Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion

Çetinkaya, Engin; KÖYTEPE, SÜLEYMAN; SEÇKİN, Turgay; YİĞİT, MURAT

Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion

Murat YİĞİT, (İnönü Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Malatya, Türkiye)

Turgay SEÇKİN, (İnönü Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Malatya, Türkiye)

Süleyman KÖYTEPE, (İnönü Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Malatya, Türkiye)

Engin ÇETİNKAYA (Ege Üniversitesi, Fen Fakültesi, Kimya Bölümü, İzmir, Türkiye)

Turkish Journal of Chemistry

5 0

Yıl: 2007 Cilt: 31 Sayı: 2 Sayfa Aralığı: 113 - 124 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion

Öz:

This paper presents the synthesis and characterization of polyimides containing a chiral (R,R)or (S,S) 1,3-bis(p-N,N'-dimethylaminobenzyl)-perhydrobenzimidazol-2-thion unit in the backbone.The reactions occur between equimolar amounts of a dianhydride and an aromatic dimethylamine in the presence of the solvent N-methyl-2-pyrollidone (NMP). In this work, the chiral monomer RR and SS -1,3-bis(p -N,N'-dimethylaminobenzyl)-perhydrobenzimidazol-2-thion were used as diamines. The polyimides obtained were characterized by thermogravimetry (TGA), differential thermal analysis (DTA), differential scanning calorimeter (DSC), infrared spectroscopy (FT-IR), and gel permeation chromatography (GPC). It was found that the composition of the polymer had a significant effect upon the thermal behavior of the material.

Anahtar Kelime:

Konular: Mühendislik, Kimya

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	YİĞİT M, SEÇKİN T, KÖYTEPE S, Çetinkaya E (2007). Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. , 113 - 124.
Chicago	YİĞİT MURAT,SEÇKİN Turgay,KÖYTEPE SÜLEYMAN,Çetinkaya Engin Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. (2007): 113 - 124.
MLA	YİĞİT MURAT,SEÇKİN Turgay,KÖYTEPE SÜLEYMAN,Çetinkaya Engin Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. , 2007, ss.113 - 124.
AMA	YİĞİT M,SEÇKİN T,KÖYTEPE S,Çetinkaya E Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. . 2007; 113 - 124.
Vancouver	YİĞİT M,SEÇKİN T,KÖYTEPE S,Çetinkaya E Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. . 2007; 113 - 124.
IEEE	YİĞİT M,SEÇKİN T,KÖYTEPE S,Çetinkaya E "Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion." , ss.113 - 124, 2007.
ISNAD	YİĞİT, MURAT vd. "Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion". (2007), 113-124.

APA	YİĞİT M, SEÇKİN T, KÖYTEPE S, Çetinkaya E (2007). Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. Turkish Journal of Chemistry, 31(2), 113 - 124.
Chicago	YİĞİT MURAT,SEÇKİN Turgay,KÖYTEPE SÜLEYMAN,Çetinkaya Engin Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. Turkish Journal of Chemistry 31, no.2 (2007): 113 - 124.
MLA	YİĞİT MURAT,SEÇKİN Turgay,KÖYTEPE SÜLEYMAN,Çetinkaya Engin Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. Turkish Journal of Chemistry, vol.31, no.2, 2007, ss.113 - 124.
AMA	YİĞİT M,SEÇKİN T,KÖYTEPE S,Çetinkaya E Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. Turkish Journal of Chemistry. 2007; 31(2): 113 - 124.
Vancouver	YİĞİT M,SEÇKİN T,KÖYTEPE S,Çetinkaya E Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. Turkish Journal of Chemistry. 2007; 31(2): 113 - 124.
IEEE	YİĞİT M,SEÇKİN T,KÖYTEPE S,Çetinkaya E "Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion." Turkish Journal of Chemistry, 31, ss.113 - 124, 2007.
ISNAD	YİĞİT, MURAT vd. "Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion". Turkish Journal of Chemistry 31/2 (2007), 113-124.