Yıl: 2021 Cilt: 9 Sayı: 1 Sayfa Aralığı: 330 - 335 Metin Dili: İngilizce DOI: 10.21923/jesd.726228 İndeks Tarihi: 01-06-2021

GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES

Öz:
In this study, we reported a simple and green manufacturing of a uniform, sphereshaped [Ni1/3Co1/3Mn1/3]CO3 nanoparticles, which can be considered as a precursorfor Li[Ni1/3Co1/3Mn1/3]O2 . Ni-Co-Mn carbonate particle was prepared via threesteps, (1), the mixing metal sulfate salts with Na2CO3 which, formed the primaryprecipitation, (2) the addition of (NH4)2CO3, responsible for the increasingconversion rate, (3) the hydrothermal treatment lead to existing of recrystallizationand spherical shape of [Ni1/3Co1/3Mn1/3]CO3 particles. The morphology andcrystalline structure of the present material is characterized by Energy-dispersiveX-ray Spectroscopy (EDS), Scanning Electron Microscopic (SEM) and X-raydiffraction (XRD). Analysis outcomes indicated that the particle's growthmechanism of spherical composition is depend on a dissolution-recrystallizationprocess of metal salts and (NH4)2CO3 dissociation process. This study opens a greenavenue to prepare cathode materials in the lithium-ion battery application.
Anahtar Kelime:

YEŞİL YÖNTEM İLE KÜRESEL Ni1/3Co1/3Mn1/3CO3 PARÇACIKLARIN SENTEZİ

Öz:
Bu çalışmada, tek tip, küre şeklinde bir [Ni1/3Co1/3Mn1/3]CO3 nanopartiküllerinin basit ve çevreye duyarlı sentez yöntemiyle üretilmesini çalışılmıştır. Ni-Co-Mn karbonat partikülü üç aşamada hazırlandı, (1), birincil sülfat oluşturan Na2CO3 ile metal sülfat tuzlarının karıştırılması, (2) ekstra (NH4)2CO3 ilave edilmesi reaksiyonun gerçekleşmesine neden olan kimyasal, (3) hidrotermal metodu ile [Ni1/3Co1/3Mn1/3]CO3 partiküllerinin kristallenmesi ve küresel şeklinin oluşması. Mevcut malzemenin morfolojisi ve kristalin yapısı, Enerji-dağıtıcı X-ışını Spektroskopisi (EDS), Taramalı Elektron Mikroskopik (SEM) ve X-ışını kırınımı (XRD) ve ile karakterize edildi. Analiz sonuçları, parçacığın küresel yapı mekanizmasının, metal tuzlarının bir çözünme-yeniden kristalizasyon işlemine ve (NH4)2CO3 ayrışma işlemine dayandığını göstermiştir. Bu makelde yapılan araştırmalar ile, lityum iyon pilleri için katot materyalleri hazırlamanmasında çevreye duyarlı hidrotermal yönteminin kullanılması bu konuda yeni yaklaşımlar açacaktır.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA demir m (2021). GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. , 330 - 335. 10.21923/jesd.726228
Chicago demir muslum GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. (2021): 330 - 335. 10.21923/jesd.726228
MLA demir muslum GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. , 2021, ss.330 - 335. 10.21923/jesd.726228
AMA demir m GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. . 2021; 330 - 335. 10.21923/jesd.726228
Vancouver demir m GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. . 2021; 330 - 335. 10.21923/jesd.726228
IEEE demir m "GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES." , ss.330 - 335, 2021. 10.21923/jesd.726228
ISNAD demir, muslum. "GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES". (2021), 330-335. https://doi.org/10.21923/jesd.726228
APA demir m (2021). GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. Mühendislik Bilimleri ve Tasarım Dergisi, 9(1), 330 - 335. 10.21923/jesd.726228
Chicago demir muslum GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. Mühendislik Bilimleri ve Tasarım Dergisi 9, no.1 (2021): 330 - 335. 10.21923/jesd.726228
MLA demir muslum GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. Mühendislik Bilimleri ve Tasarım Dergisi, vol.9, no.1, 2021, ss.330 - 335. 10.21923/jesd.726228
AMA demir m GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. Mühendislik Bilimleri ve Tasarım Dergisi. 2021; 9(1): 330 - 335. 10.21923/jesd.726228
Vancouver demir m GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES. Mühendislik Bilimleri ve Tasarım Dergisi. 2021; 9(1): 330 - 335. 10.21923/jesd.726228
IEEE demir m "GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES." Mühendislik Bilimleri ve Tasarım Dergisi, 9, ss.330 - 335, 2021. 10.21923/jesd.726228
ISNAD demir, muslum. "GREEN SYNTHESIS OF SPHERICAL-SHAPED Ni1/3Co1/3Mn1/3CO3 PARTICLES". Mühendislik Bilimleri ve Tasarım Dergisi 9/1 (2021), 330-335. https://doi.org/10.21923/jesd.726228