Yıl: 2021 Cilt: 46 Sayı: 1 Sayfa Aralığı: 82 - 96 Metin Dili: İngilizce DOI: 10.15237/gida.GD20055 İndeks Tarihi: 02-06-2021

OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE

Öz:
In the current study, the Central Composite Design was applied to optimize HS-SPME extraction in orderto detect 2,3,5,6 tetramethyl pyrazine in isomalt contaning milk chocolate. The optimal conditions for thethree experimental responses influencing SPME efficiency were 10 min, 40 min and 57 °C for equilibrationtime, extraction time and extraction temperature, respectively. SPME fibers coated with 100 mpolydimethylsiloxane coating, 65 µm polydimethylsiloxane/divinylbenzene coating, 75 µmcarboxen/polydimethylsiloxane coating and 50/30 µm divinylbenzene/carboxen/polydimethylsiloxane ona StableFlex fiber were investigated. The preparation conditions of the chocolate samples were also evaluatedby measuring their effects on the coating composition of the head space. The SPME fiber coated with 50/30µm divinylbenzene/carboxen-polydimethylsiloxane provided the highest extraction efficiency, especiallywhen the samples were extracted at 60 °C for 30 min under dry conditions. Eighty-one blends were extractedand experimentally detected most of which have been formerly stated as odor-active components.
Anahtar Kelime:

SÜTLÜ ÇİKOLATA İÇİN KATI FAZ MİKROEKSTRAKSIYON YÖNTEMİNİN OPTİMİZASYONU

Öz:
Bu çalışmada, isomalt içeren sütlü çikolatalarda 2,3,5,6 tetra metal pirazin tayini için HS-SPME ekstraksiyonunun optimizasyonunda merkezi kompozit tasarım uygulanmıştır. SPME verimliliği etkileyen dengeleme süresi, ekstraksiyon süresi ve ekstraksiyon sıcaklığı için optimum koşullar olarak sırasıyla 10 dk, 40 dk ve 57 °C olarak belirlenmiştir. Çalışmada StableFlex fibere uygulanmış 100 µm polidimetilsiloksan, 65 µm polidimetilsiloksan/divinilbenzen, 75 µm karboksen/polidimetilsiloksan ve 50/30 µm divinilbenzen/karboksen/polidimetilsiloksan kaplamalar SPME fiberler olarak incelenmiştir. Çikolata örneklerinin hazırlama koşulları ayrıca tepe boşluğunun kaplama bi leşimi üzerindeki etkileri ölçülerek de değerlendirilmiştir. Özellikle örneklerin kuru koşullarda 60 °C’de 30 dk örnek ekstraksiyonunda 50/30 µm divinilbenzen/karboksen/polidimetilsiloksan kaplı SPME fiber en yüksek ekstraksiyon verimliliğini sağlamıştır.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA Oba Ş, Toker O, Rasouli Pirouzian H, palabiyik i, Konar N, ARTIK N, SAGDIC O (2021). OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. , 82 - 96. 10.15237/gida.GD20055
Chicago Oba Şirin,Toker Omer Said,Rasouli Pirouzian Haniyeh,palabiyik ibrahim,Konar Nevzat,ARTIK NEVZAT,SAGDIC OSMAN OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. (2021): 82 - 96. 10.15237/gida.GD20055
MLA Oba Şirin,Toker Omer Said,Rasouli Pirouzian Haniyeh,palabiyik ibrahim,Konar Nevzat,ARTIK NEVZAT,SAGDIC OSMAN OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. , 2021, ss.82 - 96. 10.15237/gida.GD20055
AMA Oba Ş,Toker O,Rasouli Pirouzian H,palabiyik i,Konar N,ARTIK N,SAGDIC O OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. . 2021; 82 - 96. 10.15237/gida.GD20055
Vancouver Oba Ş,Toker O,Rasouli Pirouzian H,palabiyik i,Konar N,ARTIK N,SAGDIC O OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. . 2021; 82 - 96. 10.15237/gida.GD20055
IEEE Oba Ş,Toker O,Rasouli Pirouzian H,palabiyik i,Konar N,ARTIK N,SAGDIC O "OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE." , ss.82 - 96, 2021. 10.15237/gida.GD20055
ISNAD Oba, Şirin vd. "OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE". (2021), 82-96. https://doi.org/10.15237/gida.GD20055
APA Oba Ş, Toker O, Rasouli Pirouzian H, palabiyik i, Konar N, ARTIK N, SAGDIC O (2021). OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. GIDA, 46(1), 82 - 96. 10.15237/gida.GD20055
Chicago Oba Şirin,Toker Omer Said,Rasouli Pirouzian Haniyeh,palabiyik ibrahim,Konar Nevzat,ARTIK NEVZAT,SAGDIC OSMAN OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. GIDA 46, no.1 (2021): 82 - 96. 10.15237/gida.GD20055
MLA Oba Şirin,Toker Omer Said,Rasouli Pirouzian Haniyeh,palabiyik ibrahim,Konar Nevzat,ARTIK NEVZAT,SAGDIC OSMAN OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. GIDA, vol.46, no.1, 2021, ss.82 - 96. 10.15237/gida.GD20055
AMA Oba Ş,Toker O,Rasouli Pirouzian H,palabiyik i,Konar N,ARTIK N,SAGDIC O OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. GIDA. 2021; 46(1): 82 - 96. 10.15237/gida.GD20055
Vancouver Oba Ş,Toker O,Rasouli Pirouzian H,palabiyik i,Konar N,ARTIK N,SAGDIC O OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE. GIDA. 2021; 46(1): 82 - 96. 10.15237/gida.GD20055
IEEE Oba Ş,Toker O,Rasouli Pirouzian H,palabiyik i,Konar N,ARTIK N,SAGDIC O "OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE." GIDA, 46, ss.82 - 96, 2021. 10.15237/gida.GD20055
ISNAD Oba, Şirin vd. "OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS OF MILK CHOCOLATE". GIDA 46/1 (2021), 82-96. https://doi.org/10.15237/gida.GD20055