Yıl: 2021 Cilt: 11 Sayı: 3 Sayfa Aralığı: 1866 - 1873 Metin Dili: İngilizce DOI: 10.21597/jist.910865 İndeks Tarihi: 09-12-2021

Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation

Öz:
There is growing interest in reclaiming waste materials from industries such asmetallurgical slags, fly ash and agricultural wastes in a resource-limited world. A large amount of steelslag is produced as waste material from steel industries. This study focused on natural organic matter(NOM) removal using steel slag as a low-cost adsorbent/catalyst. The aim of this study was toinvestigate the potential use of steel slag to remove NOM in waters with high specific UV absorbance(SUVA254) value. The effects of steel slag particles size and dosages of slag and hydrogen peroxide onNOM removals were determined. UV absorbing NOM fractions were preferentially removed by thesteel slag. Maximum UV absorbance and dissolved organic carbon (DOC) reduction after adsorptionwere 83% and 54%, respectively. In addition to adsorptive properties, iron oxides on steel slag surfacessignificantly catalyses hydrogen peroxide decomposition. As a result of formation of strong oxidantsafter hydrogen peroxide decomposition, NOM removal increased. The results showed that steel slag canbe used as adsorbent and catalyst for removal of NOM in high SUVA value waters. Besides, steel slagmay be effective for controlling the formation of disinfection by-products (DBPs) in drinking watertreatment due to the removal of NOM fractions with high UV absorbance values.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • Branca TA, Colla V, Algermissen D, Granbom H, Martini U, Morillon A, Pietruck R, Rosendahl S, 2020. Reuse and Recycling of By-Products in the Steel Sector: Recent Achievements Paving the Way to Circular Economy and Industrial Symbiosis in Europe. Metals, 10 (3):345.
  • Dastgheib SA, Karanfil T, Cheng W, 2004. Tailoring Activated Carbons for Enhanced Removal of Natural Organic Matter from Natural Waters. Carbon, 42 (3):547-557.
  • Dimitrova SV, 2002. Use of Granular Slag Columns for Lead Removal. Water Research, 36 (16):4001-4008.
  • Escobar-Hoyos LF, Hoyos-Giraldo LS, Londoño-Velasco E, Reyes-Carvajal I, Saavedra-Trujillo D, CarvajalVarona S, Sánchez-Gómez A, Wagner ED, Plewa MJ, 2013. Genotoxic and Clastogenic Effects of Monohaloacetic Acid Drinking Water Disinfection By-Products in Primary Human Lymphocytes. Water Research, 47(10):3282-3290.
  • Kitis M, Kaplan SS, 2007. Advanced Oxidation of Natural Organic Matter Using Hydrogen Peroxide and IronCoated Pumice Particles. Chemosphere, 68 (10):1846-1853.
  • Kitis M, Karanfil T, Kilduff JE, 2004. The Reactivity of Dissolved Organic Matter for Disinfection By-Product Formation. Turkish Journal of Engineering and Environmental Sciences, 28 (3):167-180.
  • Liu S, Lim M, Fabris R, Chow C, Drikas M, Amal R, 2010. Comparison of Photocatalytic Degradation of Natural Organic Matter in Two Australian Surface Waters Using Multiple Analytical Techniques. Organic Geochemistry, 41 (2):124-129.
  • Manchisi J, Matinde E, Rowson NA, Simmons MJ, Simate GS, Ndlovu S, Mwewa B, 2020. Ironmaking and Steelmaking Slags As Sustainable Adsorbents for Industrial Effluents and Wastewater Treatment: A Critical Review of Properties, Performance, Challenges and Opportunities. Sustainability, 12 (5):2118.
  • Moncayo-Lasso A, Pulgarin C, Benítez N, 2008. Degradation of DBPs' Precursors in River Water Before and After Slow sand Filtration by Photo-Fenton Process at pH 5 in a Solar CPC Reactor. Water Research, 42 (15):4125-4132.
  • Nawrocki J, Andrzejewski P, 2011. Nitrosamines and Water. Journal of Hazardous Materials, 189 (1-2):1-8.
  • Nie Y, Hu C, Zhou L, Qu J, Wei Q, Wang D, 2010. Degradation characteristics of humic acid over iron oxides/Fe0 core–shell nanoparticles with UVA/H2O2. Journal of Hazardous Materials, 173 (1-3):474-479.
  • Oh C, Rhee S, Oh M, Park J, 2012. Removal Characteristics of As (III) and As (V) from Acidic Aqueous Solution By Steel Making Slag. Journal of Hazardous Materials, 213:147-155.
  • Ramakrishna KR, Viraraghavan T,1998. Use of Slag for Dye Removal. Waste Management, 17(8):483-488.
  • Richardson SD, Plewa MJ, Wagner ED, Schoeny R, DeMarini DM, 2007. Occurrence, Genotoxicity, and Carcinogenicity of Regulated and Emerging Disinfection By-Products in Drinking Water: A Review and Roadmap for Research. Mutation Research/Reviews in Mutation Research, 636 (1-3):178-242.
  • Shuai X, Zinati G, 2009. Proton Charge and Adsorption of Humic Acid and Phosphate on Goethite. Soil Science Society of America Journal, 73 (6):2013-2020.
  • Tozum-Akgul S, Yigit NO, 2017. Natural Organic Matter Removal by Catalytic Ozonation using Original and Surface-Modified Waste and Natural Materials. Desalination and Water Treatment, 67:117-124.
  • Yigit NO, Tozum S, 2012. Removal of Selenium Species from Waters Using Various Surface‐Modified Natural Particles and Waste Materials. Clean–Soil, Air, Water, 40 (7):735-745.
APA Kaplan Bekaroglu S, ATEŞ N, KİTİŞ M (2021). Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. , 1866 - 1873. 10.21597/jist.910865
Chicago Kaplan Bekaroglu Sehnaz Sule,ATEŞ Nuray,KİTİŞ Mehmet Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. (2021): 1866 - 1873. 10.21597/jist.910865
MLA Kaplan Bekaroglu Sehnaz Sule,ATEŞ Nuray,KİTİŞ Mehmet Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. , 2021, ss.1866 - 1873. 10.21597/jist.910865
AMA Kaplan Bekaroglu S,ATEŞ N,KİTİŞ M Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. . 2021; 1866 - 1873. 10.21597/jist.910865
Vancouver Kaplan Bekaroglu S,ATEŞ N,KİTİŞ M Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. . 2021; 1866 - 1873. 10.21597/jist.910865
IEEE Kaplan Bekaroglu S,ATEŞ N,KİTİŞ M "Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation." , ss.1866 - 1873, 2021. 10.21597/jist.910865
ISNAD Kaplan Bekaroglu, Sehnaz Sule vd. "Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation". (2021), 1866-1873. https://doi.org/10.21597/jist.910865
APA Kaplan Bekaroglu S, ATEŞ N, KİTİŞ M (2021). Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 11(3), 1866 - 1873. 10.21597/jist.910865
Chicago Kaplan Bekaroglu Sehnaz Sule,ATEŞ Nuray,KİTİŞ Mehmet Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi 11, no.3 (2021): 1866 - 1873. 10.21597/jist.910865
MLA Kaplan Bekaroglu Sehnaz Sule,ATEŞ Nuray,KİTİŞ Mehmet Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol.11, no.3, 2021, ss.1866 - 1873. 10.21597/jist.910865
AMA Kaplan Bekaroglu S,ATEŞ N,KİTİŞ M Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2021; 11(3): 1866 - 1873. 10.21597/jist.910865
Vancouver Kaplan Bekaroglu S,ATEŞ N,KİTİŞ M Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation. Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2021; 11(3): 1866 - 1873. 10.21597/jist.910865
IEEE Kaplan Bekaroglu S,ATEŞ N,KİTİŞ M "Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation." Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 11, ss.1866 - 1873, 2021. 10.21597/jist.910865
ISNAD Kaplan Bekaroglu, Sehnaz Sule vd. "Removal of Natural Organic Matter by Steel Slag through Adsorption and Catalytic Oxidation". Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi 11/3 (2021), 1866-1873. https://doi.org/10.21597/jist.910865