Yıl: 2020 Cilt: 12 Sayı: 1 Sayfa Aralığı: 106 - 112 Metin Dili: İngilizce DOI: https://doi.org/10.29137/umagd.550013 İndeks Tarihi: 28-04-2021

Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching

Öz:
An investigation was made of the production of boric acid from microwave-dehydrated ulexite waste by leaching with oxalicacid solution. An ulexite waste sample was dehydrated in a domestic microwave oven, and then dissolved in oxalic solution attemperatures of between 25 and 70°C. The experimental data from this dissolution process were analyzed using homogeneousand heterogeneous kinetic models, and the leaching kinetics of the microwave-dehydrated ulexite waste were defined. Theactivation energy of the oxalic acid solution of the microwave-dehydrated ulexite waste was also calculated.
Anahtar Kelime:

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  • Al-Harahsheh, M., Kingman, S.W. (2004). Microwaveassisted leaching-a review. Hydrometallurgy, 73 (3-4), 189-203.
  • Alkan, M., Cifci, C., Ayaz, F. Dogan, M. (2000). Dissolution kinetics of ulexite in aqueous EDTA solutions. Canadian Metallurgical Quarterly, 39, 433-440.
  • Alkan, M., Kocakerim, M.M. (1987). Dissolution Kinetics of Ulexite in Water Saturated by Sulphurdioxide. Journal of Chemical Technology and Biotechnology. 40, 215-222,
  • Banik, S., Bandyopadhyay, S. and Ganguly, S. (2003). Bioeffects of microwave-a brief review. Bioresource Technol, 87, 155-159.
  • Bayca, S.U. (2009). Effects of the addition of ulexite to the sintering behavior of a ceramic body. Journal of Ceramic Processing Research, 10, 162–166.
  • Bayca, S.U., Kocan, F. Abali, Y. (2014). Investigation of Leaching Kinetics of Ulexite Waste in Oxalic Acid Solutions. Chemical and Biochemical Engineering Quarterly, 28 (3) 273–280.
  • Brotherton, R.J. (1995). Encyclopedia of Inorganic Chemistry, Wiley, New York, USA, 363-367.
  • Demir, I., Güngören, C., Özkan, Ş.G. (2017). Mikrodalga enerjisinin kolemanit cevherinin ufalanmasına ve flotasyonuna etkisi, Boron, 2, 75 – 81.
  • Demirkiran, N. (2009). Dissolution kinetics of ulexite in ammonium nitrate solutions. Hydrometallurgy, 95, 198–202.
  • Dogan T., Yartasi, A. (2009). Kinetic investigation of reaction between ulexite ore and phosphoric acid. Hydrometallurgy, 96, 294- 299.
  • Ekmekyapar, A., Kunkul, A., Demirkiran N. (2012). Kinetic Investigation of Reaction Between Mineral Ulexite and Citric Acid. Mineral Processing and Extractive Metallurgy Review, 31, 250 – 255.
  • Eymir, C., Okur, H. (2005). Dehydration of Ulexite By Microwave Heating, Thermochimica Acta, 428, 125-129.
  • Gerhartz, W. (1985). Ullmann’s Encyclopedia of Industrial Chemistry, Wiley, Germany, A4, p. 263, 272, 274, 275.
  • George, R.M. and Burnett, S.A. (1991). General guidelines for microwaveable products. Food Control, 2 (1), 35-44.
  • Gungoren, C., S.G., Ozkan, Hacifazlioglu, H. (2016). Mikrodalga kurutmanın linyit kömürünün öğütülebilirliğine etkisi, Bilimsel madencilik dergisi, 55, 15 – 22.
  • Guo, W., Liu, Y., Zhu, X. and Wang, S. (2011). Temperature-dependet dielectric properties of honey associated with dielectric heating. Journal of Food Engineering, 102, 209-216.
  • Koklu, M., Ozyetis, O., Maraslioglu, D., Yavuklu E., Celen, B., Tufan T., Gunduz, M. (2003). Developments in analyzes of calcium borate. (in Turkish), 18 International Mining Congress and Exhibition of Turkey, 10 – 13 June, Antalya, pp. 141 – 146.
  • Kunkul, A., Yapici, S., Kocakerim, M.M., Copur, M. (1997). The dissolution kinetics of ulexite in ammonia solutions saturated with CO2. Hydrometallurgy, 44, 135–145.
  • Kunkul, A., Tunc, M., Yapici, S., Ersahan, H., Kocakerim, M.M. (1997). Dissolution of thermally dehydrated ulexite in sulphuric acid solution. Industrial & Engineering Chemistry Research, 36, 4847–4851.
  • Levenspiel O. (1999). Chemical Reaction Engineering, New York, John Wiley and Sons.
  • Roskill, 1999, The Economics of Boron, roskill Information Services Ltd, london England.
  • Sener, S. Ozbayoglu, G. Demirci, S. (2000). Changes in the structure of ulexite on heating, Thermochim. Acta 362, 107–112.
  • Siguemoto, E.S. and Gut, J.A.W. (2016). Dielectric properties of cloudy apple juices relevant to microwave pasteurization. Food Bioprocess Technology, 9, 1345 – 1357.
  • Smith, R.A., McBroom, R.B. (1992). Boron Compouns, Kirk othmer Encyclopedia of Chemical Technology vol 4, New York, John Wiley and Sons.
  • Tunc, M., Kocakerim, M.M., Yapici, S., Bayrakceken, S. (1999). Dissolution mechanism of ulexite in H2SO4 solution. Hydrometallurgy, 51, 359–370.
  • Vorster, W. (2001). The effect of microwave radiation on mineral processing. The University of Birmingham, Birmingham, p. 256.
APA KOÇAN F, BAYÇA S (2020). Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. , 106 - 112. https://doi.org/10.29137/umagd.550013
Chicago KOÇAN Feray,BAYÇA Salih Uğur Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. (2020): 106 - 112. https://doi.org/10.29137/umagd.550013
MLA KOÇAN Feray,BAYÇA Salih Uğur Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. , 2020, ss.106 - 112. https://doi.org/10.29137/umagd.550013
AMA KOÇAN F,BAYÇA S Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. . 2020; 106 - 112. https://doi.org/10.29137/umagd.550013
Vancouver KOÇAN F,BAYÇA S Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. . 2020; 106 - 112. https://doi.org/10.29137/umagd.550013
IEEE KOÇAN F,BAYÇA S "Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching." , ss.106 - 112, 2020. https://doi.org/10.29137/umagd.550013
ISNAD KOÇAN, Feray - BAYÇA, Salih Uğur. "Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching". (2020), 106-112. https://doi.org/https://doi.org/10.29137/umagd.550013
APA KOÇAN F, BAYÇA S (2020). Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. Uluslararası Mühendislik Araştırma ve Geliştirme Dergisi, 12(1), 106 - 112. https://doi.org/10.29137/umagd.550013
Chicago KOÇAN Feray,BAYÇA Salih Uğur Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. Uluslararası Mühendislik Araştırma ve Geliştirme Dergisi 12, no.1 (2020): 106 - 112. https://doi.org/10.29137/umagd.550013
MLA KOÇAN Feray,BAYÇA Salih Uğur Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. Uluslararası Mühendislik Araştırma ve Geliştirme Dergisi, vol.12, no.1, 2020, ss.106 - 112. https://doi.org/10.29137/umagd.550013
AMA KOÇAN F,BAYÇA S Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. Uluslararası Mühendislik Araştırma ve Geliştirme Dergisi. 2020; 12(1): 106 - 112. https://doi.org/10.29137/umagd.550013
Vancouver KOÇAN F,BAYÇA S Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching. Uluslararası Mühendislik Araştırma ve Geliştirme Dergisi. 2020; 12(1): 106 - 112. https://doi.org/10.29137/umagd.550013
IEEE KOÇAN F,BAYÇA S "Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching." Uluslararası Mühendislik Araştırma ve Geliştirme Dergisi, 12, ss.106 - 112, 2020. https://doi.org/10.29137/umagd.550013
ISNAD KOÇAN, Feray - BAYÇA, Salih Uğur. "Production of Boric Acid from Microwave-Dehydrated Ulexite Waste by Oxalic Acid Solution Leaching". Uluslararası Mühendislik Araştırma ve Geliştirme Dergisi 12/1 (2020), 106-112. https://doi.org/https://doi.org/10.29137/umagd.550013