bands) of vim were observed. X-ray crystallographicdata of the titled complex revealed that vim ligand coordinated to the metal atom via the heterocyclic ringnitrogen atom. The coordination geometry of the Cd(II) central atom is elongated octahedral. Compoundcrystallized in P21/n space group, and the mononuclear units were weakly linked to each other by C-H⋯Clhydrogen bonds. It was determined by thermal analysis data that the complex degraded in four steps and totalmass loss was 99%.
Anahtar Kelime:

1-Vinilimidazol Ligantı İçeren Kadmiyum(II) Klorür Kompleksi: Yapısal, Spektroskopik ve Termal Özellikler

Öz:
Bu çalışmada 1-vinilimidazol (vim) ve CdCl2 kullanılarak; diklorotetrakis(1-vinilimidazol)kadmiyum(II), [CdCl2(vim)4] kompleksi sentezlendi. Kompleksin yapısı FT-IR spektroskopisi, termal analiz (TG, DTG, DTA) ve X-ışınları tek kristal çalışmaları ile karakterize edildi. Kompleksin IR spektrumunda vim ligandna ait karakteristik pikler (C−H gerilme, C=C ve C=N titreşim bandları) gözlendi. Kompleksin X-ışınları kristallografik verileri komplekste vim ligantlarının heterosiklik halka azotu üzerinden metal atomuna koordine olduğunu ortaya koymuştur. Cd(II) merkez atomunun koordinasyon geometrisi uzamış oktahedraldir. Kompleks P21/n uzay grubunda kristallenmiş ve mononükleer birimler, C-H⋯Cl hidrojen bağları ile birbirlerine zayıf şekilde bağlanmıştır. Termal analiz verilerinden kompleksin dört basamakta bozunduğu ve toplam kütle kaybının % 99 olduğu belirlenmiştir.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • Altomare, A., Burla, M. C., Camalli, M., Cascarano, G. L., Giacovazzo, C., Guagliardi, A., Moliterni, A. G. G., Polidori, G., Spagna. R. 1999. “SIR97: a new tool for crystal structure determination and refinement”, Journal of Applied Crystallography, 32, 115-119.
  • Baran, Y. and Linert, W. 1999. “Hexa(1- vinylimidazole)Co(II) perchlorate”, Journal of Chemical Crystallography, 29(10), 1077- 1079.
  • Brooks, P. and Davidson, N. 1960. “Mercury(II) Complexes of Imidazole and Histidine”, Journal of the American Chemical Society, 82(9), 2118-2123.
  • Cheng, C. C., Shen, N. N., Du, C. F., Wang, Z., Li, J. R., Huang, X. Y. 2017. “Cadmium(II) chloride complexes of imidazole-based ligands: Solvothermal syntheses, crystal structures and luminescent properties”, Inorganic Chemistry Communıcations, 85, 21-25.
  • Di Santo, A., Echeverria, G. A., Gustavo A., Piro, O. E., Perez, H., Ben Altabef, A., Gil, D. M. 2017. “Supramolecular architectures in luminescent Zn(II) and Cd(II) complexes containing imidazole derivatives: Crystal structures, vibrational and thermal properties, Hirshfeld surface analysis and electrostatic potentials”, Journal Of Molecular Structure, 1134, 492-503.
  • Ebel, K., Koehler, H., Gamer, A. O., Jäckh, R. (2000). “Ullmann’s Encyclopedia of Industrial Chemistry”, Wiley-VCH, Verlag GmbH & Co. KGaA, 637-645.
  • Edsall, J. T., Felsenfeld, G., Goodman, D. S., Gurd, F. R. N. 1954. “The Association of Imidazole with the Ions of Zinc and Cupric Copper” Journal of the American Chemical Society, 76(11), 3054-3061.
  • Erhardt, P. W., Hagdon, A. A., Davey, D., Pease, C. A., Venepalli, B. R., Griffin C. W., Gomez, R. P., Wiggins J. R., Ingebretsen W.R., Pang D. 1989. “Cardiotonic Agents. 5. Fragments From The Heterocycle-PhenylImidazole Pharmacophore”, Journal of Medicinal Chemistry, 32(6), 1173-1176.
  • Jencks, P. 1970. “Imidazole and proton transfer in catalysis” Biochemical Journal, 117(3), 50-50.
  • Jian, F., Zhao, P., Wang, S. and Zhang, S. 2002. “Structure of hexakis(imidazole) cadmium(II) carbonate trihydrate: [Cd(Im)6]CO3.3H2O”, Journal of Chemical Crystallography, 32(10), 395-398.
  • Johnson, R. A., Huong, S. M., Huang, E. S. 1999. “Inhibitory effect of 4-(4- fluorophenyl)-2-(4-hydroxyphenyl)-5-(4- pyridyl)1H-imidazole on HCMV DNA replication and permissive infection”, Antiviral Research, 41(3), 101-111.
  • Li, R. X., Li, S. X., Wu, Q. Y., Liu, G. Y. Liu, F. Q. 2007. “Catena-Poly[[bis(1- vinylimidazole-kappa N-3)-zinc(II)]-muphthalato-kappa O-2(1): O-2]”, Acta Crystallographica Section E, 63, M2874- U146.
  • Liu, F. Q., Li, R. X., Li, S. X., Li, C. Q., Liu, G. Y. 2007. “Dibromidotetrakis(1-vinyl-1Himidazole-kappa N-3)copper(II)”, Acta Crystallographica Section E, 63, M2437- U1691.
  • Liu, G. Y., Chen, H. N., Liu, F. Q., Li, S. X., Li, R. X., Huang, S. Y. 2007. “Crystal and Electrochemical Property of tetrakis(1-vinyl1H-imidazolekN(3))diisothiocyanatocadmium(II)”, Chinese Journal Of Inorganic Chemistry, 23, 1085-1088.
  • Lunt, E., Newton, C. G., Smith, C., Stevens, G. P., Stevens, M. F., Straw, C. G., Walsh, R. J., Warren, P. J., Fizames, C., Lavelle, F., 1987. “Antitumor imidazotetrazines. 14. Synthesis and antitumor activity of 6- and 8- substituted imidazo[5,1-d]-1,2,3,5- tetrazinones and 8-substituted pyrazolo[5,1- d]-1,2,3,5-tetrazinones”, Journal of Medicinal Chemistry, 30(2), 357-366.
  • Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J., Wood, P. A. 2008. “Mercury CSD 2.0 - new features for the visualization and investigation of crystal structures”, Journal Of Applied Crystallography, 41, 466-470.
  • Mighell, A. D. and Santoro, A. 1971. “The crystal and molecular structures of hexakis(imidazole)cadmium(II) nitrate, [Cd(C3H4N2)6](NO3)2 and hexakis(imidazole)cadmium-(II) hydroxide nitrate tetrahydrate, [Cd(C3H4N2)6](OH)(NO3).4H2O”, Acta Crystallographica Section B, B27, 2089- 2097.
  • Miyachi, H., Kiyota, H., Segawa, M. 1998. “Novel imidazole derivatives with subtypeselective antimuscarinic activity”, Bioorganic & Medicinal Chemistry Letters, 8(14), 1807–1812.
  • Pandey, J., Tiwari, V. K., Verma, S. S., Chaturvedi, V., Bhatnagar, S., Sinha, S., Gaikwad, A. N., Tripathi, R. P. 2009. “Synthesis and antitubercular screening of imidazole derivatives”, European Journal of Medicinal Chemistry, 44(8), 3350-3355.
  • Pang, S. J., Su, J., Lin, Q. 2007. “Bis(thiocyanato-kappa N)tetrakis(1-vinyl-1H-imidazole-kappa N-3)nickel(II)”, Acta Crystallographica Section E, 63, M2369- U1120.
  • Samdal, S. and Møllendal, H. 2011. “Microwave Spectrum and Conformational Composition of 1-Vinylimidazole”, The Journal of Physical Chemistry A, 115(26), 7559-7565.
  • Sheldrick, G. M. 2015. “Crystal structure refinement with SHELXL” Acta Crystallographica C, 71, 3-8.
  • Suzuki, F., Kuroda, T., Tamura, T., Sato, S., Ohmori, K., Ichikawa, S. 1992. “New antiinflammatory agents. 2. 5-Phenyl-3Himidazo[4,5-c][1,8]naphthyridin-4(5H)-ones: a new class of nonsteroidal antiinflammatory agents with potent activity like glucocorticoids”, Journal of Medicinal Chemistry, 35(15), 2863-2870.
  • Tas, M., Topal, S., Camur, S., Yolcu, Z., Celik, O. 2014. “Structural elucidation of novel mixed ligand complexes of 2- thiophene carboxylic acid [M(TCA)2(H2O)(x)(im)2] [x=2 M: Mn(II), Co(II) or Cd(II), x=0 Cu(II)]”, Main Group Metal Chemistry, 37(1-2), 39-47.
  • Wu, B., Bi, Y., Zhou, Z., Yang, L., Zhang, J. and Zhang, T. 2013. “Preparation, crystal structure, and thermal decomposition of an azide energetic compound [Cd(IMI)2(N3)2]n (IMI = imidazole)”, Journal of Coordination Chemistry, 66(17), 3014–3024,
  • Vijesh, A. M., Isloor, A. M., Telkar, S., Arulmoli, T., Fun, H. K. 2013. “Molecular docking studies of some new imidazole derivatives for antimicrobial properties”, Arabian Journal Of Chemistry, 6(2), 197- 204.
  • Yilmaz, H., Andac, O. 2018. “A novel zinc(II) complex containing square pyramidal, octahedral and tetrahedral geometries on the same polymeric chain constructed from pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole”, Journal Of Chemical Sciences, 130(4), 1-11.
  • Yolcu, Z., Demir S., Andac O., Büyükgüngör O. 2016. “Synthesis, Characterization and DFT-Based Investigation of a Novel Trinuclear Singly-Chloro-Bridged Copper(II)-1-Vinylimidazole Complex”, Acta Chimica Slovenica, 63, 646–653.
APA Yolcu Z (2020). Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. , 25 - 32. 10.18185/erzifbed.566231
Chicago Yolcu Zuhal Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. (2020): 25 - 32. 10.18185/erzifbed.566231
MLA Yolcu Zuhal Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. , 2020, ss.25 - 32. 10.18185/erzifbed.566231
AMA Yolcu Z Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. . 2020; 25 - 32. 10.18185/erzifbed.566231
Vancouver Yolcu Z Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. . 2020; 25 - 32. 10.18185/erzifbed.566231
IEEE Yolcu Z "Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties." , ss.25 - 32, 2020. 10.18185/erzifbed.566231
ISNAD Yolcu, Zuhal. "Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties". (2020), 25-32. https://doi.org/10.18185/erzifbed.566231
APA Yolcu Z (2020). Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 13(1), 25 - 32. 10.18185/erzifbed.566231
Chicago Yolcu Zuhal Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi 13, no.1 (2020): 25 - 32. 10.18185/erzifbed.566231
MLA Yolcu Zuhal Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol.13, no.1, 2020, ss.25 - 32. 10.18185/erzifbed.566231
AMA Yolcu Z Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2020; 13(1): 25 - 32. 10.18185/erzifbed.566231
Vancouver Yolcu Z Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2020; 13(1): 25 - 32. 10.18185/erzifbed.566231
IEEE Yolcu Z "Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties." Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 13, ss.25 - 32, 2020. 10.18185/erzifbed.566231
ISNAD Yolcu, Zuhal. "Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties". Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi 13/1 (2020), 25-32. https://doi.org/10.18185/erzifbed.566231
Sayfa Oluşturulma Tarihi
24-04-2024 20:36

İLETİŞİM

TÜBİTAK ULAKBİM TR Dizin

Yüzüncüyıl, İşçi Blokları Mahallesi

Muhsin Yazıcıoğlu Caddesi No:51/C

06530 Çankaya / ANKARA +90 (312) 298 92 00

trdizin@tubitak.gov.tr

TÜBİTAK ULAKBİM Ulusal Akademik Ağ ve Bilgi Merkezi Cahit Arf Bilgi Merkezi © Tüm Hakları Saklıdır. Gizlilik Politikası Kullanım Şartları