Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation
Yıl: 2022 Cilt: 50 Sayı: 1 Sayfa Aralığı: 85 - 92 Metin Dili: İngilizce DOI: 10.15671/hjbc.962119 İndeks Tarihi: 29-07-2022
Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation
Öz: A heterogeneous catalyst in the form of Au nanoparticles (Au NPs) immobilized porous manganese oxide (Mn5 O8 ) microspheres was synthesized. Mn5 O8microspheres were obtained by sol-gel templating method. The heterogeneous catalyst (Au@Mn5 O8 ) showed good performance when compared with similar catalysts in the oxidation of benzyl alcohol (BnOH). Au@Mn5 O8microspheres obtained by the decoration of Au NPs on Mn5 O8microspheres performed 99.4% of BnOH conversion and 100 % of benzaldehyde (BnCHO) formation yield. Also the heterogeneous catalyst showed a good stability and agglomeration resistance in the reusability experiments. There was no remarkable loss in the catalytic activity when the catalyst was reused up to 5 times.
Anahtar Kelime: Benzil alkol oksidasyonu için heterojen katalizör olarak altın nanoparçacık immobilize edilmiş gözenekli manganez oksit mikroküreler
Öz: Altın nanopartiküllerle (Au NP'ler) dekore edilmiş gözenekli manganez oksit (Mn5O8) mikroküreleri formunda heterojen bir katalizör sentezlenmiştir. Mn5O8 mikrokürelerinin sentezi için sol-jel kalıplama yöntemi kullanılmıştır. Sentezlenen heterojen katalizör, benzil alkol oksidasyonunda benzer katalizörlerle karşılaştırıldığında iyi performans göstermiştir. Au NP'lerin Mn5O8 mikroküreleri üzerinde immobilizasyonu ile elde edilen heterojen katalizör (Au@Mn5O8) ile %99.4 benzil alkol dönüşümü ve %100 benzaldehit oluşum verimi elde edilmiştir. Ayrıca heterojen katalizör, tekar kullanılabilirlik deneylerinde iyi bir stabilite ve aglomerasyona karşı direnç göstermiştir. Au@Mn5O8 mikroküreleri, katalitik aktivitede kayda değer bir kayıp olmaksızın 5 kata kadar yeniden kullanılabilmiştir.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
- 1. Y. Zhang, X. Cui, F. Shi, Y. Deng, Nano-gold catalysis in fine chemical synthesis, Chem. Rev. 112 (2012) 2467–2505.
- 2. C.D. Pina, E. Falletta, M. Rossi, Update on selective oxidation using gold, Chem. Soc. Rev. 41 (2012) 350–369.
- 3. A. Abad, A. Corma, H. Garcia, Catalyst parameters determining activity and selectivity of supported gold nanoparticles for the aerobic oxidation of alcohols: the molecular reaction mechanism, Chem. Eur. J. 14 (2008) 212–222.
- 4. Y. Hui, S. Zhang, W. Wang, Recent progress in catalytic oxidative transformations of alcohols by supported gold nanoparticles, Adv. Synth. Catal., 361(2019) 2215-2235.
- 5. G. Liu, M. Hou, J. Song, T. Jiang, H. Fan, Z. Zhang, B. Han, Immobilization of Pd nanoparticles with functional ionic liquid grafted onto cross-linked polymer for solvent-free Heck reaction, Green Chem., 12 (2010) 65-69.
- 6. M. Zou, M. Du, M. Zhang, T. Yang, H. Zhu, P. Wang, S. Bao, Synthesis and deposition of ultrafine noble metallic nanoparticles on amino-functionalized halloysite nanotubes and their catalytic application, Mater. Res. Bull., 61 (2015) 375- 382.
- 7. L. Chen, J. Yan, Z. Tong, S. Yu, J. Tang, B. Ou, L. Yue, L. Tian, Nanofiber-like mesoporous alumina supported palladium nanoparticles as a highly active catalyst for base-free oxidation of benzyl alcohol, Micropor. Mesopor. Mat., 266 (2018) 126- 131.
- 8. S. Niu, W. Guo, T.W. Lin, W. Yu, Y. Wu, X. Ji, L. Shao, Nanoscale Pd supported on 3D porous carbon for enhanced selective oxidation of benzyl alcohol, RSC Adv., 7 (2017) 25885-25890.
- 9. Z. Hu, G. Zhou, L. Xu, J. Yang, B. Zhang, X. Xiang, Preparation of ternary Pd/CeO2-nitrogen doped graphene composites as recyclable catalysts for solvent-free aerobic oxidation of benzyl alcohol, Appl. Surf. Sci., 471 (2019) 852-861.
- 10. K. Morgan, A. Goguet, C. Hardacre, Metal redispersion strategies for recycling of supported metal catalysts: a perspective, ACS Catal., 5 (2015) 3430-3445.
- 11. L. Wolski, G. Nowaczyk, S. Jurga, M. Ziolek, Influence of coprecipitation agent on the structure, texture and catalytic activity of Au-CeO2 catalysts in low-temperature oxidation of benzyl alcohol, Catalysts, 11 (2021), 641-656.
- 12. X. Li, J. Feng, M. Perdjon, R. Oh, W. Zhao, X. Huang, S. Liu, Investigations of supported Au-Pd nanoparticles on synthesized CeO2 with different morphologies and application in solvent-free benzyl alcohol oxidation, Appl. Surf. Sci., 505 (2020) 144473.
- 13. S. Mandal, C. Santra, K.K. Bando, O.O. James, S. Maity, D. Mehta, B. Chowdhury, Aerobic oxidation of benzyl alcohol over mesoporous Mn-doped ceria supported Au nanoparticle catalyst, J. Mol. Catal. A: Chem., 378 (2013) 47-56.
- 14. A. Mahdavi-Shakib, J. Sempel, M. Hoffman, A. Oza, E. Bennett, J.S. Owen, A.R. Chokanlu, B.G. Frederick, R.N. Austin, Au/TiO2- catalyzed benzyl alcohol oxidation on morphologically precise anatase nanoparticles, ACS Appl. Mater. Interfaces, 13 (2021) 11793-11804.
- 15. R.H. Adnan, V.B. Golovko, Benzyl alcohol oxidation using gold catalysts derived from Au8 clusters on TiO2, Catal. Lett., 149 (2019) 449-455.
- 16. P. Verma, K. Mori, Y. Kuwahara, S.J. Cho, H. Yamashita, Synthesis of plasmonic gold nanoparticles supported on morphologycontrolled TiO2 for aerobic alcohol oxidation, Catal. Today, 352 (2020) 255-261.
- 17. L.C. Wang, Y.M. Liu, M. Chen, Y. Cao, H.Y. He, K.N. Fan, MnO2 nanorod supported gold nanoparticles with enhanced activity for solvent-free aerobic alcohol oxidation, J. Phys. Chem. A, 112 (2008) 6981-6987.
- 18. B. Das, M. Sharma, M.J. Baruah, B.P. Mounash, G.V. Karunakar, K.K. Bania, Gold nanoparticle supported on mesoporous vanadium oxide for photo-oxidation of 2-naphthol with hydrogen peroxide and aerobic oxidation of benzyl alcohols, J. Environ. Chem. Eng., 8 (2020) 104268.
- 19. G. Nagy, A. Beck, G. Sáfrán, Z. Schay, S. Liu, T. Li, B. Qiao, J. Wang, K. Lázár, Nanodisperse gold catalysts in oxidation of benzyl alcohol: comparison of various supports under different conditions, React. Kinet. Mech. Catal., 128 (2019) 71-95.
- 20. J.A. Gualteros, M.A. Garcia, A.G. da Silva, T.S. Rodrigues, E.G. Cândido, F.A. e Silva, F.C. Fonseca, J. Quiroz, D.C. de Oliveira, S.I.C. de Torresi, C.V.R. de Moura, P.H.C. Camargo, E.M. de Moura, Synthesis of highly dispersed gold nanoparticles on Al2O3, SiO2, and TiO2 for the solvent-free oxidation of benzyl alcohol under low metal loadings, J. Mater. Sci., 54 (2019) 238- 251.
- 21. X. Rao, A. Abou-Hassan, C. Guyon, E.O.M Ruiz, M. Tatoulian, S. Ognier, Synthesis of benzaldehyde with high selectivity using immobilized AuNPs and AuNPs@ zeolite in a catalytic microfluidic system, Lab on a Chip, 19 (2019) 2866-2873.
- 22. L. Liu, H. Li, Y. Tan, X. Chen, R. Lin, W. Yang, C. Huang, S. Wang, X. Wang, X.Y. Liu, M. Zhao, Y. Ding, Metal-support synergy of supported gold nanoclusters in selective oxidation of alcohols, Catalysts, 10 (2020) 107-127.
- 23. M. Haruta, Gold as a low-temperature oxidation catalyst: factors controlling activity and selectivity, Stud. Surf. Sci. Catal., 110 (1997) 123-134.
- 24. L.I. Jinwei, L.I. Weibin, Effect of preparation method on the catalytic activity of Au/CeO2 for VOCs oxidation, J. Rare Earth, 28 (2010) 547-551.
- 25. C. Santra, S. Rahman, S. Bojja, O.O. James, D. Sen, S. Maity, A.K. Mohanty, S. Mazumder, B. Chowdhury, Barium, calcium and magnesium doped mesoporous ceria supported gold nanoparticle for benzyl alcohol oxidation using molecular O2, Catal. Sci. Technol., 3 (2013) 360-370.
- 26. S. Mandal, K.K. Bando, C. Santra, S. Maity, O.O. James, D. Mehta, B. Chowdhury, Sm-CeO2 supported gold nanoparticle catalyst for benzyl alcohol oxidation using molecular O2, Appl. Catal. A: Gen., 452 (2013) 94-104.
- 27. R.B. Tosun, Ç. Kip, A. Tuncel, Polymeric template assisted synthesis of monodisperse-porous manganese oxide microspheres: a new nanozyme with oxidase-like activity allowing biomolecule determination via bimodal sensing, New J. Chem., 43 (2019) 18505-18516.
- 28. R.B. Tosun, K.Ö. Hamaloğlu, P.A. Kavaklı, C. Kavaklı, A. Tuncel, A synergistic catalyst based on a multivalence monodisperseporous microspheres with oxygen vacancies for benzyl alcohol oxidation, Mol. Catal., 497 (2020) 111227.
- 29. C. Keresszegi, D. Ferri, T. Mallat, A. Baiker, Unraveling the surface reactions during liquid-phase oxidation of benzyl alcohol on Pd/Al2O3: an in situ ATR− IR study, J. Phys. Chem. B, 109 (2005) 958-967.
- 30. A. Savara, C.E. Chan‐Thaw, I. Rossetti, A.Villa, L. Prati, Benzyl alcohol oxidation on carbon‐supported Pd nanoparticles: Elucidating the reaction mechanism, ChemCatChem, 6 (2014) 3464-3473.
- 31. C.E. Chan-Thaw, A. Savara, A. Villa, Selective benzyl alcohol oxidation over Pd catalysts, Catalysts, 8 (2018), 431-452.
- 32. F. Galvanin, M. Sankar, S. Cattaneo, D. Bethell, V. Dua, G.J. Hutchings, A. Gavriilidis, On the development of kinetic models for solvent-free benzyl alcohol oxidation over a gold-palladium catalyst. Chem. Eng. J., 342 (2018) 196-210.
| APA | HAMALOGLU K (2022). Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. , 85 - 92. 10.15671/hjbc.962119 |
| Chicago | HAMALOGLU KADRIYE OZLEM Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. (2022): 85 - 92. 10.15671/hjbc.962119 |
| MLA | HAMALOGLU KADRIYE OZLEM Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. , 2022, ss.85 - 92. 10.15671/hjbc.962119 |
| AMA | HAMALOGLU K Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. . 2022; 85 - 92. 10.15671/hjbc.962119 |
| Vancouver | HAMALOGLU K Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. . 2022; 85 - 92. 10.15671/hjbc.962119 |
| IEEE | HAMALOGLU K "Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation." , ss.85 - 92, 2022. 10.15671/hjbc.962119 |
| ISNAD | HAMALOGLU, KADRIYE OZLEM. "Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation". (2022), 85-92. https://doi.org/10.15671/hjbc.962119 |
| APA | HAMALOGLU K (2022). Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. Hacettepe Journal of Biology and Chemistry, 50(1), 85 - 92. 10.15671/hjbc.962119 |
| Chicago | HAMALOGLU KADRIYE OZLEM Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. Hacettepe Journal of Biology and Chemistry 50, no.1 (2022): 85 - 92. 10.15671/hjbc.962119 |
| MLA | HAMALOGLU KADRIYE OZLEM Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. Hacettepe Journal of Biology and Chemistry, vol.50, no.1, 2022, ss.85 - 92. 10.15671/hjbc.962119 |
| AMA | HAMALOGLU K Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. Hacettepe Journal of Biology and Chemistry. 2022; 50(1): 85 - 92. 10.15671/hjbc.962119 |
| Vancouver | HAMALOGLU K Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation. Hacettepe Journal of Biology and Chemistry. 2022; 50(1): 85 - 92. 10.15671/hjbc.962119 |
| IEEE | HAMALOGLU K "Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation." Hacettepe Journal of Biology and Chemistry, 50, ss.85 - 92, 2022. 10.15671/hjbc.962119 |
| ISNAD | HAMALOGLU, KADRIYE OZLEM. "Gold Nanoparticle Immobilized Porous Manganese Oxide Microspheres As Heterogeneous Catalyst for Benzyl Alcohol Oxidation". Hacettepe Journal of Biology and Chemistry 50/1 (2022), 85-92. https://doi.org/10.15671/hjbc.962119 |
