Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes

GÜLTEK, Ahmet

Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes

Ahmet GÜLTEK (İnönü Üniversitesi, Kimya Bölümü, Malatya, Türkiye)

Turkish Journal of Chemistry

4 0

Yıl: 2010 Cilt: 34 Sayı: 3 Sayfa Aralığı: 437 - 445 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes

Öz:

Congo red dye has been bonded to the functionalized octameric polyhedral silsesquioxanes (POSS), which were prepared by hydrolytic condensation of chloro-functionalized organosilicon monomers in the presence of a catalyst. The binding reaction of congo red to the POSS with chloro groups was achieved via the addition of the congo red via NaCl elimination. The structures of POSS with chloro side groups provided an attractive site for binding congo red that not only retains some of its characteristic properties, but also has exceptional hybrid properties possessed by the silica. The dye characteristics of the material were determined by means of UV spectroscopy as well as other conventional techniques.

Anahtar Kelime:

Konular: Mühendislik, Kimya

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

1. Turnell, W. G.; Finch, J. T. J. Mol. Biol. 1992, 227, 1205-1223.
2. Prival, M. J.; Bell, S. J.; Mitchell, V. D.; Peiperl M. D.; Vaughan, V. L. Mutattion Res./Genetic Toxicology 1984, 136, 33-47.
3. Feher, F. J.; Soulivong, D.; Eklund, A. G. Chem. Commun 1998, 399-400.
4. Feher, F. J.; Soulivong, D.; Nguyen, F. Chem. Commun 1998, 1279-1280.
5. Feher, F. J.; Wyndham, K. D.; Knauer D. J. Chem. Commun 1998, 2393-2394.
6. Feher, F. J.; Wyndham, K. D.; Scialdone, M. A.; Hamuro, Y. Chem. Commun 1998, 1469-1470.
7. Feher, F. J.; Soulivong, D.; Eklund, A. G.; Wyndham, K. D. Chem. Commun 1997, 1185-1186.
8. Mantz, R. A.; Jones, P. F.; Chaffe, K. P.; Lichtenhan J. D.; Gilman, J. W. Chem. Mater. 1996, 8, 1250-1259.
9. Feher, F. J.; Soulivong, D. T.; Lewis, G. T. J. Am. Chem. Soc. 1997, 119, 11323-11324.
10. Lee, A.; Lichtenhan, J. D. Macromolecules 1998, 31, 4970-4974.
11. Gültek, A.; Seçkin T.; Adıgüzel, H. İ. Turk. J. Chem. 2005, 29, 391-399.
12. Marui, A. N.; Riccardi, C. C.; Williams, R. J. J. Poly. Bull. 2001, 45, 523-530.
13. Sellinger, A.; Laine, R. M. Chem. Mater. 1996, 8, 1592-1593.
14. Feher, F. J.; Phillips, S. H.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 3397-3398.
15. Zhang, C.; Babonneau, F.; Bonhemme, C.; Laine, R. M.; Soles, C. L.; Hristov, H. A.; Yee, A. F. J. Am. Chem. Soc. 1998, 120, 8380-8391.
16. Kudo, T.; Gordon, M. S. J. Am. Chem. Soc. 1998, 120, 11432-11438.
17. Sellinger, A.; Laine, R. M. Macromolecules 1996, 29, 2327-2330.
18. Haddad, T. S.; Lichtenhan, J. D. Macromolecules 1996, 29, 7302-7304.
19. Tsuchida, A.; Bolln, C.; Sernetz, F. G.; Frey H.; M¨ulhaupt, R. Macromolecules 1997, 30, 2818-2824.
20. Hedrick, J. L.; Cha, H. J.; Miller, R. D.; Yoon, D. Y.; Brown, H. R.; Srinivasan, S.; Pietro, R. D.; Cook, R. F.; Hummel, J. P.; Klaus, D. P.; Liniger, E. G.; Simonyi, E. E., Macromolecules 1997, 30, 8512-8515.
21. Lee, A.; Lichtenhan, J. D. Macromolecules 1998, 31, 4970-4974.
22. Harkness, B. R.; Takeuchi K.; Tachikawa, M. Macromolecules 1998, 31, 4798-4805.
23. Fasce, D. P.; Williams, R. J. J.; Mechin, F.; Pascault, J. P.; Llauro, M. F.; Petiaud, R. Macromolecules 1999, 32, 4757-4763.
24. Pyun, J.; Matyjaszewski, K. Macromolecules 2000, 33, 217-220.
25. Eisenberg, P.; Erra-Balsells, R.; Ishikawa, Y.; Lucas, J. C.; Mauri, A. N.; Nonami, H; Riccardi, C. C.; Williams, R. J. J. Macromolecules 2000, 33, 1940-1947.
26. Chandrasekhar, V.; Murugavel, R.; Voigt, A.; Roesky, H. W.; Schmidt, H. G.; Noltemeyer, M. Organometallic 1996, 15, 918-922.
27. Klemp, A.; Roesky, H.W.; Schmidt, H. G.; Park, H. S.; Noltemeyer, M. Organometallics 1998, 17, 5225-5227.
28. Duchateau, R.; Abbenhuis, H. C. L.; van Santen, R. A.; Thiele, S. K. H.; van Tol, M. F. H. Organometallics 1998, 17, 5222-5224.
29. Duchateau, R.; Cremer, U.; Harmsen, R. J.; Mohamud, S. I.; Abbenhuis, H. C. L.; van Santen, R. A.; Meetsma, A.; Thiele, S. K. T.; van Tol, M. F. H.; Kranenburg, M. Organometallics 1999, 18, 5447-5459.
30. Duchateau, R.; van Santen, R. A.; Yap, G. P. A. Organometallics 2000, 19, 809-816.
31. Yermiyahu, Z.; Landau, A.; Zaban, A.; Lapides I.; Yariv, S. J. Thermal Analysis and Calorimetry 2003, 72, 431-441.
32. Kiuchi, M.; Uchikawa, A.; Tanigmai, T.; Matsuzawa, S.; Yamura, K. J. Appl. Polym. Sci. 2002, 85, 632-637.
33. Kabalka, G. W.; Namboodri, V.; Akula, M. R. J. Labelled Cpd. Radiopharm. 2001, 44, 921-929.
34. Cui, Y.; Wang, M.; Chen, L.; Qian, G. Dyes and Pigments 2004, 62, 43-47.
35. Lye, J.; Freeman, H. S.; Cox, R. D. Dyes and Pigments 2000, 47, 53-64.
36. Neumann, B. Dyes and Pigments 2002, 52, 47-53.
37. Salem, I. A. Transition Metal Chemistry 2000, 25, 599-604.
38. Denizli, A.; K¨okt¨urk, G.; Salih, B.; Kozluca, A.; Pi¸skin. E. J. Appl. Polym. Sci. 1997, 63, 27-33.
39. Caerts, B.; Mol, V.; Sainte, T.; Wilms, G.; Van Den Berg, V.; Stessens, L. Eur. Radiol. 2001, 7, 474-476.
40. Anderson, S. A.; Frank, J. A.; NMR Biomed. 2007, 20, 200-215.
41. Biswas, S.; Hussain, S. A.; Deb, S.; Nath, R. K.; Bhattacharjee, D.; Spectrochimica Acta Part A. 2006, 65, 628-632.

APA	GÜLTEK A (2010). Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. , 437 - 445.
Chicago	GÜLTEK Ahmet Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. (2010): 437 - 445.
MLA	GÜLTEK Ahmet Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. , 2010, ss.437 - 445.
AMA	GÜLTEK A Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. . 2010; 437 - 445.
Vancouver	GÜLTEK A Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. . 2010; 437 - 445.
IEEE	GÜLTEK A "Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes." , ss.437 - 445, 2010.
ISNAD	GÜLTEK, Ahmet. "Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes". (2010), 437-445.

APA	GÜLTEK A (2010). Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. Turkish Journal of Chemistry, 34(3), 437 - 445.
Chicago	GÜLTEK Ahmet Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. Turkish Journal of Chemistry 34, no.3 (2010): 437 - 445.
MLA	GÜLTEK Ahmet Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. Turkish Journal of Chemistry, vol.34, no.3, 2010, ss.437 - 445.
AMA	GÜLTEK A Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. Turkish Journal of Chemistry. 2010; 34(3): 437 - 445.
Vancouver	GÜLTEK A Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes. Turkish Journal of Chemistry. 2010; 34(3): 437 - 445.
IEEE	GÜLTEK A "Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes." Turkish Journal of Chemistry, 34, ss.437 - 445, 2010.
ISNAD	GÜLTEK, Ahmet. "Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes". Turkish Journal of Chemistry 34/3 (2010), 437-445.