Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms

Öztürk, Tuba; Aydin Keskin, Gulsen; AKBAŞ, Hande

Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms

Tuba Öztürk, (Tekirdağ Namık Kemal Üniversitesi, Çorlu Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Tekirdağ, Türkiye)

Hande Akbaş, (Tekirdağ Namık Kemal Üniversitesi, Çorlu Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Tekirdağ, Türkiye)

Gülşen Aydın Keskin (Balıkesir Üniversitesi, Mühendislik Fakültesi, Endüstri Mühendisliği Bölümü, Balıkesir, Türkiye)

Manas Journal of Engineering

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Yıl: 2020 Cilt: 8 Sayı: 2 Sayfa Aralığı: 115 - 124 Metin Dili: İngilizce İndeks Tarihi: 11-01-2022

Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms

Öz:

In this study, treatment of wastewaters containing Setazol Black TNN, which is a reactive diazo dyestuff that is prevalently used in dyeing natural fibers in the textile industry, by the electrocoagulation method was examined. Experiments investigating the effectiveness of Al and Fe electrodes in treatment of real wastewaters collected from the dye bath of a yard dyeing facility and synthetic wastewaters prepared with Setazol Black TNN used in this bath were carried out by determining the optimum treatment conditions. The optimum current, pH and initial dye concentration in the synthetic wastewaters for the Al electrodes were 8 ampere (A), 7.57 and 50 mg/L, respectively, while these for the Fe electrodes were 8A, 9 and 100 mg/L, respectively. The optimum current, pH and thinning rate were seen in the dye bath wastewaters for the Al electrodes as 8A, 8 and 1/60 and for the Fe electrodes as 8A, 9 and 1/30, respectively. While carrying out the experiments using these experimental conditions, color and Chemical Oxygen Demand (COD) removal from the synthetic wastewaters and the dye bath wastewaters with long-running treatments was investigated. As a result of the treatment experiments, removal efficiencies of 96% and 57% respectively for color and COD for the Al electrodes and 99% and 61% for the Fe electrodes in the synthetic wastewaters, 87% and 55% for the Al electrodes and 89% and 55% for the Fe electrodes in the dye bath wastewaters were obtained. With this study, it was aimed to reveal not only the position and effectiveness of the treatment process for wastewaters containing intense color but also the effects of chemicals used in dye baths on removal efficiency. Moreover, it was determined that the Langmuir isotherm model was more convenient for the experimental data in the process. In the last part of the study, a correlation analysis was carried out between the color and COD removal efficiencies. Besides, the efficiencies for the use of Al and Fe electrodes respectively for both color and COD removal were compared, and comments were made for different groups by one-way ANOVA..

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

[1]. EPA, “EPA office of compliance sector notebook project: Profile of the textile industry”, EPA/310-R-97- 009, Washington, (1997), pp. 13-51.
[2]. Verma A.K., Dash R.R., Bhunia P., “A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewater”, Journal of Environmental Management, 93, (2012), 154-168.
[3]. Vahdat A., Bahrami S.H., Arami M., Bahjat A., Tabakh F., Khairkhah M., “Decoloration and mineralization of reactive dyes using electron beam irradiation, part I: Effect of the dye structure, concentration and absorbed dose (single, binary and ternary systems)”, Radiation Physics and Chemistry, 81, (2012), 851-856.
[4]. Khandegar V., Saroha A.K., “Electrocoagulation for the treatment of textile industry effluent- a review”, Journal of Environmental Management, 128, (2013), 949-963.
[5]. Khatri A., Peerzada M.H., Mohsin M., White M., “A review on developments in dyeing cotton fabrics with reactive dyes for reducing effluents pollution”, Journal of Cleaner Production, 87, (2015), 50-57.
[6]. Khan R., Banerjee U.C., “Decolorization of azo dyes by mmobilized bacteria. In: Erkurt, H. A. (ed.), Biodegradation of azo dyes”, The Handbook of Environmental Chemistry, Springer: (2010), pp. 73-75.
[7]. Choudhury A.K.R., “Textile preparation and dyeing”, Science Publishers, (2006), pp. 376-377.
[8]. Rizk H.F., İbrahim S.A., El-Borai M.A., “Synthesis, fastness properties, color assessment and antimicrobial activity of some azo reactive dyes having pyrazole moiety”, Dyes Pigments, 112, (2015), 86-92.
[9]. Christie, R. M., “Color chemistry”, The Royal Society of Chemistry: Cambridge, (2001), pp. 24-146.
[10]. Christie, R. M., “Colour Chemistry”, 2nd edition, Royal Society of Chemistry, Cambridge, (2015), pp.72-75.
[11]. Khan Z., Jain K., Soni A., Madamwar D., “Microaerophilic degradation of sulphonated azo dyereactive red 195 by bacterial consortium AR1 through co-metabolism”, International Biodeterioration & Biodegradation, 94, (2014), 167-175.
[12]. Singh R.L., Singh P.K., Sing R.P., “Enzymatic decolorization and degradation of azo dyes-A review”, International Biodeterioration & Biodegradation, 104, (2015), 21-31.
[13]. Malakootian M., Mansoorian H.J., Hosseini A., Khanjani N., “Evaluating the efficacy of alumina/carbon nanotube hybrid adsorbents in removing azo reactive red 198 and blue 19 dyes from aqueous solutions”, Process Safety and Environmental Protection, 96, (2015), 125-137.
[14]. Chequer F.M.D., Lizier T.M., Felicio R., Zanoni M.V.B., Debonsi, H.M., Lopesi N.P., Oliveira D.P., “The azo dye disperse red 13 and its oxidation and reduction products showed mutagenic potential”, Toxicol in Vitro, 29, (2015), 1906-1915.
[15]. Shan B., Tong X., Xiong W., Qiu W., Tang B., Lu R., Ma W., Luo Y., Zhang S., “A new kind of h-acid monoazo-anthraquinone reactive dyes with surprising colour”, Dyes Pigments, 123, (2015), 44-54.
[16]. Aouni A., Fersi C., Cuartes-Uribe B., Bes-Pia A., Alcaina-Miranda M.I., Dhabbi M., “Reactive dyes rejection and textile effluent treatment sudy using ultrafiltration and nanofiltration processes”, Desalination, 297, (2012), 87-96.
[17]. Standard Methods, “Standard methods for the examination of water and wastewater”, American Public Health Association, 19th edition, APHA, AWWA, WPCF, Washington, (1995).
[18]. Fajardo A.S., Martins R.C., Silva D.R., Martinez-Huitle C.A., Quinta-Ferreira R.M., “Dye wastewaters treatment using batch and recirculation flow electrocoagulation systems”, Journal of Electroanalytical Chemistry, 801, (2017), 30-37.
[19]. Khemila B., Merzouk B., Chouder A., Zidelkhi A., Leclerc J-P., Lapicque F., “Removal of a textile dye using photovoltaic electrocoagulation”, Sustainable Chemistry and Pharmacy, 7, (2018), 27-35.
[20]. Khorram A.G., Fallah N., “Treatment of textile dyeing factory wastewater by elctrocoagulation with low sludge settling time: Optimization of operataing parameters by RSM”, Journal of Environmental Chemical Engineering, 6, (2018), 635-642.
[21]. Daneshvar N., Oladegaragoze A., Djafarzadeh N., “Decolorization of basic dye solutions by electrocoagulation: An investigation of the effect of operational parameters”, Journal of Hazardous Material, 129, (2006), 116-122.
[22]. Öztürk T., Veli S., Dimoglo A., “The effect of seawater conductivity on the treatment of leachate by electrocoagulation”, Chemical and Biochemical Engineering Quarterly, 27, (2013), 347-354.
[23]. Verma A. K., “Treatment of textile wastewaters by electrocoagulation employing Fe-Al composite electrode”, Journal of Water Process Engineering, 20, (2017), 168-172.
[24]. Katal R., Pahlavanzadeh H., “Influence of different combinations of aluminum and iron electrode on electrocoagulation fficiency: Application to the treatment of paper mill wastewater”, Desalination, 265, (2011), 199-205.
[25]. Ma H., Wang B. Wang Y., “Application of molybdenum and phosphate modified kaolin in electrochemical treatment of paper mill wastewater”, Journal of Hazardous Material, 145, (2007), 417-423.
[26]. Pajootan E., Arami M., Mahmoodi N.M., “Binary system dye removal by electrocoagulation from synthetic and real colored wastewaters”, Journal of the Taiwan Institute of Chemical Engineers, 43, (2012), 282-290.
[27]. Nandi B.K., Patel S., “Effects of operational parameters on the removal of brilliant green dye from aqueous solutions by electrocoagulation”, Arabian Journal of Chemistry, 10, (2017), S2961-S2968.
[28]. Zaied M., Bellakhal N., “Electrocoagulation treatment of black liquor from paper industry” Journal of Hazardous Material, 163, (2009), 995-1000.
[29]. Ouaissa Y.A., Chabani M., Amrane A., Bensmaili A., “Removal of tetracycline by electrocoagulation: Kinetic and isotherm modeling through adsorption”, Journal of Environmental Chemical Engineering, 2, (2014), 177- 184.
[30]. Mbacké M.K., Kane C., Diallo N.O., Diop C.M., Chauvet F., Combat M., Tzedakis T., “Electrocoagulation process applied on pollutants treatment-experimental optimization and fundamental investigation of the crystal violet dye removal”, Journal of Environmental Chemical Engineering, 4, (2016), 4001-4011.
[31]. Hakizimana J.N., Gourich B., Chafi M., Stiriba Y., Vial C., Drogui P., Naja J., “Electrocoagulation Process in Water Treatment: A Review of Electrocoagulation Modeling Approaches”, Desalination, 404, (2017), 1- 21.
[32]. Yoosefian M., Ahmadzadeh S., Aghasi M., Dolatabadi M., (2017) “Optimization of Electrocoagulation Process for Efficient Removal of Ciprofloxacin Antibiotic Using Iron Electrode: Kinetic and Isotherm Studies of Adsorption”, Journal of Molecular Liquids, 225, (2017), 544-553.
[33]. Zhang Y., Huang G., An C., Xin X., Liu X., Raman M., Yao Y., Wang W., Doble M., “Transport of anion azo dyes from aqueous solution to gemini surfactantmodified wheat bran: Synchrotron infrared, molecular interaction and adsorption studies”, Science of the Total Environmental, 595, (2017), 723-732.
[34]. Alshameri A., He H., Zhu J. Xi, Y., Zhu R., Ma L., Tao Q., “Adsorption of ammonium by different natural clay minerals: Characterization, kinetics and adsorption isotherms”, Applied Clay Science, 159, (2018), 83-93

APA	Öztürk T, AKBAŞ H, Aydin Keskin G (2020). Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. , 115 - 124.
Chicago	Öztürk Tuba,AKBAŞ Hande,Aydin Keskin Gulsen Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. (2020): 115 - 124.
MLA	Öztürk Tuba,AKBAŞ Hande,Aydin Keskin Gulsen Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. , 2020, ss.115 - 124.
AMA	Öztürk T,AKBAŞ H,Aydin Keskin G Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. . 2020; 115 - 124.
Vancouver	Öztürk T,AKBAŞ H,Aydin Keskin G Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. . 2020; 115 - 124.
IEEE	Öztürk T,AKBAŞ H,Aydin Keskin G "Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms." , ss.115 - 124, 2020.
ISNAD	Öztürk, Tuba vd. "Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms". (2020), 115-124.

APA	Öztürk T, AKBAŞ H, Aydin Keskin G (2020). Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. Manas Journal of Engineering, 8(2), 115 - 124.
Chicago	Öztürk Tuba,AKBAŞ Hande,Aydin Keskin Gulsen Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. Manas Journal of Engineering 8, no.2 (2020): 115 - 124.
MLA	Öztürk Tuba,AKBAŞ Hande,Aydin Keskin Gulsen Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. Manas Journal of Engineering, vol.8, no.2, 2020, ss.115 - 124.
AMA	Öztürk T,AKBAŞ H,Aydin Keskin G Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. Manas Journal of Engineering. 2020; 8(2): 115 - 124.
Vancouver	Öztürk T,AKBAŞ H,Aydin Keskin G Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms. Manas Journal of Engineering. 2020; 8(2): 115 - 124.
IEEE	Öztürk T,AKBAŞ H,Aydin Keskin G "Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms." Manas Journal of Engineering, 8, ss.115 - 124, 2020.
ISNAD	Öztürk, Tuba vd. "Dye removal from synthetic and dye bath wastewater by electrocoagulation method and isotherms". Manas Journal of Engineering 8/2 (2020), 115-124.